화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.48, 212-223, April, 2017
DOI10.1016/j.jiec.2017.01.004  Export Citation
Effect of shear processing on the linear viscoelastic behaviour and microstructure of bitumen/montmorillonite/MDI ternary composites
Francisco J. Ortega, Francisco J. Navarro†, Moisés García-Morales, and Tony McNally1
  • Departamento de Ingeniería Química, Centro de Investigación en Tecnología de Productos y Procesos Químicos (Pro2TecS), Campus de ‘El Carmen’, Universidad de Huelva, 21071, Huelva, Spain
  • 1International Institute for Nanocomposites Manufacturing (IINM), WMG, University of Warwick, CV4 7AL, Coventry, United Kingdom, UK
E-mail:
Polymer modified bitumens (PMBs) have largely been utilized as a construction material. However, lack of affinity between bitumen and polymer leads to phase separation, and eventually, performance depletion. In this paper, alternative formulations of bitumen with an organically-modified montmorillonite (OMMT) Cloisite 20A® and polymeric methylene diphenyl diisocyanate (MDI) were prepared by melt blending. Their comprehensive rheological characterisation evidenced improved linear viscoelastic properties when OMMT is added, revealing a noticeable structural reinforcement and thermal stability. Rheological data also showed that MDI-involved reactions control the composite end properties, being greatly influenced by the shear conditions applied.
Keywords:Bitumen;Nanoclay;Isocyanate;Shear processing;Composite
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