화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.107, 354-364, March, 2022
DOI1016/j.jiec.2021.12.007  Export Citation
Glycerol acetalization over highly ordered mesoporous molybdenum dioxide: Excellent catalytic performance, recyclability and water-tolerance
Gyoung Hee Hong, Zhengyang Li, Jin Seo Park, Zhenghua Li, Ki Yeong Kim, Chengbin Li, Jungho Lee, Mingshi Jin1, †, Galen D. Stucky2, and Ji Man Kim†
  • Department of Chemistry, Sungkyunkwan University, Suwon 16419, Republic of Korea
  • 1Department of Chemistry, Yanbian University, Park Road 977, Yanji City133002, Jilin Province, China
  • 2Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106, USA
E-mail:,
Highly ordered mesoporous molybdenum dioxide (meso-MoO2) was successfully synthesized by a nano-replication method using a mesoporous silica template with 3D cubic Ia3d mesostructure. Structural analyses using X-ray diffraction, N2 sorption, and electron microscopy indicated that the meso-MoO2 material exhibited high surface area (106 m2/g), large pore volume (0.66 cm3/g), and well-defined mesopores. Under the optimized reaction conditions, the meso-MoO2 catalyst showed excellent catalytic performances for the acetalization of glycerol with acetone (95.8% of glycerol conversion, and 97.8% of solketal selectivity) at 20 °C, due to its high surface area with large number of acid sites. During recycling, the meso-MoO2 catalyst exhibited a slight decrease in activity; and after a simple regeneration at 350 °C, the catalytic performances could be completely recovered. More importantly, a partial hydrophobic treatment of the meso-MoO2 catalyst dramatically enhanced the water-tolerance during the catalytic reaction.
Keywords:Mesoporous catalyst;Molybdenum dioxide;Glycerol acetalization;Re-usability;Hydrophobic treatment;Water-tolerance
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