화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.79, 245-254, November, 2019
DOI10.1016/j.jiec.2019.06.045  Export Citation
A novel morphology of 3D graphene hydrogel nanotubes for high-performance nonenzymatic hydrogen peroxide sensor
Mohamed A. Yassin1, Bishnu Kumar Shrestha1, Joshua Lee1, Ju Yeon Kim1, Chan Hee Park1, 2, †, and Cheol Sang Kim1, 2, †
  • 1Department of Bionanosystem Engineering, Graduate School, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 54896, Republic of Korea
  • 2Division of Mechanical Design Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 54896, Republic of Korea
E-mail:,
A novel nanostructure of three-dimensional graphene hydrogel nanotubes (3DGHNTs) is successfully synthesized for the purpose of sensing non-enzymatic H2O2 in alkaline solution. The 3DGHNTs were fabricated using manganese dioxide nanotubes (MnO2 NTs) as the effective sacrificial template and without the use of any acids or a high temperature process. 3DGH with different percentages of MnO2 NTs ranging from 5 to 30% are prepared via a hydrothermal method. When the loading percentage of MnO2 NTs is 10%, the obtained 3DGHNTs-Mn10 nanocomposite exhibits a large specific surface area with high porosity, which enhance the electrochemical properties for H2O2 detection. The developed biosensor exhibits excellent sensitivity (220.4 mA μM-1 cm-2) with a wide linear detection range (25 μ M-22.57 mM) and a low detection limit (4 μM). The biosensor also shows a fast response time (less than 5 s) and good selectivity as well as reproducibility and long-term stability. Hence, the prepared 3DGHNTs-Mn10 nanocomposite can be considered a promising electrode material for the detection of H2O2 in real sample.
Keywords:3D graphene nanotubes;Sacrificial template;Electrochemical sensors;Hydrogen peroxide
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