화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.41, No.3, 385-393, May, 2017
DOI10.7317/pk.2017.41.3.385  Export Citation
UV 경화성 수분산 폴리우레탄 아크릴레이트에 표면개질된 γ-Al2O3가 함유된 나노복합재료 필름의 합성과 특성
Synthesis and Properties of UV Curable Waterborne Polyurethane Acrylate Nanocomposite Films Based on the Surface Modification of γ-Al2O3
Wen Ran, Shaohui Lin, Garry L. Rempel1, and Qinmin Pan†
  • Green Polymer and Catalysis Technology Laboratory, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu Province, People’s Republic of China
  • 1Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada
E-mail:
Waterborne polyurethane acrylate/surface-modified γ-Al2O3 (WPUA/SAl2O3) nanocomposite films were prepared via a UV-initiated free radical photopolymerization system composed of nanocomposite emulsion, reactive diluents and a photoinitiator. To improve the compatibility of inorganic and organic phases, γ-Al2O3 nanoparticles were surface-modified by γ-methacryloxypropyl trimethoxysilane and combined with a WPUA matrix. The WPUA oligomer was initially prepared by step-growth polymerization, and the content of hydrophilic chain extender, dimethylolpropionic acid (DMPA) was varied to investigate its effect on the properties of the oligomer emulsion. Performance of nanocomposite films with various loadings of SAl2O3 was evaluated by TGA and DSC, water uptake/swelling degree, surface wettability, tensile strength and elongation at break, etc. The results revealed that thermostability of the nanocomposite film was reinforced compared with the WPUA matrix. Swelling capacity and mechanical strength were also improved due to the increase of crosslinking density. Moreover, the optimum content of DMPA for oligomer synthesis was 5%.
Keywords:waterborne polyurethane acrylate;nanocomposite films;surface-modified γ-Al2O3;dimethylolpropionic acid
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