화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.27, 245-250, July, 2015
DOI10.1016/j.jiec.2014.12.041  Export Citation
Simultaneous ICP-OES determination of trace metals in water and food samples after their preconcentration on silica gel functionalized with N-(2-aminoethyl)-2,3-dihydroxybenzaldimine
Esra Durduran, Huseyin Altundag†, Mustafa Imamoglu, Salih Zeki Yıldız, and Mustafa Tuzen1
  • Faculty of Sciences and Arts, Department of Chemistry, Sakarya University, 54187 Sakarya, Turkey
  • 1Department of Chemistry, Faculty of Sciences and Arts, Gaziosmanpasa University, 60250 Tokat, Turkey
E-mail:
Silica gel was functionalized with N-(2-aminoethyl)-2,3-dihydroxybenzaldimine group (AEDHB-SG) and characterized by elemental analysis and FT-IR spectroscopy. Preconcentration conditions of Cd(II), Cu(II), Ni(II) and Pb(II) were investigated on the AEDHB-SG loaded column using a solid phase extraction technique. The effects of parameters such as the pH, sample volume, flow rates, matrix ions were examined. Adsorption capacity of AEDHB-SG for Cd(II), Cu(II), Ni(II) and Pb(II) was 0.40, 0.56, 0.50 and 0.23 mmol g-1. The accuracy of the developed method was confirmed by certified reference materials. Optimized method was applied to water and food samples for the determination of trace metals using ICP-OES.
Keywords:Preconcentration;Modified silica gel;Trace metals;ICP-OES;Water and food samples
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