화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.108, 81-87, April, 2022
DOI10.1016/j.jiec.2021.12.028  Export Citation
Advanced model for conductivity estimation of graphene-based samples considering interphase effect, tunneling mechanism, and filler wettability
Yasser Zare, and Kyong Yop Rhee1, †
  • Biomaterials and Tissue Engineering Research Group, Department of Interdisciplinary Technologies, Motamed Cancer Institute, ACECR, Tehran, Iran
  • 1Department of Mechanical Engineering (BK21 four), College of Engineering, Kyung Hee University, Yongin, Republic of Korea
E-mail:
In this study, we propose a model for the estimation of conductivity of graphene-based samples considering the roles of the interphase depth, filler portion in the nets, network efficiency, tunneling processes (as a quantum effects of graphene), and superficial energies of polymer and nanoparticles. This model considers the effects of the amount, dimensions, conduction, and percolation onset of graphene nanosheets on conductivity. The proposed model is evaluated using experimental data and parametric examinations. The outputs of the proposed model display a desirable agreement with experimental results. It is demonstrated that the interphase deepness, network efficiency, polymer surface energy, and graphene aspect ratio directly control the conductivity, and a superior conductivity is acquired by the slimmer tunnels, lower percolation onset, and lower filler surface energy.
Keywords:Polymer graphene system;Conductivity;Interphase;Surface energy;Tunneling mechanism;Network
  1. Tang B, Yu H, Peng H, Wang Z, Li S, Ma T, Huang W, RSC Adv., 8, 29220 (2018)
  2. Tang B, Hu G, Gao H, Shi Z, J. Power Sources, 234, 60 (2013)
  3. Tang B, Wang S, Zhang J, Wang Z, He Y, Huang W, Int. Mater. Rev., 63, 204 (2018)
  4. Rostami A, Moosavi MI, J. Appl. Polym. Sci., 137, 48520 (2020)
  5. Rahimzadeh Z, Naghib SM, Askari E, Molaabasi F, Sadr A, Zare Y, Afsharpad M, Rhee KY, Nanotechnol. Rev., 10, 744 (2021)
  6. Liu C, Huang X, Wu YY, Deng X, Liu J, Zheng Z, Hui D, Nanotechnol. Rev., 9, 155 (2020)
  7. Jiang J, Yang S, Li L, Bai S, Polym. Adv. Technol., 31, 1291 (2020)
  8. Ramezanzadeh M, Ramezanzadeh B, Sari MG, Saeb MR, J. Ind. Eng. Chem., 82, 290 (2020)
  9. Heo J, Tanum J, Park S, Choi D, Jeong H, Han U, Hong J, J. Ind. Eng. Chem., 88, 312 (2020)
  10. Jeon JW, Biswas MC, Patton CL, Wujcik EK, J. Ind. Eng. Chem., 84, 72 (2020)
  11. Wang H, Narasaki M, Zhang Z, Takahashi K, Chen J, Zhang X, Sci. Rep., 10, 1 (2020)
  12. Yan Y, Nashath FZ, Chen S, Manickam S, Lim SS, Zhao H, Lester E, Wu T, Pang CH, Nanotechnol. Rev., 9, 1284 (2020)
  13. Kong S, Lim MY, Shin H, Baik JH, Lee JC, J. Ind. Eng. Chem., 84, 131 (2020)
  14. Jang J, Choi Y, Tanaka M, Choi J, J. Ind. Eng. Chem., 83, 46 (2020)
  15. Alimohammadian M, Sohrabi B, Sci. Rep., 10, 1 (2020)
  16. Hajiahmadi M, Zarei M, Khataee A, J. Ind. Eng. Chem., 96, 254 (2021)
  17. Shahini M, Mousavi M, Arabi AM, Mahdavian M, Ramezanzadeh B, J. Ind. Eng. Chem., 101, 51 (2021)
  18. Zhang HB, Zheng WG, Yan Q, Yang Y, Wang JW, Lu ZH, Ji GY, Yu ZZ, Polymer, 51, 1191 (2010)
  19. Song N, Yang J, Ding P, Tang S, Shi L, Compos. Pt. A-Appl. Sci. Manuf., 73, 232 (2015)
  20. Alimohammadian M, Sohrabi B, Sci. Rep., 10, 1 (2020)
  21. Haidari MM, Kim H, Kim JH, Park M, Lee H, Choi JS, Sci. Rep., 10, 1 (2020)
  22. Pal R, Compos. Pt. A-Appl. Sci. Manuf., 39, 718 (2008)
  23. Krupa I, Novák I, Chodák I, Synth. Met., 145, 245 (2004)
  24. Zare Y, Rhee KY, Park SJ, Polym. Compos., 41, 2401 (2020)
  25. Zare Y, Rhee KY, J. Mater. Sci., 55, 5402 (2020)
