화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.41, No.3, 394-403, May, 2017
DOI10.7317/pk.2017.41.3.394  Export Citation
유무기 하이브리드 흡착제의 합성과 수용액에서의 페놀 흡착 특성 연구
Synthesis of a Chemically Organic/Inorganic Hybrid Adsorbent and Its Adsorption to Phenol in Aqueous Solution
Man Yang, Yun Huang†, Haijun Cao1, Yuanhua Lin, Amin Song, and Qingyuan Sun
  • School of Materials Science and Engineering, Southwest Petroleum University, Chengdu, Sichuan Province 610500, PR China
  • 1Institute of Blood Transfusion, Chinese Academy of Medical Sciences, Chengdu, Sichuan Province 610052, PR China
E-mail:
A novel organic/inorganic hybrid TVE-resin containing SiO2 structure for phenol removal is successfully prepared by dispersion polymerization, in which the inorganic phase is composed of nano-SiO2 modified by vinyltrimethoxy silane (VTMS) and the organic phase is constituted of ethylene glycol dimethacrylate (EGDMA). The chemical structure and physical properties of TVE-resin are characterized by FTIR, TGA, SEM and BET. The adsorption studies imply that the novel materials show optimum adsorption capacity at pH=6, dose 0.1 g, contact time 60 min, initial concentration 3000 mg/L and room temperature. The pseudo first-order model can be well fitted with the kinetic process. According to the adsorption isotherm analysis, the Freundlich model gives a better fit to the experimental data, indicating a multiple molecular adsorption for phenol removal. The calculated thermodynamic parameters indicate an exothermic and spontaneous process. A mixture desorption solvent containing methanol and deionized water (v:v, 1:1) can regenerate the TVE-resin completely and the resin displays good reusability after five regeneration recycles.
Keywords:adsorption;hybrid;phenol;kinetics;thermodynamics
  1. Anbia M, Ghaffari A, Appl. Surf. Sci., 255(23), 9487 (2009)
  2. An FQ, Gao BJ, J. Hazard. Mater., 152(3), 1186 (2008)
  3. An FQ, Du RK, Wang XH, Wan M. Dai X, Gao JF, J. Hazard. Mater., 201-202, 74 (2012)
  4. Zhao GH, Li YF, Liu XX, Liu XL, J. Hazard. Mater., 175(1-3), 715 (2010)
  5. Zeng XW, Yao HJ, Ma N, Fan YG, Wang CH, Shi RF, J. Colloid Interface Sci., 354(1), 353 (2011)
  6. Buran TJ, Sandhu AK, Li Z, Rock CR, Yang WHW, Gu LW, J. Food Eng., 128, 167 (2014)
  7. Liu JS, Liu GN, Liu WX, Chem. Eng. J., 257, 299 (2014)
  8. Nematollahzadeh A, Shojaei A, Karimi M, React. Funct. Polym., 86, 7 (2015)
  9. Jiang XF, Huang JH, J. Colloid Interface Sci., 467, 230 (2016)
  10. Ling X, Li HB, Zha HW, He CL, Huang JH, Chem. Eng. J., 286, 400 (2016)
  11. Tian YA, Yin P, Qu RJ, Wang CH, Zheng HG, Yu ZX, Chem. Eng. J., 162(2), 573 (2010)
  12. Zhao YL, Song JL, Wu D, Tang T, Sun YH, J. Phys. Chem. Solids, 86, 1 (2015)
  13. Parolo ME, Pettinari GR, Musso TB, Sanchez-Izquierdo MP, Fernandez LG, Appl. Surf. Sci., 320, 356 (2014)
  14. Jung CY, Kim JS, Kim HY, Ha JM, Kim YH, Koo SM, J. Colloid Interface Sci., 367, 67 (2012)
  15. Bratkowska D, Fontanals N, Borrull F, Cormack PA, Sherrington DC, Marce RM, J. Chromatogr. A, 1217, 3238 (2010)
  16. Kannan AG, Choudhury NR, Dutta NK, Polymer, 48(24), 7078 (2007)
  17. Wang X, Zheng YQ, Zhang CY, Yang YZ, Lin XC, Huang GH, Xie ZH, J. Chromatogr. A, 1239, 56 (2012)
  18. Mallard I, Stade LW, Ruellan S, Jacobsen PAL, Larsen KL, Fourmentin S, Colloids Surf. A: Physicochem. Eng. Asp., 482, 50 (2015)
  19. Mthombeni NH, Onyango MS, Aoyi O, J. Taiwan Inst. Chem. Eng., 50, 242 (2015)
  20. Han JX, Xie KJ, Du ZJ, Zou W, Zhang C, Carbohydr. Polym., 120, 85 (2015)
  21. Durduran E, Altundag H, Imamoglu M, Yıldız SZ, Tuzen M, J. Ind. Eng. Chem., 27, 245 (2015)
  22. Chang G, He L, Zheng W, Pan AZ, Liu J, Li YJ, Cao RJ, J. Colloid Interface Sci., 396, 129 (2013)
  23. Zeng FX, Liu WJ, Luo SW, Jiang H, Yu HQ, Guo QX, Ind. Eng. Chem. Res., 50(20), 11614 (2011)
  24. Wang XM, Lu MX, Wang H, Pei YF, Rao HH, Du XZ, Sep. Purif. Technol., 153, 7 (2015)
  25. Kim YH, Lee B, Choo KH, Choi SJ, Microporous Mesoporous Mater., 185, 121 (2014)
  26. An FQ, Gao BJ, Feng XQ, Chem. Eng. J., 153(1-3), 108 (2009)
  27. Mwangi IW, Ngila JC, Ndung'u P, Msagati TA, J. Environ. Manage., 134, 70 (2014)
  28. Li ZL, Kong Y, Ge YY, Chem. Eng. J., 270, 229 (2015)
  29. Olu-Owolabi BI, Diagboya PN, Ebaddan WC, Chem. Eng. J., 195-196, 270 (2012)
  30. Uguzdogan E, Denkbas EB, Ozturk E, Tuncel SA, Kabasakal OS, J. Hazard. Mater., 162(2-3), 1073 (2009)
  31. Wang W, Ma Y, Li AM, Zhou Q, Zhou WW, Jin J, J. Hazard. Mater., 294, 158 (2015)
  32. Sen BK, Deshmukh DK, Deb MK, Verma D, Pal J, Bull. Environ. Contam. Toxicol., 93, 549 (2014)
  33. Li ZL, Ge YY, Wan L, J. Hazard. Mater., 285, 77 (2015)
  34. Fu ZY, Li HB, Yang L, Yuan H, Jiao ZH, Chen LM, Huang JH, Liu YN, Chem. Eng. J., 273, 240 (2015)
  35. Wu XW, Liu Y, Liu YF, Di DL, Colloids Surf. A: Physicochem. Eng. Asp., 469, 141 (2015)
  36. Klapiszewski L, Bartczak P, Wysokowski M, Jankowska M, Kabat K, Jesionowski T, Chem. Eng. J., 260, 684 (2015)
  37. Huang HH, Huang KL, Liu SQ, Luo Q, Shi SY, J. Colloid Interface Sci., 317(2), 434 (2008)
  38. Yang GD, Tang L, Zeng GM, Cai Y, Tang J, Pang Y, Zhou YY, Liu YY, Wang JJ, Zhang S, Xiong WP, Chem. Eng. J., 259, 854 (2015)