화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.19, No.6, 599-607, June, 2011
DOI10.1007/s13233-011-0603-8  Export Citation
Synthesis and Characterization of Hybrid Films of Polyimide and Silica Hollow Spheres
Sang Joon Lee, Myeon-Cheon Choi, Sung Soo Park, and Chang-Sik Ha†
  • Department of Polymer Science and Engineering, Pusan National University, Busan, 609-735, Korea
E-mail:
Hybrid films were prepared with pyromellitic dianhydride (PMDA)/4,4’-oxydianiline (ODA) polyimide (PMDA-ODA PI) and amino-modified silica hollow spheres (a-SHS). Scanning electron microscopy confirmed the formation of silica hollow spheres without aggregation or deformation. Thermogravimetric analyses showed that the thermal stability of the hybrid films was superior to those of the neat PMDA-ODA PI films. The dielectric constant of the PMDA-ODA PI films was reduced from 3.33 to 2.24 for a hybrid film containing 5 wt% silica hollow spheres. On the other hand, when the content of silica hollow spheres was > 7 wt%, the dielectric constant increased due to the aggregation and collapse of silica hollow spheres. The tensile properties of the hybrid films degraded with increasing a-SHS content compared to those of the neat PMDA-ODA PI film, whereas they were still sufficient for applications as a low-k passivation coating material.
Keywords:polyimide;hybrid;silica hollow sphere;dielectric constant;tensile properties.
  1. Ghosh MK, Mittal KL, Polyimides: Fundamental and Applications, Marcel Dekker, New York, 1996.
  2. Mathews AS, Jung Y, Lee T, Park SS, Kim I, Ha CS, Selvaraj M, Han M, Macromol. Res., 17(9), 638 (2009)
  3. Kim KH, Kim YG, Kwon Y, Macromol. Res., 17(6), 388 (2009)
  4. Kioul A, Mascia L, J. Non-Cryst. Solids, 175, 169 (1994)
  5. Hahm SG, Jin KS, Park S, Ree M, Kim HS, Kwon SK, Kim YH, Macromol. Res., 17(12), 976 (2009)
  6. Ragosta G, Musto P, eXPRESS Polym. Lett., 3, 413 (2009)
  7. Eckert H, Ward M, Chem. Mater., 13, 3059 (2001)
  8. Mark JE, Polym. Eng. Sci., 36(24), 2905 (1996)
  9. Mascia L, Zhang Z, Shaw SJ, Compos. Pt. A-Appl. Sci. Manuf., 27A, 1211 (1996)
  10. Wei Y, Yeh JM, Jin D, Jia X, Wang J, Jang GW, Chen C, Gumbs RW, Chem. Mater., 7, 969 (1995)
  11. Guizard CG, Julbe AC, Ayral A, J. Mater. Chem., 9, 55 (1999)
  12. Wang H, Zhong W, Xu P, Du Q, Compos. Pt. A-Appl. Sci. Manuf., 36A, 909 (2005)
  13. Mascia L, Kioul A, Polymer, 36(19), 3649 (1995)
  14. Maier G, Prog. Polym. Sci, 36, 3 (2001)
  15. Krause B, Koops GH, van der Vegt NFA, Wessling M, Wubbenhorst M, van Turnhout J, Adv. Mater., 14(15), 1041 (2002)
  16. Sharp KG, Adv. Mater., 10(15), 1243 (1998)
  17. Cornelius CJ, Marand E, Polymer, 43(8), 2385 (2002)
  18. Jeng RJ, Chen YM, Jain AK, Kumar J, Tripathy SK, Chem. Mater., 4, 1141 (1992)
  19. Watanabe Y, Shibasaki Y, Ando S, Ueda M, Chem. Mater., 14, 1762 (2002)
  20. Lee J, Hong J, Park DW, Shim SE, Macromol. Res., 17(9), 718 (2009)
  21. Nandi M, Conklin JA, Salvati LJ, Sen A, Chem. Mater., 3, 201 (1991)
  22. Caruso F, Caruso RA, Mohwald H, Science, 282(5391), 1111 (1998)
  23. Sun Y, Xia Y, Science, 298, 2176 (2002)
  24. Sun X, Li Y, Angew. Chem.-Int. Edit., 43, 3827 (2004)
  25. Yang Z, Niu Z, Lu Y, Hu Z, Han CC, Angew. Chem.-Int. Edit., 42, 1943 (2003)
  26. Bamnolker H, Nitzan B, Gura S, Margel S, J. Mater. Sci. Lett., 16(16), 1412 (1997)
  27. Margel S, Bamnolker H, U.S. Patent 6,103,379 (2000).
  28. Chen M, Wu L, Zhou S, You B, Adv. Mater., 19, 801 (2006)
  29. Li ZZ, Wen LX, Shao L, Chen JF, J. Control. Release, 98, 245 (2004)
  30. Chen JF, Ding HM, Wang JX, Shao L, Biomaterials, 25, 723 (2004)
  31. Sharma RK, Das S, Maitra A, J. Colloid Interface Sci., 284(1), 358 (2005)
  32. Wang J, Ding H, Tao X, Chen J, Nanotechnology, 18, 245705 (2007)
  33. Yuan JJ, Zhou GB, Pu HT, J. Membr. Sci., 325(2), 742 (2008)
  34. Lee T, Park SS, Jung Y, Han S, Han D, Kim I, Ha CS, Eur. Polym. J., 45, 19 (2009)
  35. Lin B, Tang J, Liu H, Sun Y, Yuan C, J. Solid State Chem., 178, 650 (2005)
  36. Cheng CF, Cheng HH, Cheng PW, Lee YJ, Macromolecules, 39(22), 7583 (2006)
  37. Lin JJ, Wang XD, Polymer, 48(1), 318 (2007)
  38. Ha YR, Kim YK, Ha CS, Polym. Bull., 59(6), 833 (2008)
  39. Chang CC, Chen WC, Chem. Mater., 14, 4242 (2002)
  40. Srinivasan SA, Hedrick JL, Miller RD, Dipietro R, Polymer, 38(12), 3129 (1997)
  41. Son M, Han S, Han D, Kim Y, Lim J, Kim I, Ha CS, Polym. Bull., 60(5), 713 (2008)
  42. Kim Y, Ha CS, Chang T, Lee WK, Kim W, Kim H, Ha Y, Ree M, J. Nanosci. Nanotechnol., 9, 4633 (2099)
  43. Wen J, Wikes GL, Chem. Mater., 8, 1667 (1996)
  44. Lee YJ, Huang JM, Kuo SW, Chang FC, Polymer, 46(23), 10056 (2005)