화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Chemical Engineering Research, Vol.55, No.2, 264-269, April, 2017
DOI10.9713/kcer.2017.55.2.264  Export Citation
무전해 구리도금 된 흑연 섬유의 발열 특성
Thermal Heating Characteristics of Electroless Cu-Plated Graphite Fibers
이경민, 김민지, 이상민, 여상영1, 이영석†
  • 충남대학교 공과대학 응용화학공학과, 34134 대전광역시 유성구 궁동 220
  • 1한국생산기술연구원, 15588 경기도 안산시 상록구 항가울로 143
Kyeong Min Lee, Min-Ji Kim, Sangmin Lee, Sang Young Yeo1, and Young-Seak Lee†
  • Department of Chemical Engineering and Applied Chemistry, Chungnam National University, 220, Gung-dong, Yuseong-gu, Daejeon, 34134, Korea
  • 1Korea Institute of Industrial Technology (KITECH), 143, Hanggaul-ro, Sangnok-gu, Ansan-si, Gyeonggi, 15588, Korea
E-mail:
초록
피치계 흑연섬유의 발열특성을 향상시키기 위하여 흑연섬유에 무전해법을 이용하여 구리 도금하였다. 구리 도금된 흑연섬유는 공기 분위기에서 열중량분석법을 실시하여 도금 시간에 따라 흑연섬유 표면에 구리가 도입된 양을 계산하였다. 또한, 전압에 따른 발열 온도는 섬유 가닥을 이용하여 열화상카메라로 관찰하였다. 무전해 도금의 시간이 증가함에 따라 도입된 구리의 양은 증가하였다. 20분 동안 무전해 도금한 섬유의 전기 전도도는 1594.3 S/cm이며, 발열 온도는 최대 57.2 °C로 가장 크게 나타났다. 이러한 결과는 도금시간이 증가함에 따라 전기 전도성이 우수한 구리가 흑연섬유 표면에 성장하고, 이에 따라 발열특성이 향상된 것으로 판단된다.
To improve heating characteristics of graphite fibers, graphite fibers were copper-plated by electroless plating. The Cu-plated graphite fibers were investigated by thermos-gravimetric analysis in air to calculate quantities of copper on surface of graphite fiber according to plating time. Also, the surface temperature with applied voltage was observed by thermos-graphic camera using a strand of graphite fiber. According to the increment of plating time, the higher quantities of plated copper on graphite fiber were obtained. The electric conductivity of plated graphite fiber for 20 minutes was resulted in 1594.3 S/cm, and surface temperature of this sample showed the maximum temperature 57.2 °C. These result could be attributed that copper having great electric conductivity are growing on graphite fiber and followed improving heating characteristics.
Keywords:Electroless plating;Graphite fibers;Surface morphology;Heat characteristics
  1. Fosbury A, Wang S, Pin YF, Chung DDL, Compos. Pt. A-Appl. Sci. Manuf., 34, 933 (2003)
  2. Jung MJ, Park MS, Lee S, Lee YS, Appl. Chem. Eng., 27(3), 319 (2016)
  3. Carrillo-Escalante HJ, Alvarez-Castillo A, Valadez-Gonzalez A, Herrera-Franco PJ, Carbon Lett., 19, 47 (2016)
  4. Chu K, Yun DJ, Kim D, Park H, Park SH, Org. Electron., 15, 2734 (2014)
  5. Kim M, Kong K, Kim N, Park HW, Park O, Park YB, Jung M, Lee SH, Kim SG, Compo. Res., 27, 72 (2013)
  6. Jee MH, Lee JH, Lee IS, Baik DG, Text. Sci. Eng., 50, 108 (2013)
  7. Pyo D, Eom S, Lee YS, Ryu S, Korean Chem. Eng. Res., 49(2), 218 (2011)
  8. Kim BJ, Choi WK, Song HS, Park JK, Lee JY, Park SJ, Carbon Lett., 9, 105 (2008)
  9. Kim BJ, Choi WK, Um MK, Park SJ, Surf. Coat. Technol., 205, 3416 (2011)
  10. Xu C, Liu G, Chen H, Zhou R, Liu Y, J. Mater. Sci. -Mater. Electron., 25, 2611 (2014)
  11. Rathmell AR, Wiley BJ, Adv. Mater., 23(41), 4798 (2011)
  12. Kim MJ, Kim JJ, Korean Chem. Eng. Res., 52(1), 26 (2014)
  13. Kim HC, Kim JJ, Korean Chem. Eng. Res., 54(6), 723 (2016)
  14. Yousef A, El-Halwany MM, Barakat NAM, Al-Maghrabi MN, Kim HY, J. Ind. Eng. Chem., 26, 251 (2015)
  15. Kim DY, Yun KJ, Lee YS, Appl. Chem. Eng., 25(3), 268 (2014)
  16. Choi JR, Rhee KY, Park SJ, J. Ind. Eng. Chem., 31, 47 (2015)
  17. Yoon HS, Oh JH, Lee HK, Jeon JK, Ryu SK, Korean Chem. Eng. Res., 46(5), 863 (2008)
  18. Oh KH, Text. Sci. Eng., 38, 309 (2001)
  19. Kim YS, Shin J, Kim HI, Cho JH, Seo HK, Kim GS, Shin HS, Korean Chem. Eng. Res., 43(4), 495 (2005)
  20. Yamamoto Y, Akiyama H, Ooka K, Yamamura K, Oshikane Y, Zettsu N, Curr. Appl. Phys., 12, S63 (2012)
  21. Chong SP, Ee YC, Chen Z, Law SB, Surf. Coat. Technol., 198, 287 (2005)
  22. Ng HT, Li SFY, Chan L, Loh FC, Tan KL, J. Electrochem. Soc., 145(9), 3301 (1998)
  23. Xueping G, Yating W, Lei L, Bin S, Wenbin H, Surf. Coat. Technol., 201, 7018 (2007)
  24. Li J, Hayden H, Kohl PA, Electrochim. Acta, 49(11), 1789 (2004)
  25. Touir R, Larhzil H, Ebntouhami M, Cherkaoui M, Chassaing E, J. Appl. Electrochem., 36(1), 69 (2006)
  26. Li J, Kohl PA, J. Electrochem. Soc., 149(12), C631 (2002)
  27. Tian F, Li HP, Zhao NQ, He CN, Mater. Chem. Phys., 115(2-3), 493 (2009)
  28. Lu W, Donepudi VS, Prakash J, Liu J, Amine K, Electrochim. Acta, 47(10), 1601 (2002)
  29. Chien AT, Cho S, Joshi Y, Kumar S, Polymer, 585, 6895 (2014)
  30. Oya N, Johnson DJ, Carbon, 39, 635 (2001)
  31. Choi KE, Park CH, Seo MK, Appl. Chem. Eng., 27(2), 210 (2016)