화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.73, 316-327, May, 2019
DOI10.1016/j.jiec.2019.01.044  Export Citation
A facile in-situ activation of protonated histidine-derived porous carbon for electrochemical capacitive energy storage
Thanh-Nhan Tran, Hwa Jung Kim1, Jitendra S. Samdani, Jun Yeon Hwang2, Bon-Cheol Ku2, †, Jae Kwan Lee1, †, and Jong-Sung Yu†
  • Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu, 42988, Republic of Korea
  • 1Department of Carbon Materials, Chosun University, Kwangju, 61452, Republic of Korea
  • 2Carbon Composite Materials Research Center, Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), Jeonbuk, 55324, Republic of Korea
E-mail:, ,
A unique and effective synthesis approach to tune the structural and electrochemical properties of carbon materials (CMs) is demonstrated by template-free one-step pyrolysis of protonated histidine (His) containing each of different inorganic acids (HAs) such as HI, HBr, HCl, HNO3, H2SO4, and H3PO4. In particular, the (H3PO4)His-CM possesses high specific surface area, high capacitance, superior energy density and power density along with excellent cycle life. Such excellent electrochemical performance of (H3PO4)His-CM is attributed to the tunable structural properties of the precursor, where H3PO4 plays dual roles of in-situ activation and additional P doping in the carbon skeleton.
Keywords:Amino acid;Histidine;Inorganic acid;Heteroatom doping;In-situ activation
  1. Burke A, Electrochim. Acta, 53(3), 1083 (2007)
  2. Winter M, Brodd RJ, Chem. Rev., 104(10), 424 (2004)
  3. Kotz R, Carlen M, Electrochim. Acta, 45(15-16), 2483 (2000)
  4. Becker H, US Pat. 2, 800, 616 (1957); 2. US2800616 A.
  5. Conway BE, Electrochemical Supercapacitors, Springer US, Boston, MA, pp.11 1999.
  6. Arico AS, Bruce P, Scrosati B, Tarascon JM, Van Schalkwijk W, Nat. Mater., 4(5), 366 (2005)
  7. Chaudhari NK, Chaudhari S, Yu JS, ChemSusChem, 7(11), 3102 (2014)
  8. Rui X, Tan H, Yan Q, Nanoscale, 6(17), 9889 (2014)
  9. Zhang LL, Zhao SY, Tian XN, Zhao XS, Langmuir, 26(22), 17624 (2010)
  10. Saha D, Li YC, Bi ZH, Chen JH, Keum JK, Hensley DK, Grappe HA, Meyer HM, Dai S, Paranthaman MP, Naskar AK, Langmuir, 30(3), 900 (2014)
  11. Razmjooei F, Singh KP, Kang TH, Chaudhari N, Yuan J, Yu JS, Sci. Rep., 7, 10910 (2017)
  12. Kang DY, Kim SO, Chae YJ, Lee JK, Moon JH, Langmuir, 29(4), 1192 (2013)
  13. Li H, Tran TN, Lee BJ, Zhang C, Park JD, Kang TH, Yu JS, ACS Appl. Mater. Interfaces, 9(24), 20294 (2017)
  14. Bhattacharjya D, Kim MS, Bae TS, Yu JS, J. Power Sources, 244, 799 (2013)
  15. Pandolfo AG, Hollenkamp AF, J. Power Sources, 157(1), 11 (2006)
  16. Chen LF, Huang ZH, Liang HW, Gao HL, Yu SH, Adv. Funct. Mater., 24(32), 5104 (2014)
  17. Bhattacharjya D, Yu JS, J. Power Sources, 262, 224 (2014)
  18. Tran TN, Song MY, Singh KP, Yang DS, Yu JS, J. Mater. Chem. A, 4(22), 8645 (2016)
  19. Fang B, Kim JH, Kim MS, Yu JS, Accounts Chem. Res., 46(7), 1397 (2013)
  20. Kim JH, Fang B, Song MY, Yu JS, Chem. Mater., 24(12), 2256 (2012)
  21. Nishihara H, Kyotani T, Adv. Mater., 24(33), 4473 (2012)
  22. Tian W, Zhang H, Sun H, Tade MO, Wang S, Carbon N. Y., 118, 98 (2017)
