화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.20, No.4, 335-343, April, 2012
DOI10.1007/s13233-012-0151-x  Export Citation
Multifunctional Materials Based on Polysilsesquioxanes
Fuping Dong, and Chang-Sik Ha†
  • Department of Polymer Science and Engineering, Pusan National University, Busan, 609-735, Korea
E-mail:
This feature article is focused on recent applications of polysilsesquioxane (PSQ), which is a type of molecular-level organic/inorganic hybrid material. PSQs refer to all materials with the formula of (RSiO1.5)n in the molecular structure. The PSQ materials contain organic moieties covalently bonded to siloxane groups. They have been used as high-performance coatings, low dielectric materials, electro-optical materials, and precursors to ceramics. New bioapplications also have been found for PSQ nanoparticles, such as drug delivery and biomolecule or metal ion adsorption, where a porous structure and suitable organic functional groups in the PSQ framework are desirable. This feature article summarizes some recent developments in the applications of PSQs, including our recent publications, with a presentation on the future outlook on the subject.
Keywords:polysilsesquioxane;multifunctional;application;drug delivery;adsorption;low dielectric constant.
  1. Sanchez C, Belleville P, Popall M, Nicole L, Chem.Soc. Rev., 40, 696 (2011)
  2. Sanchez C, Julian B, Belleville P, Popall M, J. Mater.Chem., 15, 3559 (2005)
  3. Bourgeat-Lami E, J. Nanosci. Nanotechnol., 2, 1 (2002)
  4. Wegner G, Demir MM, Faatz M, Gorna K, Munoz-Espi R, Guillemet B, Grohn F, Macromol. Res., 15(2), 95 (2007)
  5. MacKenzie JD, Bescher EP, Acc. Chem. Res., 40, 810 (2007)
  6. Cho W, Char K, Kwon S, Macromol. Res., 17(9), 697 (2009)
  7. Park SS, Ha CS, Chem. Rec., 6, 32 (2006)
  8. Avnir D, Coradin T, Lev O, Livage J, J. Mater. Chem., 16, 1013 (2006)
  9. Pescarmona PP, Maschmeyer T, Aust. J. Chem., 54, 583 (2001)
  10. Moreau JJE, Vellutini L, Man MWC, Bied C, Chem.-Eur. J., 9, 1594 (2003)
  11. Arkhireeva A, Hay JN, J. Mater. Chem., 13, 3122 (2003)
  12. Hah HJ, Kim JS, Jeon BJ, Koo SM, Lee YE, Chem. Commun., 39, 1712 (2003)
  13. Wang Q, Liu Y, Yan H, Chem. Commun., 43, 2339 (2007)
  14. Yuan J, Wan D, Yang Z, J. Phys. Chem. C., 112, 17156 (2008)
  15. Takahashi K, Tadanaga K, Hayashi A, Matsuda A, Katagiri K, Tatsumisago M, J. Nanosci. Nanotechnol., 7, 3307 (2007)
  16. Hamciuc C, Hamciuc E, Okrasa L, Macromol. Res., 19(3), 250 (2011)
  17. Lee SH, Kim HG, Kim SS, Macromol. Res., 18(1), 40 (2010)
  18. Baney RH, Itoh M, Sakakibara A, Suzuki T, Chem. Rev., 95(5), 1409 (1995)
  19. Tamaki R, Tanaka Y, Asuncion MZ, Choi JW, Laine RM, J. Am. Chem. Soc., 123(49), 12416 (2001)
