Journal of Industrial and Engineering Chemistry, Vol.73, 306-315, May, 2019
The recyclability of alginate hydrogel particles used as a palladium catalyst support
E-mail:,
We investigated the catalytic efficiency of alginate hydrogels used as a catalyst support. An alginate solution containing palladium and magnetic nanoparticles was dropped continuously through a tapered glass capillary using a syringe pump, and the generated alginate droplets were collected in an aqueous solution containing divalent cations. The prepared PdNPs/MNPs-embedded alginate particles were used as a catalyst, catalyst support, and magnetic stirrer for the reduction of 4-nitrophenol. The catalytic reactions were found to depend on the magnetic stirring of the alginate hydrogels. Furthermore, we examined the recyclability while changing the alginate concentration, divalent cation species, and incubation protocols.
- Lee JH, Hong SK, Ko W, Asian J. Chem., 23, 2347 (2011)
- Seo YS, Ahn EY, Park J, Kim TY, Hong JE, Kim K, Park Y, Park Y, Nanoscale Res. Lett., 12, 7 (2017)
- Saha S, Pal A, Kundu S, Basu S, Pal T, Langmuir, 26(4), 2885 (2010)
- Shanmugam S, Viswanathan B, Varadarajan TK, Mater. Chem. Phys., 95(1), 51 (2006)
- Sakamoto M, Majima T, Bull. Chem. Soc. Jpn., 83, 1133 (2010)
- Chairam S, Konkamdee W, Parakhun R, J. Saudi Chem. Soc., 21, 656 (2017)
- Zhao XH, Li Q, Ma XM, Xiong Z, Quan FY, Xia YZ, RSC Adv., 5, 49534 (2015)
- Ai LH, Yue HT, Jiang J, J. Mater. Chem., 22, 23447 (2012)
- Zhao SZ, Duan LP, Xiao CL, Li L, Liao F, J. Adv. Nanomater., 2, 31 (2017)
- Liu YY, Zhao YH, Zhou Y, Guo XL, Chen ZT, Zhang WJ, Zhang Y, Chen J, Wang ZM, Sun LT, Zhang T, Nanotechnology, 29, 315702 (2018)
- Sudhakar P, Soni H, J. Environ. Chem. Eng., 6, 28 (2018)
- Lim JH, Im KM, Junmg EY, Yu TK, Kim JS, Park BJ, J. Ind. Eng. Chem., 62, 471 (2018)
- Xia M, Kim KH, Lee J, Go EM, Park B, Yu TK, Kwak SK, Na HB, Park BJ, Chem. Eng. J., 339, 2125 (2018)
- Lim JH, Cho A, Lee SH, Park B, Kang DW, Koo CM, Yu T, Park BJ, Appl. Surf. Sci., 429, 108 (2018)
- Maki Y, Ito K, Hosoya N, Yoneyama C, Furusawa K, Yamamoto T, Dobashi T, Sugimoto Y, Wakabayashi K, Biomacromolecules, 12(6), 2145 (2011)
- Ramos PE, Silva P, Alario MM, Pastrana LM, Teixeira JA, Cerqueira MA, Vicente AA, Food Hydrocoll., 77, 8 (2018)
- Chtchigrovsky M, Lin Y, Ouchaou K, Chaumontet M, Robitzer M, Quignard F, Taran F, Chem. Mater., 24, 1505 (2012)
- Jouannin C, Vincent C, Dez I, Gaumont AC, Vincent T, Guibal E, Nanomaterials, 2, 31 (2012)
- Nashihah S, Mun’im A, Saputri FC, J. Young Pharm., 10, 37 (2018)
- Mohanapriya S, Bhat SD, Sahu AK, Manokaran A, Vijayakumar R, Pitchumani S, Sridhar P, Shukla AK, Energy Environ. Sci., 3, 1746 (2010)
- Burana-osot J, Hosoyama S, Nagamoto Y, Suzuki S, Linhardt RJ, Toida T, Carbohydr. Res., 344, 2023 (2009)
- Raghu S, Pennathur G, Turk. J. Biol., 42, 307 (2018)
- Dekamin MG, Peyman SZ, Karimi Z, Javanshir S, Naimi-Jamal MR, Barikani M, Int. J. Biol. Macromol., 87, 172 (2016)
- Ching SH, Bansal N, Bhandari B, Crit. Rev. Food Sci. Nutr., 57, 1133 (2017)
- Sun J, Tan H, Materials, 6, 1285 (2013)
- Hu YD, Azadi G, Ardekani AM, Carbohydr. Polym., 120, 38 (2015)
- Chuang JJ, Huang YY, Lo SH, Hsu TF, Huang WY, Huang SL, Lin YS, Int. J. Polym. Sci., 2017, 1 (2017)
- Segale L, Giovannelli L, Mannina P, Pattarino F, Scientifica, 2016, 506270 (2016)
- Kuhbeck D, Mayr J, Haring M, Hofmann M, Quignard F, Diaz DD, New J. Chem., 39, 2306 (2015)
- Wang Q, Liu S, Wang H, Zhu J, Yang Y, Colloids Surf. A: Physicochem. Eng. Asp., 482, 371 (2015)
- Shan C, Li ZX, Wang LX, Su XW, Shi FW, Hu JL, Catal. Commun., 101, 116 (2017)
- Lin YS, Yang CH, Hsu YY, Hsieh CL, Electrophoresis, 34(3), 425 (2013)
- Ai LH, Jiang J, Bioresour. Technol., 132, 374 (2013)
- Thomas M, Naikoo GA, Sheikh MUD, Bano M, Khan F, New J. Chem., 39, 9761 (2015)
- Gao C, An QD, Xiao ZY, Zhai SR, Zhai B, Shi Z, New J. Chem., 41, 13327 (2017)
- Gao C, An QD, Xiao ZY, Zhai SR, Zhai B, Shi Z, Carbohydr. Polym., 181, 744 (2018)
- Pandey S, Mishra SB, Carbohydr. Polym., 113, 525 (2014)
- Lim B, Jiang MJ, Camargo PHC, Cho EC, Tao J, Lu XM, Zhu YM, Xia YN, Science, 324, 1302 (2009)
- Zhu H, Zhang Q, Zhu SP, ACS Appl. Mater. Interfaces, 8, 17395 (2016)
- Morch YA, Donati I, Strand BL, Skjak-Braek G, Biomacromolecules, 7(5), 1471 (2006)
- Haug A, Smidsrød O, Acta Chem. Scand., 24, 843 (1970)
- Hu YD, Wang SB, Abbaspourrad A, Ardekani AM, Langmuir, 31(6), 1885 (2015)
- Hong HJ, Jeong HS, Roh KM, Kang IM, Macromol. Res., 26(11), 1019 (2018)
- Song CK, Kim MK, Lee J, Davaa E, Baskaran R, Yang SG, Macromol. Res. (2018).
- Lee KY, Mooney DJ, Prog. Polym. Sci, 37, 106 (2012)
- Bajpai SK, Sharma S, React. Funct. Polym., 59(2), 129 (2004)