Efficient extraction and recovery of Lignosulfonate using sunflower oil as green solvent in liquid membrane transport: Equilibrium and kinetic study

Vikas Kumar; Raghubansh K. Singh; Pradip Chowdhury

Journal of Industrial and Engineering Chemistry, Vol.67, 109-122, November, 2018

DOI10.1016/j.jiec.2018.06.021 Export Citation

Efficient extraction and recovery of Lignosulfonate using sunflower oil as green solvent in liquid membrane transport: Equilibrium and kinetic study

Vikas Kumar, Raghubansh K. Singh, and Pradip Chowdhury^†

Department of Chemical Engineering, National Institution of Technology Rourkela, Rourkela 769008, Odisha, India

E-mail:

This work highlights extraction and removal of Lignosulfonate using sunflower oil-Tri-n-octylamine (TOA) system in bulk liquid membrane transport. Maximum extraction and recovery percentages of 92.4% and 75.2% were achieved. Optimum manifold operating conditions were: 4 vol.% TOA, 2±0.1 feed phase pH, 300 rpm stirring speed, at 40 °C with 0.2 (M) Na2SO4 solution. 1:2 (organic/aqueous) and 1:1 (aqueous/aqueous) phase ratios produced best results. Extraction (36.85 kJ/mol) was found to be intermediate controlled and stripping (54.79 kJ/mol) was chemical reaction controlled. Kinetic estimation of data with higher rate constants for stripping vis-a-vis extraction showed latter to be rate determining.

Keywords:Lignosulfonate;Sunflower oil;Tri-n-octylamine;Bulk liquid membrane;Transport kinetics

[References]

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Norgren M, Edlund H, Curr. Opin. Colloid Interface Sci., 19, 409 (2014)
Ouyang XP, Zhang P, Qiu XQ, Deng YH, Chen P, Ind. Eng. Chem. Res., 50(18), 10792 (2011)
Wang M, Leitch M, Xu CC, Eur. Polym. J., 45, 3380 (2009)
Ghaffar SH, Fan M, Int. J. Adhes. Adhes., 48, 92 (2014)
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Matsushita Y, Yasuda S, Bioresour. Technol., 96(4), 465 (2005)
Qian Y, Qiu X, Zhu S, Green Chem., 17, 320 (2015)
Ouyang X, Qiu X, Chen P, Colloids Surf. A: Physicochem. Eng. Asp., 282-283, 489 (2006)
Telysheva G, Dizhbite T, Paegle E, Shapatin A, Demidov I, J. Appl. Polym. Sci., 82(4), 1013 (2001)
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[1] Konowała E, Modrzejewska-Sikorskaa A, Motylenkob M, Klapiszewskic L, Wysokowskic M, Bazhenovd VV, Rafajab D, Ehrlichd H, Milczareka G, Jesionowskic T, Int. J. Biol. Macromol., 85, 74 (2016)

[2] Garcia A, Toledano A, Serrano L, Egues I, Gonzalez M, Marin F, Labidi J, Sep. Purif. Technol., 68(2), 193 (2009)

[3] Norgren M, Edlund H, Curr. Opin. Colloid Interface Sci., 19, 409 (2014)

[4] Ouyang XP, Zhang P, Qiu XQ, Deng YH, Chen P, Ind. Eng. Chem. Res., 50(18), 10792 (2011)

[5] Wang M, Leitch M, Xu CC, Eur. Polym. J., 45, 3380 (2009)

[6] Ghaffar SH, Fan M, Int. J. Adhes. Adhes., 48, 92 (2014)

[7] Feldman D, Lacasse M, Beznaczuk L, Prog. Polym. Sci, 12, 271 (1986)

[8] Matsushita Y, Yasuda S, Bioresour. Technol., 96(4), 465 (2005)

[9] Qian Y, Qiu X, Zhu S, Green Chem., 17, 320 (2015)

[10] Ouyang X, Qiu X, Chen P, Colloids Surf. A: Physicochem. Eng. Asp., 282-283, 489 (2006)

