화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.67, 99-108, November, 2018
DOI10.1016/j.jiec.2018.06.020  Export Citation
Thiadiazole-thione surfactants: Preparation, flotation performance and adsorption mechanism to malachite
Yaoguo Huang, Guangyi Liu†, Jun Liu, Xianglin Yang, and Zhiyong Zhang
  • College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China
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In this paper, novel thiadiazole-thione surfactants including 5-heptyl-1,3,4-thiadiazole-2-thione(HpSDT), 5-phenyl-1,3,4-thiadiazole-2-thione (PSDT) and 5-(2-hydroxyphenyl)-1,3,4-thiadiazole-2-thione (HPhSDT) were synthesized and originally introduced as collectors in froth flotation. Microflotation tests showed that HpSDT exhibited better flotation response to malachite than PSDT and HPhSDT, as well as excellent flotation selectivity against quartz. The contact angle results inferred that the hydrophobization intensity of these collectors toward malachite was in the order as HpSDT > PSDT > HPhSDT. ζ-potential recommended a chemisorption of HpSDT on malachite surfaces. FTIR deduced that cupric or cuprous atoms might bond with the S and N atoms of HpSDT to form a conjugated ring. XPS further gave an additional evidence that HpSDT-Cu(I) complexes were produced on malachite surfaces via combining surface Cu atoms with HpSDT’s N and S atoms, with reducing surface Cu(II) to Cu (I). The tighter orientation arrangement on malachite and stronger hydrophobicity rendered HpSDT to possess better flotation affinity toward malachite than PSDT and HPhSDT.
Keywords:Thiadiazole-thione;Chelating collector;Flotation;Malachite;Adsorption mechanism
  1. Corin KC, Kalichini M, O'Connor CT, Simukanga S, Miner. Eng., 102, 15 (2017)
  2. Lee K, Archibald D, McLean J, Reuter MA, Miner. Eng., 22(4), 395 (2009)
  3. Marion C, Jordens A, Li RH, Rudolph M, Waters KE, Sep. Purif. Technol., 183, 258 (2017)
  4. Liu GY, Liu J, Huang YG, Yang XL, Zhong H, Miner. Eng., 118, 78 (2018)
  5. Fuerstenau MC, Jameson GJ, Yoon RH, Froth Flotation: A Century of Innovation, Society for Mining, Metallurgy, and Exploration, Littleton, CO, 2007.
  6. Nagaraj DR, Farinato RS, Miner. Eng., 96, 2 (2016)
  7. Liu G, Yang X, Zhong H, Adv. Colloid Interface Sci., 246, 181 (2017)
  8. Kalichini M, Corin KC, O’Connor CT, Simukanga S, J. S. Afr. Inst. Min. Metall., 117, 803 (2017)
  9. Lee JS, Nagaraj DR, Coe JE, Miner. Eng., 11(10), 929 (1998)
  10. Park K, Park S, Choi J, Kim G, Tong MP, Kim H, Sep. Purif. Technol., 168, 1 (2016)
  11. Shengo LM, Gaydardzhiev S, Kalenga NM, Miner. Eng., 65, 145 (2014)
  12. Feng Q, Zhao W, Wen S, Cao Q, J. Ind. Eng. Chem., 48, 125 (2017)
  13. Feng QC, Zhao WJ, Wen SM, Appl. Surf. Sci., 436, 823 (2018)
  14. Feng Q, Zhao W, Wen S, J. Alloy. Compd., 744, 301 (2018)
  15. Liu G, Huang Y, Qu X, Xiao J, Yang X, Xu Z, Colloids Surf. A: Physicochem. Eng. Asp., 503, 34 (2016)
  16. Li F, Zhong H, Xu H, Jia H, Liu G, Miner. Eng., 17, 188 (2015)
  17. Yang X, Liu S, Liu G, Zhong H, J. Ind. Eng. Chem., 46, 404 (2017)
  18. Liu S, Zhong H, Liu GY, Xu ZH, J. Colloid Interface Sci., 512, 701 (2018)
  19. Liu S, Liu G, Zhong H, Yang X, J. Ind. Eng. Chem., 52, 359 (2017)
  20. Witt CCD, Batchelder FV, J. Am. Chem. Soc., 61, 1250 (1939)
  21. Xu H, Zhong H, Wang S, Niu Y, Liu G, Miner. Eng., 66, 173 (2014)
  22. Xiao JJ, Liu GY, Zhong H, Int. J. Miner. Process., 166, 53 (2017)
  23. Hope GA, Buckley AN, Parker GK, Numprasanthai A, Woods R, McLean J, Miner. Eng., 36, 2 (2012)
  24. Deng J, Wen S, Yin Q, Wu D, Sun Q, J. Taiwan Inst. Chem. Eng., 71, 20 (2017)
  25. Marabini AM, Cirlachi M, Plescia P, Barbaro M, Miner. Eng., 20(10), 1014 (2007)
  26. Liu G, Zeng H, Lu Q, Zhong H, Choi P, Xu Z, Colloids Surf. A: Physicochem. Eng. Asp., 409, 1 (2012)
  27. Nowak P, Barbaro M, Marabini AM, Int. J. Miner. Process., 32, 23 (1991)
  28. Marabini AM, Bornengo G, Alesse V, Bergamini F, 2-Mercapto-benzoxazole derivatives as collectors for the selective flotation of metal ores, U.S. Patent 5505310 (1996).
