SiO2 Nanodot Arrays Using Patterned Functionalization of Self-Assembled Block Copolymer and Selective Adsorption of Amine-Terminated Polydimethylsiloxane

Su Min Kim; Se Jin Ku; Jin-Baek Kim

Macromolecular Research, Vol.19, No.9, 891-896, September, 2011

DOI10.1007/s13233-011-0903-z Export Citation

SiO2 Nanodot Arrays Using Patterned Functionalization of Self-Assembled Block Copolymer and Selective Adsorption of Amine-Terminated Polydimethylsiloxane

Su Min Kim, Se Jin Ku, and Jin-Baek Kim^†

Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, Korea

E-mail:

Silicon dioxide (SiO2) nanodot arrays were fabricated by the selective adsorption of amine-terminated polydimethylsiloxane on functionalized block copolymer thin films. A polystyrene-b-poly(acrylic acid/acrylic anhydride) thin film was created by the acid-catalyzed thermal deprotection of polystyrene-b-poly(tert-butyl acrylate). The amine-terminated polydimethylsiloxane selectively adsorbed on poly(acrylic acid) (PAA)/(acrylic anhydride) (AN) spherical nanodomains using a simple dipping method. Patterned SiO2 nanodot arrays were also fabricated using polystyrene-b-poly(tert-butyl acrylate) coated on the patterned SU-8 film. The final SiO2 nanodot arrays were obtained by the calcination of an organosilicon film.

Keywords:block copolymer;selective adsorption;polydimethylsiloxane;self-assembly;nanodot array.

[References]

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Ni PG, Dong P, Cheng BY, Li XY, Zhang DZ, Adv. Mater., 13(6), 437 (2001)
Lu Y, Yin Y, Li ZY, Xia Y, Nano Lett., 2, 785 (2002)
Kim HC, Jia XQ, Stafford CM, Kim DH, McCarthy TJ, Tuominen M, Hawker CJ, Russell TP, Adv. Mater., 13(11), 795 (2001)
Melde BJ, Burkett SL, Xu T, Goldbach JT, Russell TP, Hawker CJ, Chem. Mater., 17, 4743 (2005)
Kim DH, Kim SH, Layery K, Russell TP, Nano Lett., 4, 1841 (2004)
Kim DH, Jia X, Lin Z, Cuarini KW, Russell TP, Adv. Mater., 16, 702 (2006)
Freer EM, Krupp LE, Hinsberg WD, Rice PM, Hedrick LJ, Cha NJ, Miller RD, Kim HC, Nano Lett., 5, 2014 (2005)
Sundstrom L, Kupp L, Delenia E, Rettner C, Sanchez M, Hart MW, Kim HC, Zhang Y, Appl. Phys. Lett., 88, 243107 (2006)
Nagarajan S, Russell TP, Watkins JJ, Adv. Funct. Mater., 19(17), 2728 (2009)
Park S, Kim B, Wang JY, Russell TP, Adv. Mater., 20(4), 681 (2008)
Jung YS, Ross CA, Nano Lett., 7, 2046 (2007)
Jung YS, Ross CA, Adv. Mater., 21(24), 2540 (2009)
Boontongkong Y, Cohen RE, Macromolecules, 35(9), 3647 (2002)
Xu C, Fu X, Fryd M, Xu S, Wayland BB, Winey KI, Composto RJ, Nano Lett., 6, 282 (2006)
Xu C, Wayland BB, Fryd M, Winey KI, Composto RJ, Macromolecules, 39(18), 6063 (2006)
La HY, Edwards EW, Park SM, Nealey PF, Nano Lett., 5, 1379 (2005)
Ku SJ, Kim SM, Kim JB, Nanotechnology, 20, 285304 (2009)
Kim SM, Ku SJ, Kim JB, Nanotechnology, 21, 235302 (2010)

[1] Whitesides GM, Mathias JP, Seto CPHR, Science, 254, 1312 (1991)

[2] Martin CR, Science, 266(5193), 1961 (1994)

[3] Xia YN, Rogers JA, Paul KE, Whitesides GM, Chem. Rev., 99(7), 1823 (1999)

[4] Liu T, Berger C, Chu B, Prog. Polym. Sci, 28, 5 (2003)

[5] Park M, Harrison CK, Chaikin M, Register RA, Adamson DH, Scinece, 276, 1407 (1997)

[6] Lee M, Cho BK, Zin WC, Chem. Rev., 101, 3869 (2000)

[7] Park C, Yoon J, Thomas EL, Polymer, 44(22), 6725 (2003)

[8] Hamley IW, Angew. Chem.-Int. Edit., 42, 1692 (2003)

[9] Kingon AI, Maria PJ, Streiffer SK, Nature, 406, 1032 (2000)

[10] Ni PG, Dong P, Cheng BY, Li XY, Zhang DZ, Adv. Mater., 13(6), 437 (2001)

[11] Lu Y, Yin Y, Li ZY, Xia Y, Nano Lett., 2, 785 (2002)

[12] Kim HC, Jia XQ, Stafford CM, Kim DH, McCarthy TJ, Tuominen M, Hawker CJ, Russell TP, Adv. Mater., 13(11), 795 (2001)

[13] Melde BJ, Burkett SL, Xu T, Goldbach JT, Russell TP, Hawker CJ, Chem. Mater., 17, 4743 (2005)

[14] Kim DH, Kim SH, Layery K, Russell TP, Nano Lett., 4, 1841 (2004)

[15] Kim DH, Jia X, Lin Z, Cuarini KW, Russell TP, Adv. Mater., 16, 702 (2006)

[16] Freer EM, Krupp LE, Hinsberg WD, Rice PM, Hedrick LJ, Cha NJ, Miller RD, Kim HC, Nano Lett., 5, 2014 (2005)

[17] Sundstrom L, Kupp L, Delenia E, Rettner C, Sanchez M, Hart MW, Kim HC, Zhang Y, Appl. Phys. Lett., 88, 243107 (2006)

[18] Nagarajan S, Russell TP, Watkins JJ, Adv. Funct. Mater., 19(17), 2728 (2009)

[19] Park S, Kim B, Wang JY, Russell TP, Adv. Mater., 20(4), 681 (2008)

[20] Jung YS, Ross CA, Nano Lett., 7, 2046 (2007)

[21] Jung YS, Ross CA, Adv. Mater., 21(24), 2540 (2009)

[22] Boontongkong Y, Cohen RE, Macromolecules, 35(9), 3647 (2002)

[23] Xu C, Fu X, Fryd M, Xu S, Wayland BB, Winey KI, Composto RJ, Nano Lett., 6, 282 (2006)

[24] Xu C, Wayland BB, Fryd M, Winey KI, Composto RJ, Macromolecules, 39(18), 6063 (2006)

[25] La HY, Edwards EW, Park SM, Nealey PF, Nano Lett., 5, 1379 (2005)

[26] Ku SJ, Kim SM, Kim JB, Nanotechnology, 20, 285304 (2009)

[27] Kim SM, Ku SJ, Kim JB, Nanotechnology, 21, 235302 (2010)