[11] Telysheva G, Dizhbite T, Paegle E, Shapatin A, Demidov I, J. Appl. Polym. Sci., 82(4), 1013 (2001)

[12] Alonso MV, Oliet M, Rodriguez F, Astarloa G, Echeverria JM, J. Appl. Polym. Sci., 94(2), 643 (2004)

[13] Chiwetelu CI, Hornof V, Neale GH, George AE, Can. J. Chem. Eng., 72(3), 534 (1994)

[14] Ansari A, Pawlik M, Miner. Eng., 20(6), 600 (2007)

[15] Konował E, Modrzejewska-Sikorska A, Milczarek G, Mater. Lett., 159, 451 (2015)

[16] Modrzejewska-Sikorskaa A, Konowała E, Klapiszewskib L, Nowaczykc G, Jurgac S, Jesionowskib T, Milczareka G, Int. J. Biol. Macromol., 103, 403 (2017)

[17] Milczarek G, Motylenko M, Modrzejewska-Sikorska A, Klapiszewski L, Wysokowski M, Bazhenov VV, Piasecki A, Konował E, Ehrlich H, Jesionowski T, RSC Adv., 4, 52476 (2014)

[18] Evstigneyev E, Shevchenko S, Mayorova H, Platonow A, J. Wood Chem. Technol., 24, 263 (2004)

[19] Vainio U, Lauten RA, Serimaa R, Langmuir, 24(15), 7735 (2008)

[20] Lin SY, in: Methods in Lignin Chemistry, Springer-Verlag Berlin Heidelberg, pp.75 1992.

[21] Kontturi AK, Sundholm G, Acta Chem. Scand. Ser. A, 40, 121 (1986)

[22] Ringena O, Saake B, Lehnen R, Holzforschung, 59, 405 (2005)

[23] Marques APE, Evtuguin DV, Magina S, Amado FML, Prates A, J. Wood Chem. Technol., 29(4), 337 (2009)

[24] Grigg RB, Bai BJ, J. Colloid Interface Sci., 279(1), 36 (2004)

[25] Pranovich AV, Reunanen M, Sjoholm R, Holmbom B, J. Wood Chem. Technol., 25, 109 (2005)

[26] Sumerskii I, Korntner P, Zinovyev G, Rosenau T, Potthast A, RSC Adv., 5, 92732 (2015)

[27] Chakrabarty K, Krishna KV, Saha P, Ghoshal AK, J. Membr. Sci., 330(1-2), 135 (2009)

[28] Chakrabarty K, Saha P, Ghoshal AK, J. Membr. Sci., 340(1-2), 84 (2009)

[29] Chakrabarty K, Saha P, Ghoshal AK, J. Membr. Sci., 360(1-2), 34 (2010)

[30] Kontturi AK, Kontturi K, Niinikoski P, Sundholm G, Nielsen M, Lehmann MS, Acta Chem. Scand. A, 44, 883 (1990)

[31] Muthuraman G, Ibrahim M, J. Ind. Eng. Chem., 19(2), 444 (2013)

[32] Muthuraman G, Teng TT, Leh CP, Norli I, Desalination, 249(2), 884 (2009)

[33] Chang SH, Teng TT, Norli I, Chem. Eng. J., 173(2), 352 (2011)

[34] Madaeni SS, Jamali Z, Islami N, Sep. Purif. Technol., 81(2), 116 (2011)

[35] Klapiszewski L, Zdarta J, Szatkowski T, Wysokowski M, Nowacka M, Szwarc-Rzepka K, Bartczak P, Siwinska-Stefanska K, Ehrlich H, Jesionowski T, Cent. Eur. J. Chem., 12(6), 719 (2014)

[36] Qian Y, Deng Y, Yi C, Yu H, Qiu X, BioRes, 6, 4686 (2011)

[37] Gorgenyi M, Dewulf J, Langenhove HV, Heberger K, Chemosphere, 65, 802 (2006)