Journal of Industrial and Engineering Chemistry, Vol.68, 168-172, December, 2018
Influence of ionic liquid structures on polyimide-based gel polymer electrolytes for high-safety lithium batteries
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This study first investigates the effect of the choice of cation on three different ionic-liquid-based gel polymer electrolytes (ILPEs) with polyimide membranes. The preparation of three ILPEs based on electrospun membranes of PI and incorporating a room-temperature ionic liquid, 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide complexed with lithium bis(trifluoromethylsulfonyl)imide, is described. ILPE-EMImTFSI has an ionic conductivity as high as 5.3 × 10-3 S cm?1 at 30 °C. Furthermore, it shows higher thermal stability and electrochemical oxidation stability compared to the other two ILPEs because of its stronger bonds. These results indicate that polyimide-based ILPE-EMImTFSI is a good candidate for use in high-safety rechargeable lithium metal batteries.
- Murata K, Izuchi S, Yoshihisa Y, Electrochim. Acta, 45(8-9), 1501 (2000)
- Xu C, Sun B, Gustafsson T, Edstrom K, Brandell D, Hahlin M, J. Mater. Chem. A, 2, 7256 (2014)
- You DJ, Yin Z, Ahn YK, Cho SH, Kim HJ, Shin DW, Yoo JY, Kim YS, J. Ind. Eng. Chem., 52, 1 (2017)
- Shin JH, Henderson W, Passerini S, Electrochem. Commun., 5, 1016 (2003)
- Keller M, Varzi A, Passerini S, J. Power Sources, 392, 206 (2018)
- Baik JH, Kim DG, Shim J, Lee JH, Choi YS, Lee JC, Polymer, 99, 704 (2016)
- Karuppasamy K, Kim DK, Kang YH, Prasanna K, Rhee HW, J. Ind. Eng. Chem., 52, 224 (2017)
- Baik JH, Kim DG, Lee JH, Kim SW, Hong DG, Lee JC, J. Ind. Eng. Chem., 64, 453 (2018)
- Rodrigues LC, Barbosa PC, Silva MM, Smith MJ, Electrochim. Acta, 53(4), 1427 (2007)
- Wetjen M, Kim GT, Joost M, Appetecchi GB, Winter M, Passerini S, J. Power Sources, 246, 846 (2014)
- Galinski M, Lewandowski A, Stepniak I, Electrochim. Acta, 51(26), 5567 (2006)
- Kim JK, Cheruvally G, Li X, Ahn JH, Kim KW, Ahn HJ, J. Power Sources, 178(2), 815 (2008)
- Ye H, Huang J, Xu JJ, Khalfan A, Greenbaum SG, J. Electrochem. Soc., 154(11), a1048 (2007)
- Yang PX, Liu L, Li LB, Hou J, Xu YP, Ren XF, An MZ, Li N, Electrochim. Acta, 115, 454 (2014)
- Kim JK, Ahn JH, Jacobsson P, Electrochim. Acta, 116, 321 (2014)
- Li X, Cheruvally G, Kim JK, Choi JW, Ahn JH, Kim KW, Ahn HJ, J. Power Sources, 167(2), 491 (2007)
- Miao YE, Zhu GN, Hou HQ, Xia YY, Liu TX, J. Power Sources, 226, 82 (2013)
- Kong LY, Yan YR, Qiu ZM, Zhou ZQ, Hu JQ, J. Membr. Sci., 549, 321 (2018)
- Kim JK, Choi JW, Cheruvally G, Kim JU, Ahn JH, Cho GB, Kim KW, Ahn HJ, Mater. Lett., 61, 3822 (2007)
- Li XW, Zhang ZX, Yin K, Yang L, Tachibana K, Hirano S, J. Power Sources, 278, 128 (2015)
- Rey I, Johansson P, Lindgren J, Lassegues JC, Grondin J, Servant L, J. Phys. Chem. A, 102(19), 3249 (1998)
- Lassegues JC, Grondin J, Aupetit C, Johansson P, J. Phys. Chem. A, 113(1), 305 (2009)
- Kim JK, Matic A, Ahn JH, Jacobsson P, J. Power Sources, 195(22), 7639 (2010)
- Duluard S, Grondin J, Bruneel JL, Pianet I, Grelard A, Campet G, Delville MH, Lassegues JC, J. Raman Spectrosc., 39, 627 (2008)
- Howlett PC, Izgorodina EI, Forsyth M, MacFarlane DR, Z. Phys. Chem., 220, 1483 (2006)
- Kim JK, Scheers J, Park TJ, Kim Y, ChemSusChem, 8, 636 (2015)
- Raghavan P, Zhao X, Choi H, Lim DH, Kim JK, Matic A, Jacobsson P, Nah C, Ahn JH, Solid State Ion., 262, 77 (2014)
- Eshetu GG, Armand M, Scrosati B, Passerini S, Angew. Chem.-Int. Edit., 53, 13342 (2014)
- Kim JK, Niedzicki L, Scheers J, Shin CR, Lim DH, Wieczorek W, Johansson P, Ahn JH, Matic A, Jacobsson P, J. Power Sources, 224, 93 (2013)
- Montanino M, Moreno M, Carewska M, Maresca G, Simonetti E, Lo Presti R, Alessandrini F, Appetecchi GB, J. Power Sources, 269, 608 (2014)
- Holzapfel M, Jost C, Novak P, Chem. Commun., 2098 (2004).
- Zheng H, Jiang J, Abe T, Ogumi Z, Carbon, 44, 203 (2006)