화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.10, No.7, 1257-1269, December, 2004
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Catalytic Dehydrogenation of Alkylaromatics with Carbon Dioxide as a Soft Oxidant
Sang-Eon Park†, and Sang-Cheol Han
  • Laboratory of Nano-Green Catalysis, Department of Chemistry, Inha University, Incheon 402-751, Korea
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For the mitigation of global warming due to carbon dioxide, catalytic conversion of CO2 has been extensively studied for the last decade. Most of studies in the field have focused on the utilizaiton of carbon dioxide as a carbon source through catalytic reduction processes with various kinds of reductants. However, catalytic hydrogenation has confronted with some limitations to be commercialized because of the use of expensive hydrogen as a reductant. As an alternative way, the utilization of CO2 as a soft oxidant and an oxygen transfer agent is attracting considerable attention. The oxygen species were proven to be active in the oxidative conversions of alkylaromatics into corresponding alkylaromatics with both increased activity and selectivity. This approach is expected to open new technology for the CO2 utilization as an oxidant in the massive utilization of carbon dioxide to get aromatic monomers. Hence, it could be coined as a soft oxidant in the dehydrogenation of alkylaromatics due to the role of CO2 of changing simple dehydrogenation into oxidative conversion together with merits of energy savings and the enhanced activity and selectivity.
Keywords:carbon dioxide;soft oxidant;ethylbenzene;dehydrogenation;styrene
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