  20. Laine RM, J. Mater. Chem., 15, 3725 (2005)
  21. Kanamori K, Nakanishi K, Chem. Soc. Rev., 40, 754 (2010)
  22. Matsubara Y, Konishi W, Sugizaki T, Moriya O, J. Polym. Sci. A: Polym. Chem., 39(13), 2125 (2001)
  23. Benvenutti EV, Moro CC, Costa TMH, Gallas MR, Quim. Nova., 32, 1926 (2009)
  24. Takamura N, Gunji T, Hatano H, Abe Y, J. Polym. Sci. A: Polym. Chem., 37(7), 1017 (1999)
  25. Dong F, Ha CS, Macromol. Res., 19(2), 101 (2011)
  26. Randall JP,Meador MAB, Jana SC, ACS Appl.Mater. Inter., 3, 613 (2011)
  27. Park HD, Ahn KY, Wahab MA, Jo NJ, Kim I, Ha CS, Kim G, Lee WK, Macromol. Res., 11(3), 172 (2003)
  28. Gomathi P, Ghim HD, Ragupathy D, Macromol. Res., 19(5), 442 (2011)
  29. Manias E, Touny A, Wu L, Strawhecker K, Lu B, Chung TC, Chem. Mater., 13, 3516 (2001)
  30. Liu YL, Chang GP, Wu CS, Chiu YS, J. Polym. Sci. A: Polym. Chem., 43(23), 5787 (2005)
  31. Yoo SH, Kim CK, Macromol. Res., 17(11), 907 (2009)
  32. Zhuo DX, Gu AJ, Liang GZ, Chen Q, Chen T, Yuan L, Hu JT, J. Mater. Sci., 46(24), 7649 (2011)
  33. Xing WT, You B, Wu LM, J. Coat. Technol. Res., 5, 65 (2008)
  34. Xing WT, You B, Wu LM, J. Sol-Gel Sci. Technol., 42, 187 (2007)
  35. Wang XL, Wu LH, Li J, Adv. Polym. Technol., 30(1), 33 (2011)
  36. Wang JB, Zhan YY, Fang JH, Gao HQ, J. Appl. Polym. Sci., 123(2), 1024 (2012)
  37. Yim JH, Lyu YY, Jeong HD, Mah SK, Hyeon-Lee J, Hahn JH, Kim GS, Chang S, Park JG, J. Appl. Polym. Sci., 90(3), 626 (2003)
  38. Nicole L, Rozes L, Sanchez C, Adv. Mater., 22(29), 3208 (2010)
  39. Jang ES, Khan SB, Seo J, Akhtar K, Choi J, Kim KI, Han H, Macromol. Res., 19(10), 1006 (2011)
  40. Lee J, Choi MC, Park SS, Ha CS, Macromol. Res., 19(6), 599 (2011)
  41. Hamciuc C, Hamciuc E, Okrasa L, Macromol. Res., 19(3), 250 (2011)
  42. Jeon JH, Lim JH, Kim KM, Macromol. Res., 18(4), 341 (2010)
  43. Wahab MA, Kim I, Ha CS, Polymer, 44(16), 4705 (2003)
  44. Gao QS, Qi SL, Wu ZP, Wu DZ, Yang WT, Thin Solid Films, 519(19), 6499 (2011)
  45. Ni Y, Zheng SX, J. Polym. Sci. A: Polym. Chem., 44(3), 1093 (2006)
  46. Hu D, Zheng SX, J. Appl. Polym. Sci., 119(5), 2933 (2011)
  47. Volksen W, Miller RD, Dubois G, Chem. Rev., 110(1), 56 (2010)
  48. Chen HJ, Fu M, Macromolecules, 40(6), 2079 (2007)
  49. Mathews AS, Jung Y, Lee T, Park SS, Kim I, Ha CS, Selvaraj M, Han M, Macromol. Res., 17(9), 638 (2009)
  50. Ro HW, Kim KJ, Theato P, Gidley DW, Yoon DY, Macromolecules, 38(3), 1031 (2005)
  51. Volksen W, Miller RD, Dubois G, Chem. Rev., 110(1), 56 (2010)
  52. Nguyen CV, Carter KR, Hawker CJ, Hedrick JL, Jaffe RL, Miller RD, Remenar JF, Rhee HW, Rice PM, Toney MF, Trollss M, Yoon DY, Chem. Mater., 11, 3080 (1999)
  53. Hamciuc C, Hamciuc E, Okrasa L, Macromol. Res., 19(3), 250 (2011)
