화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.57, 226-235, January, 2018
DOI10.1016/j.jiec.2017.08.028  Export Citation
Catalytic conversion of glycerol to lactic acid over graphite-supported nickel nanoparticles and reaction kinetics
Haixu Yin, Hengbo Yin†, Aili Wang†, and Lingqin Shen
  • Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
E-mail:,
Catalytic conversion of biomass glycerol to lactic acid is an alternative to the conventional fermentation process starting from carbohydrate. Graphite-supported metallic Ni0 nanoparticles effectively catalyzed the hydrothermal conversion of glycerol to lactic acid in NaOH aqueous solution. Ni0 nanoparticle and NaOH synergistically catalyzed the glycerol conversion to lactic acid. When the reaction was carried out with the initial glycerol and NaOH concentrations of 1.0 and 1.1 mol L-1 at 230 °C for 3 h over Ni0.3/ graphite catalyst, the selectivity of lactic acid was 92.2% at the glycerol conversion of 97.6%. The reaction activation energy, Ea, was 69.2 kJ mol L-1.
Keywords:Glycerol;Lactic acid;Graphite;Nickel nanoparticles;Reaction kinetics
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