화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.54, 369-376, October, 2017
DOI10.1016/j.jiec.2017.06.017  Export Citation
A simple preparation method for rare-earth phosphate nano materials using an ionic liquid-driven supported liquid membrane system
Panpan Zhao1, 2, Fan Yang1, 2, †, Zhigang Zhao1, 2, Qiuxiao Liao1, 2, Yang Zhang1, 2, Peng Chen1, 2, Wanghuan Guo1, 2, and Ruixi Bai1, 2
  • 1Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, No.1300 Jimei Road, Jimei, Xiamen, Fujian, 361021, China
  • 2Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, Fujian, 350002, China
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For the first time, our group has developed a novel, high-flux strategy for shape-controlled synthesis of rare earth nano-materials (CePO4) using ionic liquid(IL)-driven supported liquid membrane (HVHP, DUPAPORE1) system. The system contains three phases including a supply phase of rare earth ions, a feed phase of phosphates, and ionic liquid-driven supporting liquid membrane phase. The imidazolium IL-driven supported liquid membrane is promising for nano-synthetic reaction of CePO4. The anion types of immersed imidazolium IL have a critical role in the formation rate of CePO4 nano materials. Moreover, the adding SO4 2- anion or adjustment of pH in supply phase containing Ce(III) ions could control effectively the morphology of the CePO4 nano-materials. The result can be regarded as a good example, the IL:[C4mim][Tf2N] -driven support liquid membrane systems can be used to prepare nano-wire and nano-sphere structures of CePO4 with high efficiency and flux. Besides, the IL-driven supported liquid membrane can be cycled many times by using the back flush activation method.
Keywords:Rare earth nano-material;Ionic liquid;Supported liquid membrane;Membrane nano-reaction;Hydrophobic HVHP
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