화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 224-234, August, 2017
DOI10.1016/j.jiec.2017.03.051  Export Citation
Improved electrochemical, mechanical and transport properties of novel lithium bisnonafluoro-1-butanesulfonimidate (LiBNFSI) based solid polymer electrolytes for rechargeable lithium ion batteries
K. Karuppasamy1, 2, †, Dongkyu Kim1, Yong Hee Kang1, K. Prasanna3, and Hee Woo Rheea1, †
  • 1Polymer Materials Lab, Department of Chemical and Biomolecular Engineering, Sogang University, Mapo-gu, Seoul, South Korea
  • 2Division of Electronics and Electrical Engineering, Dongguk University-Seoul, Seoul 04620, South Korea
  • 3Electrochemical Energy Storage and Conversion Lab (EESC), Kyung Hee University, 1732, Deogyeong-daero, Giheung-gu, Yongin, Gyeonggi 17104, South Korea
E-mail:,
In the present work, a new methodology for improving the ionic conductivity and cation transport properties of polymer electrolytes have been synthesized by adding bulky anion based novel lithium bisnonafluoro-1-butanesulfonimidate salt and characterized for its applications in lithium ion batteries. The self-standing solid polymer electrolyte films exhibit excellent mechanical, thermal, and electrochemical stability. The ion.polymer interactions are examined thoroughly by ATR Fourier Transform-Infra Red Spectroscopy. The solid polymer electrolyte prepared with EO/Li ratio 14 exhibits a highest ionic conductivity of 10-4 S cm-1 at 333 K. Also, it achieves a maximum lithium transference number of 0.31 and it is electrochemically stable in the scanned electrochemical window. This new type of polymer electrolytes with high ion conductivity and improved mechanical properties paves way to be a potential candidate along with lithium anode and LiCoO2 cathode in the lithium ion batteries.
Keywords:Ionic conductivity;Transference number;Electrochemical stability;Lithium ion batteries;Laviron’s theory
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