  26. Takeda T, Shindo Y, Kuronuma Y, Narita F, Polymer, 52, 3852 (2011)
  27. Deng F, Zheng QS, Appl. Phys. Lett., 92 (2008)
  28. Li J, Ma PC, Chow WS, To CK, Tang BZ, Kim JK, Adv. Funct. Mater., 17, 3207 (2007)
  29. Taherian R, Compos. Sci. Technol., 123, 17 (2016)
  30. Zare Y, Rhee KY, J. Mater. Res. Technol., 9, 15996 (2020)
  31. Jabari E, Ahmed F, Liravi F, Secor EB, Lin L, Toyserkani E, 2D Mater., 6 (2019)
  32. Wang F, Gosling JH, Trindade GF, Rance GA, Makarovsky O, Cottam ND, Kudrynskyi Z, Balanov AG, Greenaway MT, Wildman RD, Adv. Funct. Mater., 31, 2007478 (2021)
  33. Clingerman ML, King JA, Schulz KH, Meyers JD, J. Appl. Polym. Sci., 83, 1341 (2002)
  34. Chang L, Friedrich K, Ye L, Toro P, J. Mater. Sci., 44, 4003 (2009)
  35. Kara S, Arda E, Dolastir F, Pekcan O, J. Colloid Interface Sci., 344, 395 (2010)
  36. Zare Y, Rhee KY, J. Phys. Chem. Solids, 131, 15 (2019)
  37. Zare Y, Rhim SS, Rhee KY, Eur. Phys. J. Plus, 136, 1 (2021)
  38. Kazemi F, Mohammadpour Z, Naghib SM, Zare Y, Rhee KY, J. Mater. Res. Technol., 15, 1777 (2021)
  39. Pontefisso A, Zappalorto M, Quaresimin M, Mech. Res. Commun., 52, 92 (2013)
  40. Mortazavi B, Bardon J, Ahzi S, Comput. Mater. Sci., 69, 100 (2013)
  41. Zare Y, Garmabi H, Compos. B Eng., 75, 29 (2015)
  42. Zare Y, Compos. B Eng., 73, 111 (2015)
  43. Zare Y, J. Colloid Interface Sci., 470, 245 (2016)
  44. Hassanzadeh-Aghdam MK, Mahmoodi MJ, Ansari R, Compos. B Eng., 168, 274 (2019)
  45. Hassanzadeh-Aghdam M, Mahmoodi M, Ansari R, Darvizeh A, J. Intell. Mater. Syst. Struct., 162, 93 (2018)
  46. Zare Y, Rhee KY, Compos. Pt. A-Appl. Sci. Manuf., 102, 137 (2017)
  47. Zare Y, Rhee KY, Polym. Compos., 40(10), 4135 (2019)
  48. Qiao R, Brinson LC, Compos. Sci. Technol., 69, 491 (2009)
  49. Baxter SC, Robinson CT, Compos. Sci. Technol., 71, 1273 (2011)
  50. Zare Y, Rhee KY, Eur. Polym. J., 87, 389 (2017)
  51. Du F, Scogna RC, Zhou W, Brand S, Fischer JE, Winey KI, Macromolecules, 37, 9048 (2004)
  52. Ryvkina N, Tchmutin I, Vilcáková J, Pelíšková M, Sáha P, Synth. Met., 148, 141 (2005)
  53. Ambrosetti G, Grimaldi C, Balberg I, Maeder T, Danani A, Ryser P, Phys. Rev. B, 81 (2010)
  54. Hu N, Karube Y, Yan C, Masuda Z, Fukunaga H, Acta Mater., 56, 2929 (2008)
  55. Rittigstein P, Torkelson JM, J. Polym. Sci. B: Polym. Phys., 44, 2935 (2006)
  56. Zare Y, Rhee KY, JOM, 71, 3989 (2019)
  57. Tu Z, Wang J, Yu C, Xiao H, Jiang T, Yang Y, Shi D, Mai YW, Li RK, Compos. Sci. Technol., 134, 49 (2016)
  58. Gao C, Zhang S, Wang F, Wen B, Han C, Ding Y, Yang M, ACS Appl. Mater. Interfaces, 6, 12252 (2014)
  59. Yanovsky YG, Kozlov G, Karnet YN, Phys. Mesomech., 16, 9 (2013)
  60. Feng C, Jiang L, Compos. Pt. A-Appl. Sci. Manuf., 47, 143 (2013)
  61. Li J, Kim JK, Compos. Sci. Technol., 67, 2114 (2007)
  62. Torrisi F, Hasan T, Wu W, Sun Z, Lombardo A, Kulmala TS, Hsieh GW, Jung S, Bonaccorso F, Paul PJ, ACS Nano, 6, 2992 (2012)
  63. Stankovich S, Dikin DA, Dommett GH, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS, Nature, 442, 282 (2006)
  64. He L, Tjong SC, Nanoscale Res. Lett., 8, 132 (2013)
  65. Goumri M, Lucas B, Ratier B, Baitoul M, Opt. Mater., 60, 105 (2016)
  66. Li Y, Zhang H, Porwal H, Huang Z, Bilotti E, Peijs T, Compos. Pt. A-Appl. Sci. Manuf., 95, 229 (2017)
  67. Martin-Gallego M, Bernal M, Hernandez M, Verdejo R, Lopez-Manchado M, Eur. Polym. J., 49, 1347 (2013)
  68. Seidel G, Puydupin-Jamin AS, Mech. Mater., 43, 755 (2011)
  69. Zare Y, Rhee KY, Eur. Phys. J. Plus, 136, 852 (2021)
  70. Zare Y, Rhee KY, Polym. Compos., 41, 748 (2020)