화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.19, No.9, 883-890, September, 2011
DOI10.1007/s13233-011-0901-1  Export Citation
High Electrically Conductive Polyaniline/Partially Phosphorylated Poly(vinyl alcohol) Composite Films via Aqueous Dispersions
Fei Chen, and Peng Liu†
  • State Key Laboratory of Applied Organic Chemistry and Institute of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China
E-mail:
A novel low-cost approach was developed for the preparation of high electrically conducting composite films with high comprehensive properties. The polyaniline (PAn)/partially phosphorylated poly(vinyl alcohol) (PPVA) dispersions were synthesized by the chemical oxidative polymerization of aniline in aqueous acidic (1 M HCl) media containing the partially phosphorylated poly(vinyl alcohol) (P-PVA), which can be cast directly to form smooth and mechanically robust composite films. The electrical, thermal, and mechanical properties of the PAn/PPVA composite films were affected by the feeding ratio of aniline in polymerization. The uniform composite films showed a higher degree of crystalline orientation and higher electrical conductivity than those of the PAn/PVA films prepared with the same feeding ratio of aniline.
Keywords:conductive polymer;composite films;casting;mechanical properties.
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