화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.88, 127-136, August, 2020
DOI10.1016/j.jiec.2020.03.037  Export Citation
Controlling the selectivity and deactivation of H-ZSM-5 by tuning b-axis channel length for glycerol dehydration to acrolein
Babar Ali, Xiaocheng Lan, Muhammad Tahir Arslan, Syed Zulfiqar Ali Gilani, Huanjun Wang, and Tiefeng Wang†
  • Beijing Key Laboratory of Green Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
E-mail:
Glycerol dehydration to value-added acrolein over zeolite catalysts is a useful approach to offer a sustainable economic route for the biodiesel industry. Glycerol dehydration over H-ZSM-5 with conventional morphology often exhibits a significant mass transfer limitation and inhibits the access to active sites in the micropores, which causes low activity, selectivity, and severe catalyst deactivation. In this study, a significant impact of b-axis channel length on acrolein selectivity and catalyst activity was revealed by using H-ZSM-5 synthesized with varied channel length in b-axis of 60, 130, 180, and 250 nm. Complete glycerol conversion and high acrolein selectivity (88%) were observed over H-ZSM-5 with 60 nm channels length in b-axis, due to high availability of active sites and enhanced diffusion through the shortest channels, which dramatically suppressed the coke formation. The catalysts with long b-axis channels exhibited a slow internal diffusion, leading to increased polymerization side reactions and coke formation.