  23. Tran TN, Shin CH, Lee BJ, Samdani JS, Park JD, Kang TH, Yu JS, Catal. Sci. Technol., 8, 5368 (2018)
  24. Choi IA, Kwak DH, Han SB, Park KW, J. Ind. Eng. Chem., 63, 112 (2018)
  25. Mohamed AR, Mohammadi M, Darzi GN, Renew. Sust. Energ. Rev., 14, 1591 (2010)
  26. Sun L, Tian C, Li M, Meng X, Wang L, Wang R, Yin J, Fu H, J. Mater. Chem. A, 1(21), 6462 (2013)
  27. Chaudhari NK, Song MY, Yu JS, Sci. Rep., 4(1), 5221 (2015)
  28. Xie L, Sun G, Su F, Guo X, Kong Q, Li X, Huang X, Wan L, Song W, Li K, Lv C, Chen CM, J. Mater. Chem. A, 4(5), 1637 (2016)
  29. Kim YK, Park JH, Lee JW, Carbon N. Y., 126, 215 (2018)
  30. Tran TN, Song MY, Kang TH, Samdani J, Park HY, Kim H, Jhung SH, Yu JS, ChemElectroChem, 5(14), 1944 (2018)
  31. An HJ, Kim NR, Song MY, Yun YS, Jin HJ, J. Ind. Eng. Chem., 45, 223 (2017)
  32. Choi J, Kim NR, Jin HJ, Yun YS, J. Ind. Eng. Chem., 43, 158 (2016)
  33. Inal IIG, Holmes SM, Yagmur E, Ermumcu N, Banford A, Aktas Z, J. Ind. Eng. Chem., 61, 124 (2018)
  34. Fang J, Zhan L, Ok YS, Gao B, J. Ind. Eng. Chem., 57, 15 (2018)
  35. Alifano P, Fani R, Lio P, Lazcano A, Bazzicalupo M, Carlomagno MS, Bruni CB, Microbiol. Rev., 60(1), 44 (1996)
  36. Stepansky A, Leustek T, Amino Acids, 30(2), 127 (2006)
  37. Gao XM, Chen Z, Yao Y, Zhou MY, Liu Y, Wang JX, Wu WD, Chen XD, Wu ZX, Zhao DY, Adv. Funct. Mater., 26(36), 6649 (2016)
  38. Huang H, Li CG, Zhu SJ, Wang HL, Chen CL, Wang ZR, Bai TY, Shi Z, Feng SH, Langmuir, 30(45), 13542 (2014)
  39. Ding Y, Niu Y, Yang J, Ma L, Liu J, Xiong Y, Xu H, Small, 12(39), 5414 (2016)
  40. Chen Z, Gao X, Wei X, Wang X, Li Y, Wu T, Guo J, Gu Q, Wu WD, Chen XD, Wu Z, Zhao XD, Carbon N. Y., 121, 143 (2017)
  41. Wang M, Yang Y, Liu X, Pu Z, Kou Z, Zhu P, Mu S, Nanoscale, 9(22), 7641 (2017)
  42. Zhou Y, Sun W, Rui X, Zhou Y, Ng WJ, Yan Q, Fong E, Nano Energy, 21, 71 (2016)
  43. Jeong H, Kim HJ, Lee YJ, Hwang JY, Park OK, Wee JH, Yang CM, Ku BC, Lee JK, Mater. Lett., 145, 273 (2015)
  44. Yao Y, Chen Z, Zhang A, Zhu J, Wei X, Guo J, Wu WD, Chen XD, Wu Z, J. Mater. Chem. A, 5(48), 25237 (2017)
  45. Tang Y, Yuan M, Jiang B, Xiao Y, Fu Y, Chen S, Deng Z, Pan Q, Tian C, Fu H, J. Mater. Chem. A, 5(41), 21979 (2017)
  46. Sevilla M, Fuertes AB, Mokaya R, Energy Environ. Sci., 4(4), 1400 (2011)
  47. Yan XD, Liu Y, Fan XR, Jia XL, Yu YH, Yang XP, J. Power Sources, 248, 745 (2014)
  48. Pang L, Zou B, Zou Y, Han X, Cao L, Wang W, Guo Y, Colloids Surf. A: Physicochem. Eng. Asp., 504, 26 (2016)
  49. Zhang S, Dokko K, Watanabe M, Chem. Mater., 26(9), 2915 (2014)
  50. Zhang SG, Miran MS, Ikoma A, Dokko K, Watanabe M, J. Am. Chem. Soc., 136(5), 1690 (2014)
  51. Zhang S, Ikoma A, Ueno K, Chen Z, Dokko K, Watanabe M, ChemSusChem, 8(9), 1608 (2015)
  52. Chen W, Fan Z, Gu L, Bao X, Wang C, Chem. Commun., 46(22), 3905 (2010)
  53. Kumar R, Kim HJ, Park S, Srivastava A, Oh IK, Carbon N. Y., 79(1), 192 (2014)
  54. Singh KP, Bhattacharjya D, Razmjooei F, Yu JS, Sci. Rep., 6, 31555 (2016)
  55. Ramakrishnan P, Shanmugam S, ACS Sustain. Chem. Eng., 4(4), 2439 (2016)
  56. Zhu C, Liu T, Qian F, Han TYJ, Duoss EB, Kuntz JD, Spadaccini CM, Worsley MA, Li Y, Nano Lett., 16(6), 3448 (2016)
