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Journal of Industrial and Engineering Chemistry, Vol.73, 1-7, May, 2019
Dual functional nickel cobalt/MWCNT composite electrode-based electrochemical capacitor and enzymeless glucose biosensor applications: Influence of Ni/Co molar ratio
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The nickel cobalt/MWCNT composites with Ni/Co molar ratio of 1:2 showed excellent electrochemical performance in term of specific capacitance (~800 F g-1 at current density of 2 A g-1), good rate capability and excellent stability, which may be attributed to the combined benefits of bi-metals and MWCNT and porous metal nanostructures, enhancing the kinetics of ions/electron transport at both electrode inside and electrode/electrolyte interface. Further, the nickel cobalt/MWCNT composite modified electrode as electro-catalyst for glucose electro-oxidation demonstrated high sensitivity, good linear range and detection limit, which hold great promise as advanced electrode materials for supercapacitor and glucose electro-oxidation applications.
Keywords:Nickel cobalt;Carbon nanotube;Composite electrode;Electrochemical capacitor;Glucose biosensor
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