Journal of Industrial and Engineering Chemistry, Vol.57, 28-36, January, 2018
Sustainable super fast adsorptive removal of Congo red dye from water by a novel technique based on microwave-enforced sorption process
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Removal of Congo red was completed in 5.20 s using microwave-enforced sorption (MES) as a sustainable technique. Nano-γ-Al2O3 was covalently bonded with 3-chloropropyltrimethoxysilane to produce γ-Al2O3-SiCl nanosorbent via microwave-assisted approach. Congo red extraction by γ-Al2O3 and γ-Al2O3-SiCl were found 58.42% and 69.41% and increased to 66.13% and 81.47%, respectively using 5 and 20 s of microwave heating. The percentage extraction of Congo red (30 mg L-1) by γ-Al2O3-SiCl was increased from 46.21% to 83.61% upon increasing the pH from 1.0 to 10.0. Other controlling conditions were investigated and optimized. Excellent recovery of Congo red from wastewater was established in 20 s.
Keywords:γ-Al2O3 nanoparticles;γ-Al2O3-SiCl nanosorbent;Congo red dye;MES-technique;Super fast removal
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