  57. Zhang W, Xu C, Ma C, Li G, Wang Y, Zhang K, Li F, Liu C, Cheng HM, Du Y, Tang N, Ren W, Adv. Mater., 29(36), 170167 (2017)
  58. Hao X, Wang J, Ding B, Shen L, Xu Y, Wang Y, Chang Z, Dou H, Lu X, Zhang X, Chem.: A Eur. J., 22(46), 16668 (2016)
  59. Wang R, Yan X, Sci. Rep., 4(1), 3712 (2014)
  60. Chen LF, Huang ZH, Liang HW, Guan QF, Yu SH, Adv. Mater., 25(34), 4746 (2013)
  61. Kim D, Li OL, Saito N, Phys. Chem. Chem. Phys., 17(1), 407 (2015)
  62. Panja T, Bhattacharjya D, Yu JS, J. Mater. Chem. A, 3(35), 18001 (2015)
  63. Cancado LG, Pimenta MA, Neves BRA, Dantas MSS, Jorio A, Phys. Rev. Lett., 93(24), 247401 (2004)
  64. Srinivas G, Zhu Y, Piner R, Skipper N, Ellerby M, Ruoff R, Carbon N. Y., 48(3), 630 (2010)
  65. Li Y, Zhang X, Yang R, Li G, Hu C, RSC Adv., 5(41), 32626 (2015)
  66. Wang H, Maiyalagan T, Wang X, ACS Catal., 2(5), 781 (2012)
  67. Liu Q, Duan YX, Zhao QP, Pan FP, Zhang B, Zhang JY, Langmuir, 30(27), 8238 (2014)
  68. Jia R, Chen J, Zhao J, Zheng J, Song C, Li L, Zhu Z, J. Mater. Chem., 20(48), 10829 (2010)
  69. Shi B, Su Y, Zhang L, Huang M, Liu R, Zhao S, ACS Appl. Mater. Interfaces, 8(17), 10717 (2016)
  70. Li Y, Li S, Wang Y, Wang J, Liu H, Liu X, Wang L, Liu X, Xue W, Ma N, Phys. Chem. Chem. Phys., 19(18), 11631 (2017)
  71. Zheng C, Qi L, Yoshio M, Wang HY, J. Power Sources, 195(13), 4406 (2010)
  72. Seredych M, Hulicova-Jurcakova D, Lu GQ, Bandosz TJ, Carbon N. Y., 46(11), 1475 (2008)
  73. Yang M, Zhou Z, Adv. Sci., 4(8), 160040 (2017)
  74. Wang C, Zhou Y, Sun L, Zhao Q, Zhang X, Wan L, Qiu J, J. Phys. Chem. C, 117(29), 14912 (2013)
  75. Xu D, Tong Y, Yan T, Shi L, Zhang D, ACS Sustain. Chem. Eng., 5(7), 5810 (2017)
  76. Gu W, Sevilla M, Magasinski A, Fuertes SB, Yushin G, Energy Environ. Sci., 6(8), 2465 (2013)
  77. Gao W, Feng X, Zhang T, Huang H, Li J, Song W, ACS Appl. Mater. Interfaces, 6(21), 19109 (2014)
  78. Wang S, Dryfe RAW, J. Mater. Chem. A, 1(17), 5279 (2013)
  79. Cherusseri J, Kar KK, J. Mater. Chem. A, 3(43), 21586 (2015)
  80. Peng H, Ma G, Sun K, Zhang Z, Yang Q, Ran F, Lei Z, J. Mater. Chem. A, 3(25), 13210 (2015)
  81. Wang S, Zhang J, Shang P, Li Y, Chen Z, Xu Q, Chem. Commun., 50(81), 12091 (2014)
  82. Jain A, Aravindan V, Jayaraman S, Kumar PS, Balasubramanian R, Ramakrishna S, Madhavi S, Srinivasan MP, Sci. Rep., 3(1), 3002 (2013)
  83. Wang DW, Li F, Liu M, Lu GQ, Cheng HM, Angew. Chem.-Int. Edit., 47(2), 373 (2008)
  84. Mai LQ, Minhas-Khan A, Tian X, Hercule KM, Zhao YL, Lin X, Xu X, Nat. Commun., 4(1), 2923 (2013)
  85. Chen LF, Zhang XD, Liang HW, Kong M, Guan QF, Chen P, Wu ZY, Yu SH, ACS Nano, 6(8), 7092 (2012)
  86. Zhao J, Lai HW, Lyu ZY, Jiang YF, Xie K, Wang XZ, Wu Q, Yang LJ, Jin Z, Ma YW, Liu J, Hu Z, Adv. Mater., 27(23), 3541 (2015)
  87. Li Y, Zhang Q, Zhang J, Jin L, Zhao X, Xu T, Sci. Rep., 5, 14155 (2015)
  88. Liu J, Deng Y, Li X, Wang L, ACS Sustain. Chem. Eng., 4(1), 177 (2016)
  89. Hou J, Cao C, Ma X, Idrees F, Xu B, Hao X, Lin W, Sci. Rep., 4(1), 7260 (2015)
  90. Yu PP, Li YZ, Zhao X, Wu LH, Zhang QH, Langmuir, 30(18), 5306 (2014)
  91. Ferrero GA, Fuertes AB, Sevilla M, J. Mater. Chem. A, 3(6), 2914 (2015)