화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.26, 234-242, June, 2015
DOI10.1016/j.jiec.2014.11.035  Export Citation
Synthesis, characterization and adsorptive application of ferrocene based mesoporous material for hazardous dye Congo red
Sumanjit Kaur1, Seema Rani1, Vipin Kumar1, R.K. Mahajan1, Mohammad Asif2, Inderjeet Tyagi3, and Vinod Kumar Gupta3, 4, †
  • 1Department of Chemistry, Guru Nanak Dev University, Amritsar 143005, India
  • 2Department of Chemical Engineering, King Saud University, Riyadh, Riyadh, Saudi Arabia
  • 3Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India
  • 4King Fahd University of Petroleum and Minerals Dhahran, India
E-mail:
Mesoporous adsorbent is prepared first time using ferrocene based surfactant as a template and adsorption of azo dye Congo red is investigated. Adsorbent is characterized by Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, dynamic light scattering and N2 adsorption?desorption and deduced a lofty surface area of 342 m2/g. Effect of contact time, adsorbent dose, initial dye concentration and temperature were speculated to optimize adsorption conditions. Experimental data were contemplated for various kinetics and thermodynamic models at different temperatures and insinuated that adsorption process is film diffusion controlled and followed second order kinetics. Langmuir model imparted high value of monolayer capacity as 312.5 mg/g. The values of thermodynamic parameters like enthalpy (ΔH) and entropy (ΔS) were found to be 49.94 kJ/mol and 265.5 J/K/mol, respectively, and negative values of ΔG corroborated that the present adsorption system is feasible, spontaneous and endothermic.
Keywords:Mesoporous material;Congo red;Kinetics;Isotherm;Adsorption
  1. Vartuli JC, Schmitt KD, Kresge CT, Roth WJ, Leonowicz ME, McCullen SB, Hellring SD, Beck JS, Schlenker JL, Olson DH, Sheppard EW, Chem. Mater., 6, 2317 (1994)
  2. Biz S, Occelli ML, Catal. Rev.-Sci. Eng., 40(3), 329 (1998)
  3. Hao T, Yang C, Rao XH, Wang JD, Niu CG, Su XT, Appl. Surf. Sci., 292, 174 (2014)
  4. Savina IN, English CJ, Whitby RLD, Zheng YS, Leistner A, Mikhalovsky SV, Cundy AB, J. Hazard. Mater., 192(3), 1002 (2011)
  5. Dong Y, Lin H, Jin Q, Li L, Wang D, Zhou D, Qu F, J. Mater. Chem., 1, 7391 (2013)
  6. Wang S, Tian L, Stud. Surf. Sci. Catal., 165, 227 (2007)
  7. Wang S, Li HT, Microporous Mesoporous Mater., 97, 21 (2006)
  8. Menger FM, Gan LH, Johnson E, Durst DH, J. Am. Chem. Soc., 109, 2800 (1987)
  9. Bunton CA, Scrimin P, Tecilla PJ, J. Chem. Soc.-Perkin Trans. 2, 419 (1995)
  10. Hafiz AA, J. Surfactants Deterg., 8, 359 (2005)
  11. Hafiz AA, Badawi AM, El-Dee FI, Soliman EA, El-Awady MY, Mohamed DE, J. Surfactants Deterg., 13, 165 (2010)
  12. Kealey TJ, Pauson PL, Nature, 168, 1039 (1951)
  13. Kwon EJ, Lee TG, Appl. Surf. Sci., 254(15), 4732 (2008)
  14. Burri DR, Shaikh IR, Choi KM, Park SE, Catal. Commun., 8, 731 (2007)
  15. Delacote C, Bouillon JP, Walcarius A, Electrochim. Acta, 51(28), 6373 (2006)
  16. Stepnicka P, Demel J, Cejka J, J. Mol. Catal. A-Chem., 224(1-2), 161 (2004)
  17. Li L, Shi JL, Yan JN, Zhao XG, Chen HG, Appl. Catal. A: Gen., 263(2), 213 (2004)
  18. Saratale RG, Saratale GD, Chang JS, Govindwar SP, J. Taiwan Inst. Chem. Eng., 42, 138 (2011)
  19. Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 343(2), 463 (2010)
  20. Debnath S, Maity A, Pillay K, J. Environ. Chem. Eng., 2, 260 (2014)
  21. Gupta VK, Ali I, Saleh TA, Nayak A, Agarwal S, RSC Adv., 2, 6380 (2012)
  22. Calogero F, Freeman HS, Esancy JF, Whaley WM, Dabney BJ, Dyes Pigment., 8(6), 431 (1987)
  23. Lednicer D, Hauser CR, Mckusick BC, Sheppard WA, Vest RD, Mower HF, Org. Synth. Coll., 5, 434 (1973)
  24. Dannenberg JJ, Levnnnerg MK, Richards JH, Tetrahedron, 29, 1575 (1973)
  25. Adam F, Balakrishnan S, Wong PL, J. Phys. Sci., 17(2), 1 (2006)
  26. Anbia M, Salehi S, Dyes Pigment., 94, 1 (2012)
  27. Wang L, Li J, Wang Y, Zhao L, Jiang Q, Chem. Eng. J., 181-182, 72 (2012)
  28. Ho YS, Chiang TH, Hsueh YM, Process Biochem., 40, 119 (2005)