  54. Xi K, He H, Xu D, Ge RJ, Meng Z, Jia XD, Yu XH, Thin Solid Films, 518(17), 4768 (2010)
  55. Cha BJ, Kim S, Char K, Macromol. Res., 13(3), 176 (2005)
  56. Lee JK, Char K, Rhee HW, Ro HW, Yoo DY, Yoon DY, Polymer, 42(21), 9085 (2001)
  57. Gunji T, Tanikawa S, Arimitsu K, Abe Y, J. Polym. Sci. A: Polym. Chem., 43(16), 3623 (2005)
  58. Gunji T, Iizuka Y, Arimitsu K, Abe Y, J. Polym. Sci. A: Polym. Chem., 42(15), 3676 (2004)
  59. Lee JH, Kim WC, Min SK, Ree HW, Yoon DY, Macromol. Mater. Eng., 288, 455 (2003)
  60. Lee JH, Lyu YY, Lee MS, Hahn JH, Rhee JH, Mah SK, Yim JH, Kim SY, Macromol. Mater. Eng., 289, 164 (2004)
  61. Su RQ, Muller TE, Prochazka J, Lercher JA, Adv. Mater., 14(19), 1369 (2002)
  62. Eckstorff F, Zhu YZ, Maurer R, Muller TE, Scholz S, Lercher JA, Polymer, 52(12), 2492 (2011)
  63. Tseng MC, Liu YL, Polymer, 51(23), 5567 (2010)
  64. Liu HC, Su WC, Liu YL, J. Mater. Chem., 21, 7182 (2011)
  65. Zhou QL, Yan SK, Han CC, Xie P, Zhang RB, Adv. Mater., 20(15), 2970 (2008)
  66. Xie P, Zhang PB, J. Mater. Chem., 15, 2529 (2005)
  67. Zhang JT, Chen ZZ, Fu WX, Xie P, Li ZB, Yan SK, Zhang RB, J. Polym. Sci. A: Polym. Chem., 48(11), 2491 (2010)
  68. Zhou QL, Zhang JT, Ren ZJ, Yan SK, Xie P, Zhang RB, Macromol. Rapid Commun., 29(14), 1259 (2008)
  69. Ren Z, Chen Z, Fu W, Zhang R, Shen F, Wang F, Ma Y, Yan S, J. Mater. Chemun., 21, 11306 (2011)
  70. Choi SS, Lee AS, Lee HS, Baek KY, Choi DH, Hwang SS, Macromol. Res., 19(3), 261 (2011)
  71. Kaneko Y, Toyodome H, Sato H, J. Mater. Chem., 21, 16638 (2011)
  72. Colombo P, Mera G, Riedel R, Soraru GD, J. Am. Ceram. Soc., 93(7), 1805 (2010)
  73. Terauds K, Sanchez-Jimenez PE, Raj R, Vakifahmetoglu C, Colombo P, J. Eur. Ceram. Soc., 30, 2203 (2010)
  74. Soraru GD, Modena S, Guadagnino E, Colombo P, Egan J, Pantano C, J. Am. Ceram. Soc., 85(6), 1529 (2002)
  75. Ma J, Shi LH, Shi YY, Luo SU, Xu J, J. Appl. Polym. Sci., 85(5), 1077 (2002)
  76. Narisawa M, Yasuda H, Mori R, Mabuchi H, Oka K, Kim YW, J. Ceram. Soc. Japan., 116, 121 (2008)
  77. Takamura N, Taguchi K, Gunji T, Abe Y, J. Sol-Gel Sci. Technol., 16, 227 (1999)
  78. Vakifahmetoglu C, Presser V, Yeon SH, Colombo P, Gogotsi Y, Microporous Mesoporous Mater., 144, 105 (2011)
  79. Hasegawa G, Kanamori K, Nakanishi K, Hanada T, J.Mater. Chem., 19, 7716 (2009)
  80. Hasegawa G, Kanamori K, Nakamshi K, Hanada T, Chem. Mater., 22, 2541 (2010)
  81. Hasegawa G, Kanamori K, Nakanishi K, Hanada T, Chem. Commun., 46, 8037 (2010)
  82. Yun MH, Yeon JW, Kim JH, Lee HI, Kim JM, Kim S, Jung Y, Macromol. Res., 19(5), 421 (2011)
  83. Seo SB, Kajiuchi T, Kim DI, Lee SH, Kim HK, Macromol. Res., 10(2), 103 (2002)
  84. Ding ZJ, Qi L, Ye JZ, Macromol. Res., 16(1), 21 (2008)