  29. Maier GS, Dobias B, Miner. Eng., 10(12), 1375 (1997)
  30. Barbaro M, Urbina RH, Cozza C, Fuerstenau D, Marabini A, Int. J. Miner. Process., 50(4), 275 (1997)
  31. Deligeorgiev TG, Kaloyanova SS, Lesev NY, Vaquero JJ, Monatsh. Chem., 142, 895 (2011)
  32. Mor S, Nagoria S, Synth. Commun., 46, 169 (2016)
  33. Qu XY, Xiao JJ, Liu GY, Liu S, Zhang ZY, Miner. Eng., 89, 10 (2016)
  34. Liu G, Xiao J, Liu J, Qu X, Liu Q, Zeng H, Yang X, Xie L, Zhong H, Liu Q, Xu Z, Colloids Surf. A: Physicochem. Eng. Asp., 511, 285 (2016)
  35. Mashhadizadeh MH, Eskandari K, Foroumadi A, Shafiee A, Talanta, 76, 497 (2008)
  36. Bharati P, Bharti A, Bharty MK, Kashyap S, Singh UP, Singh NK, Polyhedron, 63, 222 (2013)
  37. Bharati P, Bharti A, Nath P, Kumari S, Singh NK, Bharty MK, Inorg. Chim. Acta., 443, 160 (2016)
  38. Geboes B, Baert K, Hubin A, Breugelmans T, Electrochim. Acta, 156, 308 (2015)
  39. Blajiev OL, Breugelmans T, Pintelon R, Terryn H, Hubin A, Electrochim. Acta, 53(25), 7451 (2008)
  40. Matsumoto F, Ozaki M, Inatomi Y, Paulson SC, Oyama N, Langmuir, 15(3), 857 (1999)
  41. Varvara S, Bostan R, Gaina L, Muresan LM, Mater. Corros., 65, 1202 (2014)
  42. Saha A, Kumar R, Kumar R, Devakumar C, J. Heterocycl. Chem., 47, 838 (2010)
  43. Li P, Shi L, Gao M, Yang X, Xue W, Jin L, Hu D, Song B, Bioorg. Med. Chem. Lett., 25, 481 (2015)
  44. Tian J, Xu LH, Deng W, Jiang H, Gao ZY, Hu YH, Chem. Eng. Sci., 164, 99 (2017)
  45. Hipler F, Fischer RA, Muller J, J. Chem. Soc. Perkin Trans., 29, 16020 (2002)
  46. Guzeldemirci NU, Kucukbasmacı O, Eur. J. Med. Chem., 45, 63 (2010)
  47. Chen W, Hong S, Li H, Luo H, Li M, Li N, Corrosion Sci., 61, 53 (2012)
  48. Chufan EE, Pedregosa JC, Borras J, Vib. Spectrosc., 15, 191 (1997)
  49. Huang L, Shen J, Ren J, Meng QJ, Yu T, Chin. Sci. Bull., 46, 387 (2001)
  50. Feng QC, Zhao WJ, Wen SM, Cao QB, Sep. Purif. Technol., 178, 193 (2017)
  51. Feng QC, Wen SM, Deng JS, Zhao WJ, Appl. Surf. Sci., 425, 8 (2017)
  52. Liu GY, Qiu ZH, Wang JY, Liu QX, Xiao JJ, Zeng HB, Zhong H, Xu ZH, J. Colloid Interface Sci., 437, 42 (2015)
  53. Zhou JJ, Chen SH, Zhang L, Feng YY, Zhai HY, J. Electroanal. Chem., 612(2), 257 (2008)
  54. Kalimuthu P, John SA, Electrochem. Commun., 11, 367 (2009)
  55. He Z, Liu G, Yang X, Liu W, J. Ind. Eng. Chem., 37, 107 (2016)
  56. Taylor CD, Chandra A, Vera J, Sridhar N, J. Electrochem. Soc., 162(7), C347 (2015)
  57. Xu LH, Wu HQ, Dong FQ, Wang L, Wang Z, Xiao JH, Miner. Eng., 41, 41 (2013)
  58. Deng LQ, Zhong H, Wang S, Liu GY, Sep. Purif. Technol., 145, 8 (2015)