  29. Dogan M, Alkan M, Demirbas O, Ozdemir Y, Ozmetin C, Chem. Eng. J., 124(1-3), 89 (2006)
  30. Dogan M, Abak H, Alkan M, J. Hazard. Mater., 164(1), 172 (2009)
  31. Chen H, Zhao J, Adsorption, 15, 381 (2009)
  32. Wang L, Wang AQ, J. Hazard. Mater., 160(1), 173 (2008)
  33. Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civil Eng., 89, 31 (1963)
  34. Ho YS, Water Res., 37(10), 2323 (2003)
  35. Gercel O, Ozcan A, Ozcan AS, Gercel HF, Appl. Surf. Sci., 253(11), 4843 (2007)
  36. Wu FC, Tseng RI, Jung RS, Water Res., 35, 613 (2001)
  37. Tan IAW, Ahmad AL, Hameed BH, J. Hazard. Mater., 164(2-3), 473 (2009)
  38. Boyd GE, Adamson AW, Meyers LS, J. Am. Chem. Soc., 69, 2836 (1947)
  39. Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 340(1), 16 (2009)
  40. Wang SB, Li H, Xu LY, J. Colloid Interface Sci., 295(1), 71 (2006)
  41. Gunay A, Arslankaya E, Tosun I, J. Hazard. Mater., 146(1-2), 362 (2007)
  42. Hamdaoui O, Chiha M, Acta Chim. Slov., 54, 407 (2007)
  43. Bangham DH, Burt FP, Proc. R. Soc. London, Ser. A.Containing Papers A Math., 105(732), 481 (1924)
  44. Tutem E, Apak R, Unal CF, Water Res., 32, 2315 (1998)
  45. Aksu Z, Tezer S, Process Biochem., 36, 431 (2000)
  46. Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
  47. Wang L, Li J, Wang Z, Zhao L, Jiang Q, J. Chem. Soc.-Dalton Trans., 42, 2572 (2013)
  48. Afkhami A, Moosavi R, J. Hazard. Mater., 174(1-3), 398 (2010)
  49. Wei Z, Xing R, Zhang X, Liu S, Yu H, Li P, Appl. Mater. Interface, 5, 598 (2013)
  50. Yu M, Zhao S, Wu H, Asuha S, J. Porous Mat., 20, 1353 (2013)
  51. Rahimi R, Kerdari H, Rabbani M, Shafiee M, Desalination, 280(1-3), 412 (2011)
  52. Cheng B, Le Y, Cai WQ, Yu JG, J. Hazard. Mater., 185(2-3), 889 (2011)
  53. Giri SK, Das NN, Pradhan GC, Colloids Surf. A: Physicochem. Eng. Asp., 389, 43 (2011)
  54. Yao YJ, Miao SD, Liu SZ, Ma LP, Sun HQ, Wang SB, Chem. Eng. J., 184, 326 (2012)
  55. Zhang P, Ma X, Guo Y, Cheng Q, Yang L, Chem. Eng. J., 189-190, 188 (2012)
  56. Zhai T, Xie S, Lu X, Xiang L, Yu M, Li W, Liang C, Mo C, Zeng F, Luan T, Tong Y, Langmuir, 28, 11078 (2012)
  57. Wang LX, Li JC, Wang YQ, Zhao LJ, J. Hazard. Mater., 196, 342 (2011)
  58. Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212 (1966)
  59. Dubinin MM, Radushkevich LV, Proc. Acad. Sci. USSR Phys. Chem. Sect., 55, 331 (1947)
  60. Akar T, Tosun I, Kaynak Z, Kavas E, Incirkus G, Akar ST, J. Hazard. Mater., 171(1-3), 865 (2009)
  61. Uluozlu OD, Sari A, Tuzen M, Soylak M, Bioresour. Technol., 99, 2971 (2008)
  62. Temkin MI, Pyzhev V, Acta Physiochim. URSS, 12, 327 (1940)
  63. Kim Y, Kim C, Choi I, Rengraj S, Yi J, Environ. Sci. Technol., 38, 924 (2004)
  64. Gercel O, Gercel HF, Koparal AS, Ogutveren UB, J. Hazard. Mater., 160(2-3), 668 (2008)
  65. Koopal LK, Van Riemsdijk WH, Kinniburgh DG, Pure Appl. Chem., 73, 2005 (2001)
  66. Gupta VK, Jain R, Mittal A, Agarwal S, Sikarwar S, Mater. Sci. Eng., 32, 12 (2012)
  67. Saleh TA, Gupta VK, Environ. Sci. Pollut. Res., 19, 1224 (2012)
  68. Gupta VK, Srivastava SK, Mohan D, Sharma S, Waste Manage., 17, 517 (1998)
  69. Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 342(2), 518 (2010)
  70. Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK, J. Colloid Interface Sci., 337(2), 345 (2009)
  71. Goal RN, Gupta VK, Chatterjee S, Talanta, 76, 662 (2008)
  72. Gupta VK, Agarwal S, Saleh TA, J. Hazard. Mater., 185, 17 (2011)
  73. Gupta VK, Ganjali MR, Norouzi P, Khani H, Nayak A, Agarwal S, Crit. Rev. Anal. Chem., 41, 282 (2011)
  74. Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 344(2), 497 (2010)
  75. Gupta VK, Jain R, Agarwal S, Shrivastava M, Mater. Sci. Eng., 31, 1062 (2011)
  76. Gupta VK, Nayak A, Chem. Eng. J., 180, 81 (2012)
  77. Saleh TA, Gupta VK, J. Colloid Interface Sci., 371, 101 (2012)
  78. Khani H, Rofouei MK, Arab P, Gupta VK, Vafaei Z, J. Hazard. Mater., 183(1-3), 402 (2010)
  79. Jain R, Gupta VK, Jadon N, Radhapyari K, Anal. Biochem., 407, 79 (2010)
  80. Gupta VK, Prasad R, Mangla R, Kumar P, Anal. Chim. Acta, 420, 19 (2000)