Keywords:Glycerol dehydration;Acrolein;ZSM-5 zeolites;b-Axis channels;Diffusion
  1. Ragauskas AJ, Williams CK, Davison BH, Britovsek G, Cairney J, Eckert CA, et al., Science, 311, 484 (2006)
  2. Behr A, Eilting J, Irawadi K, Leschinski J, Lindner F, Green Chem., 10, 13 (2008)
  3. Basha SA, Gopal KR, Jebaraj S, Renew. Sust. Energ. Rev., 13, 1628 (2009)
  4. Quispe CAG, Coronado CJR, Carvalho JA, Renew. Sust. Energ. Rev., 27, 475 (2013)
  5. Pagliaro M, Ciriminna R, Kimura H, Rossi M, Della Pina C, Angew. Chem.-Int. Edit., 46, 4434 (2007)
  6. Zhou CH, Beltramini JN, Fan YX, Lu GQ, Chem. Soc. Rev., 37, 527 (2008)
  7. Alhanash A, Kozhevnikova EF, Kozhevnikov IV, Appl. Catal. A: Gen., 378(1), 11 (2010)
  8. Katryniok B, Paul S, Capron M, Dumeignil F, ChemSusChem, 2, 719 (2009)
  9. Omata K, Izumi S, Murayama T, Ueda W, Catal. Today, 201, 7 (2013)
  10. Galadima A, Muraza O, J. Taiwan Inst. Chem. Eng., 67, 29 (2016)
  11. Talebian-Kiakalaieh A, Amin NAS, Hezaveh H, Renew. Sust. Energ. Rev., 40, 28 (2014)
  12. Katryniok B, Paul S, Dumeignil F, ACS Catal., 3, 1819 (2013)
  13. Grasselli RK, Trifiro F, Rendiconti Lincei, 1 (2017).
  14. Kubicka D, Kubickova I, Cejka J, Catal. Rev.-Sci. Eng., 55(1), 1 (2013)
  15. Corma A, Chem. Rev., 97(6), 2373 (1997)
  16. Mitchell S, Pinar AB, Kenvin J, Crivelli P, Karger J, Perez-Ramirez J, Nat. Commun., 6, 8633 (2015)
  17. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
  18. Chen LH, Li XY, Rooke JC, Zhang YH, Yang XY, Tang Y, Xiao FS, Su BL, J. Mater. Chem., 22, 17381 (2012)
  19. Chal R, Gerardin C, Bulut M, van Donk S, ChemCatChem, 3, 67 (2011)
  20. Perez-Ramirez J, Christensen CH, Egeblad K, Christensen CH, Groen JC, Chem. Soc. Rev., 37, 2530 (2008)
  21. Shan J, Li Z, Zhu S, Liu H, Li J, Wang J, Fan W, Catalyst, 9, 121 (2019)
  22. Suprun W, Lutecki M, Haber T, Papp H, J. Mol. Catal. A-Chem., 309(1-2), 71 (2009)
  23. Park H, Yun YS, Kim TY, Lee KR, Baek J, Yi J, Appl. Catal. B: Environ., 176-177, 1 (2015)
  24. Yun D, Yun YS, Kim TY, Park H, Lee JM, Han JW, Yi J, J. Catal., 341, 33 (2016)
  25. Zhang H, Hu Z, Huang L, Zhang H, Song K, Wang L, Shi Z, Ma J, Zhuang Y, Shen W, Zhang Y, Xu H, Tang Y, ACS Catal., 5, 2548 (2015)
  26. Decolatti HP, Dalla Costa BO, Querini CA, Microporous Mesoporous Mater., 204, 180 (2015)
  27. Katryniok B, Paul S, Capron M, Lancelot C, Belliere-Baca V, Rey P, Dumeignil F, Green Chem., 12, 1922 (2010)
  28. Corma A, Huber GW, Sauvanauda L, O'Connor P, J. Catal., 257(1), 163 (2008)
  29. Chai SH, Wang HP, Liang Y, Xu BQ, Green Chem., 9, 1130 (2007)
  30. Suganuma S, Hisazumi T, Taruya K, Tsuji E, Katada N, Chem. Sel., 2, 5524 (2017)
  31. Wang Z, Wang L, Jiang Y, Hunger M, Huang J, ACS Catal., 4, 1144 (2014)
  32. Possato LG, Diniz RN, Garetto T, Pulcinelli SH, Santilli CV, Martins L, J. Catal., 300, 102 (2013)
  33. Carrico CS, Cruz FT, dos Santos MB, Oliveira DS, Pastore HO, Andrade HMC, Mascarenhas AJS, J. Catal., 334, 34 (2016)
  34. Vieira LH, Carvalho KTG, Urquieta-Gonzalez EA, Pulcinelli SH, Santilli CV, Martins L, J. Mol. Catal. A-Chem., 422, 148 (2016)
  35. Neves TM, Fernandes JO, Liao LM, Deise da Silva E, Augusto da Rosa C, Mortola VB, Microporous Mesoporous Mater., 275, 244 (2019)
  36. Rolf B, Liang H, Raveendran SN, Gadi R, Wei S, Hualong X, ChemCatChem, 10, 211 (2018)
  37. Huang Liang, Qin Feng, Huang Zhen, Zhuang Yan, Ma Jianxue, Xu Hualong, Shen Wei, Ind. Eng. Chem. Res., 55(27), 7318 (2016)
  38. Zhang F, Ren X, Huang H, Huang J, Sudhakar M, Liu LC, Chin. J. Chem. Eng., 26(5), 1031 (2018)
  39. Diallo MM, Laforge S, Pouilloux Y, Mijoin J, Catal. Lett., 148(8), 2283 (2018)
  40. Lopez-Pedrajas S, Estevez R, Blanco-Bonilla F, Luna D, Bautista FM, J. Chem. Technol. Biotechnol., 92(10), 2661 (2017)
