Kinetics of the Reaction between Carbon Dioxide and Glycidyl Methacrylate using 18-Crown-6 as a Catalyst

Sang-Wook Park; Byoung-Sik Choi; Dae-Won Park; Seong-Soo Kim

Journal of Industrial and Engineering Chemistry, Vol.11, No.4, 527-532, July, 2005

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Kinetics of the Reaction between Carbon Dioxide and Glycidyl Methacrylate using 18-Crown-6 as a Catalyst

Sang-Wook Park^†, Byoung-Sik Choi, Dae-Won Park , and Seong-Soo Kim¹

Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea
¹School of Environmental Science, Catholic University of Pusan, Busan 609-757, Korea

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Carbon dioxide was absorbed into organic solutions of glycidyl methacrylate (GMA) in a stirred semi-batch tank having a planar gas-liquid interface at 101.3 kPa. From the absorption rates of carbon dioxide, the reaction kinetics between carbon dioxide and GMA were studied using 18-crown-6 as a catalyst. The reaction rate constants were estimated for the mass transfer mechanism, which is accompanied by a pseudo-first-order reaction. An empirical correlation between the reaction rate constants and the solubility parameters of the solvents, such as toluene, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide, is presented.

Keywords:absorption;carbon dioxide;glycidyl methacrylate;18-crown-6

[References]

Inoue S, in Organic and Bioorganic Chemistry of Carbon Dioxide, S. Inoue and N. Yamazaki, Eds., Kodansha Ltd., Tokyo (1982)
Muratov G, Seo KW, Kim C, J. Ind. Eng. Chem., 11(1), 42 (2005)
Park SE, Han SC, J. Ind. Eng. Chem., 10(7), 1257 (2004)
Hong KM, Kim MS, Chung JG, J. Ind. Eng. Chem., 10(4), 683 (2004)
Peppel WJ, Ind. Eng. Chem., 50, 767 (1950)
Nihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
Rokicki G, Makromol. Chem., 186, 331 (1985)
Park SW, Cho HB, Park DW, J. Ind. Eng. Chem., 9(4), 464 (2003)
Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)
Nishikubo T, Kameyama A, Yamashida J, Tomoi M, Fukuda W, J. Polym. Sci. A: Polym. Chem., 31, 939 (1993)
Rokoski G, Pawlicki J, Kuran W, Polym. J., 17, 509 (1985)
Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
Danckwerts PV, Gas-Liquid Reaction, McGraw-Hill Book Company; New York (1970)
Park SW, Sohn IJ, Park DW, Oh KJ, Sep. Sci. Technol., 38(6), 1361 (2003)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Herbrandson HF, NEufeld FB, J. Org. Chem., 31, 1140 (1966)
Brandrup J, Immergut EH, Polymer Handbook, 2nd Ed., John Wiley & Sons, New York (1975)
Morrison RT, Boyd RN, Organic Chemistry, 4th Ed., Allyn and Bacon, Inc., Toronto, pp 244-246 (1983)

[Referenced By]

[Related Articles]

[1] Inoue S, in Organic and Bioorganic Chemistry of Carbon Dioxide, S. Inoue and N. Yamazaki, Eds., Kodansha Ltd., Tokyo (1982)

[2] Muratov G, Seo KW, Kim C, J. Ind. Eng. Chem., 11(1), 42 (2005)

[3] Park SE, Han SC, J. Ind. Eng. Chem., 10(7), 1257 (2004)

[4] Hong KM, Kim MS, Chung JG, J. Ind. Eng. Chem., 10(4), 683 (2004)

[5] Peppel WJ, Ind. Eng. Chem., 50, 767 (1950)

[6] Nihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)

[7] Rokicki G, Makromol. Chem., 186, 331 (1985)

[8] Park SW, Cho HB, Park DW, J. Ind. Eng. Chem., 9(4), 464 (2003)

[9] Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)

[10] Nishikubo T, Kameyama A, Yamashida J, Tomoi M, Fukuda W, J. Polym. Sci. A: Polym. Chem., 31, 939 (1993)

[11] Rokoski G, Pawlicki J, Kuran W, Polym. J., 17, 509 (1985)

[12] Kihara N, Endo T, Macromolecules, 25, 4824 (1992)

[13] Danckwerts PV, Gas-Liquid Reaction, McGraw-Hill Book Company; New York (1970)

[14] Park SW, Sohn IJ, Park DW, Oh KJ, Sep. Sci. Technol., 38(6), 1361 (2003)

[15] Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)

[16] Herbrandson HF, NEufeld FB, J. Org. Chem., 31, 1140 (1966)

[17] Brandrup J, Immergut EH, Polymer Handbook, 2nd Ed., John Wiley & Sons, New York (1975)

[18] Morrison RT, Boyd RN, Organic Chemistry, 4th Ed., Allyn and Bacon, Inc., Toronto, pp 244-246 (1983)