Morphology-controllable 3D flower-like TiO2 for UV shielding application

Yawen Wang; Zunli Mo; Chun Zhang; Ping Zhang; Ruibin Guo; Hao Gou; Rere Hu; Xiaojiao Wei

Journal of Industrial and Engineering Chemistry, Vol.32, 172-177, December, 2015

DOI10.1016/j.jiec.2015.08.013 Export Citation

Morphology-controllable 3D flower-like TiO2 for UV shielding application

Yawen Wang¹, Zunli Mo^{1, †}, Chun Zhang^{1, 2}, Ping Zhang¹, Ruibin Guo¹, Hao Gou¹, Rere Hu¹, and Xiaojiao Wei¹

¹Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, PR China
²College of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, PR China

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Calliandra like rutile TiO2 hierarchical microspheres with different diameters were successfully prepared by hydrothermal method via altering reaction time. All these as synthesized unique hierarchical microspheres displayed higher UV shielding capability compared with commercial P25 and anatase TiO2. Noticeably, the UV shielding efficiency of these microspheres had a close relation to their diameters and packing density of constituted nanorods. The S-24h-C sample exhibited the highest UV shielding efficiency, which could not only block all UV light below 400 nm but also show poor photocatalytic activity under UV light radiation, indicating its great applied potential in UV-blocking materials.

Keywords:UV shielding;Rutile TiO2;Three-dimensional structure;Morphologic control

[References]

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[Referenced By]

[1] Moan J, Porojnicu AC, Dahlback A, Setlow RB, PNAS, 105, 668 (2008)

[2] Hader DP, Helbling EW, Williamsonc CE, Worrestd RC, Photochem. Photobiol. Sci., 10, 242 (2011)

[3] Andrady AL, Hamid HS, Torikaic A, Photochem. Photobiol. Sci., 2, 68 (2003)

[4] Lin SW, Wheeler DC, Park Y, Cahoon EK, Hollenbeck AR, Freedman DM, Abnet CC, Int. J. Cancer, 131, 1015 (2012)

[5] Hammond BR, Johnson BA, George ER, Exp. Eye Res., 129, 135 (2014)

[6] Mori Y, Honda T, Lu R, Hayakawa N, Miyakoshi T, Polym. Degrad. Stabil., 114, 30 (2015)

[7] Celina MC, Polym. Degrad. Stabil., 98, 2419 (2013)

[8] Cockelol CS, Knowland J, Biol. Rev., 74, 311 (1999)

[9] De Lima JF, Serra OA, Dyes Pigment., 97, 291 (2013)

[10] Nallis K, Katsumata K, Isobe T, Okada K, Bone P, Othman R, Appl. Clay Sci., 80-81, 147 (2013)

[11] Clemente Z, Castro V, Moura MAM, Jonssona CM, Fraceto LF, Aquat. Toxicol., 147, 129 (2014)

[12] Du JZ, Sun H, ACS Appl. Mater. Interfaces, 6, 13535 (2014)

[13] Xiao J, Chen WQ, Wang FYK, Du JZ, Macromolecules, 46(2), 375 (2013)

[14] Chung KH, Jung HY, Lee YW, Lee KY, J. Ind. Eng. Chem., 16(2), 261 (2010)

[15] Singhal A, Dubey KA, Bhardwaj YK, Jain D, Choudhury S, Tyagi AK, RSC Adv., 3, 20913 (2013)

[16] Wang XL, Zhou SX, Wu LM, J. Mater. Chem. C, 2, 5752 (2014)

[17] Livraghi S, Corazzari I, Paganini MC, Ceccone G, Giamello E, Fubini B, Fenoglio I, Chem. Commun., 46, 8478 (2010)

[18] Man Y, Mu LY, Wang Y, Lin SH, Rempel GL, Pan QM, Polym. Compos., 1, 8 (2015)

[19] Yang W, Wan F, Wang Y, Jiang C, Appl. Phys. Lett., 95, 133121 (2009)

[20] Zhang JF, Zhou P, Liu JQ, Yu JG, Phys. Chem. Chem. Phys., 16, 20382 (2014)

[21] Veres A, Menesi J, Janaky C, Samu GF, Scheyer MK, Xu Q, Salahioglu F, Garland MV, Dekany I, Zhong Z, RSC Adv., 5, 2421 (2015)

[22] Luttrell T, Halpegamage S, Tao J, Kramer A, Sutter E, Batzill M, Sci. Rep., 4, 4043 (2014)

[23] Zhao PS, Song J, Zhou SS, Zhu Y, Jing L, Guo ZY, Mater. Res. Bull., 48(11), 4476 (2013)

[24] Kempaiah DM, Yin S, Sato T, Cryst. Eng. Comm., 13, 741 (2011)

[25] Yin H, Casey PS, Mater. Lett., 121, 8 (2014)

[26] Kwon HJ, Lee YW, Kim HS, Zhoh CK, Park KW, Mater. Lett., 93, 175 (2013)

[27] Huang JY, Li SH, Ge MZ, Wang LN, Xing TL, Chen GQ, Liu XF, et al., J. Mater. Chem. A, 3, 2825 (2015)

[28] Zhu TJ, Li J, Wu QS, ACS Appl. Mater. Interfaces, 3, 3448 (2011)

[29] Mali SS, Kim HJ, Shim CS, Patil PS, Kim JH, Hong CK, Sci. Rep., 3, 3004 (2013)

[30] Ziaei-Azad H, Semagina N, Appl. Catal. A: Gen., 482, 327 (2014)

[31] Xiao L, Cao ML, Mei DD, Guo YL, Yao LF, Qu DY, Deng BH, J. Power Sources, 238, 197 (2013)

[32] Sun ZQ, Kim JH, Zhao Y, Attard D, Doua SX, Chem. Commun., 49, 966 (2013)

[33] Xian JY, Hua Q, Jiang ZQ, Ma YS, Huang WX, Langmuir, 28(17), 6736 (2012)

[34] Bae E, Ohno T, Appl. Catal. B: Environ., 91(3-4), 634 (2009)

[35] Tang Y, He W, Wang SX, Tao ZH, Cheng LJ, Cryst. Eng. Comm., 16, 4431 (2014)

[36] Humphrey SM, Grass ME, Habas SE, Niesz K, Somorjai GA, Tilley TD, Nano Lett., 7, 785 (2007)

[37] Nie D, Xu CJ, Chen HY, Wang YJ, Li JW, Liu YQ, Mater. Lett., 131, 306 (2014)

[38] Subramaniam MR, Devanathan S, Kumaresan D, RSC Adv., 4, 36791 (2014)

[39] Song HM, Guo LQ, Liu ZJ, Liu K, Zeng X, Ji DX, Zhang N, Hu HF, Jiang SH, Gan QQ, Adv. Mater., 26(17), 2737 (2014)

[40] Ge SX, Wang BB, Li DP, Fa WJ, Yang ZY, Yang Z, Jia GY, Zheng Z, Appl. Surf. Sci., 295, 123 (2014)