  41. Viswanadham B, Nagaraju N, Rohitha CN, Vishwanathan V, Chary KVR, Catal. Lett., 148(1), 397 (2018)
  42. Ren X, Zhang F, Sudhakar M, Wang N, Dai J, Liu L, Catal. Today (2018).
  43. Pala Rosas I, Contreras J, Salmones J, Tapia C, Zeifert B, Navarrete J, Vazquez T, Garcia D, Catalyst, 7, 73 (2017)
  44. Katryniok B, Melendez R, Belliere-Baca V, Rey P, Dumeignil F, Fatah N, Paul S, Front. chem., 7, 127 (2019)
  45. Jiang XC, Zhou CH, Tesser R, Di Serio M, Tong DS, Zhang JR, Ind. Eng. Chem. Res., 57(32), 10736 (2018)
  46. Hulteberg C, Leveau A, Brandin JGM, Top. Catal., 56, 813 (2013)
  47. Monson PA, Langmuir, 24(21), 12295 (2008)
  48. Qureshi BA, Lan XC, Arslan MT, Wang TF, Ind. Eng. Chem. Res., 58(28), 12611 (2019)
  49. Jia CJ, Liu Y, Schmidt W, Lu AH, Schuth F, J. Catal., 269(1), 71 (2010)
  50. Gu Y, Cui N, Yu Q, Li C, Cui Q, Appl. Catal. A: Gen., 429-430, 9 (2012)
  51. Kim YT, Jung KD, Park ED, Appl. Catal. A: Gen., 393(1-2), 275 (2011)
  52. Ma Y, Cai D, Li Y, Wang N, Muhammad U, Carlsson A, Tang D, Qian W, Wang Y, Su D, Wei F, RSC Adv., 6, 74797 (2016)
  53. Liu Y, Zhou X, Pang X, Jin Y, Meng X, Zheng X, Gao X, Xiao FS, ChemCatChem, 5, 1517 (2013)
  54. Lu X, Peng Y, Wang Z, Yan Y, Chem. Commun., 51, 11076 (2015)
  55. Wang N, Sun WJ, Hou YL, Ge BH, Hu L, Nie JQ, Qian WZ, Wei F, J. Catal., 360, 89 (2018)
  56. Treacy MM, Higgins JB, Collection of SIMULATED XRD Powder Patterns for Zeolites, Fifth Revised Ed., Elsevier, 2007.
  57. Liu Z, Wu D, Ren S, Chen X, Qiu M, Wu X, Yang C, Zeng G, Sun Y, ChemCatChem, 8, 3317 (2016)
  58. Luo HY, Bui L, Gunther WR, Min E, Roman-Leshkov Y, ACS Catal., 2, 2695 (2012)
  59. van Donk S, Janssen AH, Bitter JH, de Jong KP, Catal. Rev.-Sci. Eng., 45(2), 297 (2003)
  60. Cundy CS, Cox PA, Chem. Rev., 103(3), 663 (2003)
  61. Baerlocher C, McCusker LB, Olson DH, Atlas of Zeolite Framework Types, Elsevier, 2007.
  62. Corma A, J. Catal., 216(1-2), 298 (2003)
  63. Kim YT, Jung KD, Park ED, Microporous Mesoporous Mater., 131, 28 (2010)
  64. Woolery GL, Kuehl GH, Timken HC, Chester AW, Vartuli JC, Zeolites, 19, 288 (1997)
  65. Al-Dughaither AS, de Lasa H, Ind. Eng. Chem. Res., 53(40), 15303 (2014)
  66. Corma A, Chem. Rev., 95(3), 559 (1995)
  67. Buzzoni R, Bordiga S, Ricchiardi G, Lamberti C, Zecchina A, Bellussi G, Langmuir, 12(4), 930 (1996)
  68. Hunger M, Ernst S, Steuernagel S, Weitkamp J, Microporous Mesoporous Mater., 6, 349 (1996)
  69. Huang J, Jiang Y, Marthala VRR, Thomas B, Romanova E, Hunger M, J. Phys. Chem. C, 112, 3811 (2008)
  70. Li SH, Zheng AM, Sul YC, Zhang HL, Chen L, Yang J, Ye CH, Deng F, J. Am. Chem. Soc., 129(36), 11161 (2007)
  71. Ong LH, Domok M, Olindo R, van Veen AC, Lercher JA, Microporous Mesoporous Mater., 164, 9 (2012)
  72. Xin S, Wang Q, Xu J, Chu Y, Wang P, Feng N, Qi G, Trebosc J, Lafon O, Fan W, Deng F, Chem. Sci., 10, 10159 (2019)
  73. Guisnet M, Magnoux P, Fundamental Description of Deactivation and Regeneration of Acid Zeolites, Elsevier, pp.53 1994.
  74. Khare R, Millar D, Bhan A, J. Catal., 321, 23 (2015)
  75. Gayubo AG, Aguayo AT, Atutxa A, Aguado R, Bilbao J, Ind. Eng. Chem. Res., 43(11), 2610 (2004)
  76. Barrault J, Clacens JM, Pouilloux Y, Top. Catal., 27, 137 (2004)
  77. Zhao H, Zhou CH, Wu LM, Lou JY, Li N, Yang HM, Tong DS, Yu WH, Appl. Clay Sci., 74, 154 (2013)
  78. Prins R, Ertl G, Knozinger H, Weitkam J, Handbook Of Heterogeneous Catalysis. 2., VCH, Weinheim, pp1908 1997.
  79. de Man AJM, van Santen RA, Zeolites, 12, 269 (1992)
  80. Li J, Xiong G, Feng Z, Liu Z, Xin Q, Li C, Microporous Mesoporous Mater., 39, 275 (2000)
  81. Chua YT, Stair PC, J. Catal., 213(1), 39 (2003)
  82. Bibby DM, Milestone NB, Patterson JE, Aldridge LP, J. Catal., 97, 493 (1986)
  83. dos Santos MB, Andrade HMC, Mascarenhas AJS, Microporous Mesoporous Mater., 223, 105 (2016)