  85. Gao T, Wang W, Wang A, Macromol. Res., 19(7), 739 (2011)
  86. Dabrowski A, Barczak M, Stolyarchuk NV, Melnyk IV, Zub YL, Adsorption., 11, 501 (2005)
  87. Guo F, Zhu GR, Gao CJ, Prog. Chem., 23, 1237 (2011)
  88. Melde BJ, Johnson BJ, Dinderman MA, Deschamps JR, Microporous Mesoporous Mater., 130, 180 (2010)
  89. Wu HY, Chen CT, Hung IM, Liao CH, Vetrivel S, Kao HM, J. Phys. Chem. C., 114, 7021 (2010)
  90. Wu HY, Liao CH, Pan YC, Yeh CL, Kao HM, Microporous Mesoporous Mater., 119, 109 (2009)
  91. Edmiston PL, Underwood LA, Sep. Sci. Technol., 6, 532 (2009)
  92. Kim YB, Kim YA, Yoon KS, Macromol. Rapid Comm., 7, 1247 (2006)
  93. Lu X, Yin QF, Xin Z, Zhang ZQ, Chem. Eng. Sci., 65(24), 6471 (2010)
  94. Alauzun J, Mehdi A, Mouawia R, Reye C, Corriu RJP, J. Sol-Gel Sci. Tech., 6, 383 (2008)
  95. Besson E, Mehdi A, Van der Lee A, Chollet H, Reye C, Guilard R, Corriu RJP, Chem.-Eur. J., 16, 10226 (2010)
  96. Dong F, Guo W, Park SK, Ha CS, Chem. Commun., 48, 1108 (2012)
  97. Bronstein LM, Linton C, Karlinsey R, Stein B, Svergun DI, Zwanziger JW, Spontak RJ, Nano Lett., 2, 873 (2002)
  98. Bronstein LM, Linton CN, Karlinsey R, Ashcraft E, Stein BD, Svergun DI, Kozin M, Khotina IA, Spontak RJ, Werner-Zwanziger U, Zwanziger JW, Langmuir, 19(17), 7071 (2003)
  99. Beari F, Brand M, Jenkner P, Lehnert R, Metternich HJ, Monkiewicz J, Siesler HW, J. Organomet. Chem., 625, 208 (2001)
  100. Lu X, Yin Q, Xin Z, Li Y, Han T, J. Hazard Mater., 196, 234 (2011)
  101. Minami F, Yamamoto S, Miyasaka Y, Moriya O, Polymer, 52(21), 4744 (2011)
  102. Shea KJ, Loy DA, Webster O, J. Am. Chem. Soc., 114, 6700 (1992)
  103. Yoshitake H, J. Mater. Chem., 20, 4537 (2011)
  104. Yang DJ, Li JP, Xu Y, Wu D, Sun YH, Zhu HY, Deng F, Microporous Mesoporous Mater., 95, 180 (2006)
  105. Yang D, Xu Y, Wu D, Sun Y, Zhu H, Deng F, J.Phys. Chem. C., 111, 999 (2006)
  106. Lee SD, Lee B, Choo KH, Korean J. Chem. Eng., 28(6), 1393 (2011)
  107. Borghard WG, Calabro DC, DiSanzo FP, Disko MM, Diehl JW, Fried JC, Markowitz MA, Zeinali M, Melde BJ, Riley AE, Langmuir, 25(21), 12661 (2009)
  108. Burleigh MC, Markowitz MA, Spector MC, Gaber BP, Environ. Sci. Technol., 36, 2515 (2002)
  109. Dabrowski A, Barczak M, Robens E, Stolyarchuk NV, Yurchenko GR, Matkovskii OK, Zub YL, Appl. Surf. Sci., 253(13), 5747 (2007)
  110. Dong F, Guo W, Park SS, Ha CS, J. Mater. Chem., 21, 10744 (2011)
  111. Rocca JD, Huxford RC, Comstock-Duggan E, Lin WB, Angew. Chem. Int. Ed., 50, 10330 (2011)
  112. Dong F, Guo W, Chu SW, Ha CS, Chem. Commun., 46, 7498 (2010)
  113. Park M, Park SS, Selvaraj M, Zhao DY, Ha CS, Microporous Mesoporous Mater., 124, 76 (2009)
  114. Park M, Park SS, Selvaraj M, Kim I, Ha CS, J.Porous Mater., 18, 217 (2011)