화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.2, 704-711, March, 2013
DOI10.1016/j.jiec.2012.10.025  Export Citation
Effects of MDI-PPG molecular weight on the thermorheological behaviour of MDI-isocyanate based bituminous foams
M.A. Izquierdo, F.J. Navarro†, F.J. Martı´nez-Boza, and C. Gallegos
  • Departamento de Ingenierı´a Quı´mica, Facultad de Ciencias Experimentales, Universidad de Huelva, Campus de El Carmen, 21071 Huelva, Spain
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Dimensionally stable bituminous foams were prepared by using 4,4'-diphenylmethane diisocyanate/ polypropylene glycol (MDI-PPG) quasi-prepolymers, with different molecular weights. From the results obtained, it may be concluded that, after foam formation, the rheological properties are remarkably affected, especially at high temperatures. Paradoxically, the greater the molecular weight of MDI-PPG, the lower the values of viscosities at 60 ℃, and the linear viscoelasticity functions of the resulting foams. This result seems to be related to the improved ability of small MDI-PPG molecules to interact strongly with polar bitumen compounds, leading to the formation of larger molecular-sized compounds.
Keywords:Bituminous foam;Isocyanate;Rheology;Viscosity;Polymer molecular weight
  1. Izquierdo MA, Navarro FJ, Martı´nez-Boza FJ, Gallegos C, Construction and Building Materials., 30, 706 (2012)
  2. Malmquist AB, Kiik M, Thick shingle. United States Patent, 5305569 (1994)
  3. Kumasaka S, Tada S, Katsuki K, Nagamine R, Tanaguchi H, Asphalt impregnated foam and method of producing the same, United States Patent, 4610922 (1986)
  4. Manufacturas Jose Jover, Procedimiento para la obtencio´n de expandidos poliuretanicos rı´gidos. ES 375769 (1972)
  5. Tzeng CG, Thagard GF, Method of making rigid asphaltic foam, United Sates Patent, 5965626 (1999)
  6. Gonza´ lez O, Munoz ME, Santamarı´a A, Garcı´a-Morales M, Navarro FJ, Partal P, European Polymer Journal., 40, 2365 (2004)
  7. Robinson HL, Polymers in asphalt, Rapra Review Reports., 15(11) (2004)
  8. Martı´n-Alfonso MJ, Partal P, Navarro FJ, Garcı´a-Morales M, Gallegos C, European Polymer Journal., 44, 1451 (2008)
  9. Masson JF, Pelletier L, Collins P, J. Appl. Polym. Sci., 79(6), 1034 (2001)
  10. Newman JK, Journal of Elastomers and Plastics., 30, 245 (1998)
  11. Martin-Alfonso MJ, Partal P, Navarro FJ, Garcia-Morales M, Gallegos C, Ind. Eng. Chem. Res., 47(18), 6933 (2008)
  12. Martin-Alfonso MJ, Partal P, Navarro FJ, Garcia-Morales M, Bordado JCM, Diogo AC, Fuel Process. Technol., 90(4), 525 (2009)
  13. Collong W, Go¨ bel A, Kleuser B, Lenhard W, Sonntag M, Progress in Organic Coatings., 45, 205 (2002)
  14. Chattopadhyay DK, Webster DC, Progress in Polymer Science., 34, 1068 (2009)
  15. Andersson A, Lundmark S, Magnusson A, Maurer FHJ, Journal of Applied Polymer Science., 111, 2290 (2008)
  16. Mahmood N, Kressler J, Busse K, J. Appl. Polym. Sci., 98(3), 1280 (2005)
  17. AASHTO, Standard Test Method for Determining the Rheological Properties of Asphalt Binder Using a Dynamic Shear Rheometer (DSR), American Association of State Highway and Transportation Officials, 1993 AASHTO designation TP5.
  18. Peramanu S, Pruden BB, Rahimi P, Ind. Eng. Chem. Res., 38(8), 3121 (1999)
  19. Navarro FJ, Partal P, Garcia-Morales M, Martin-Alfonso MJ, Martinez-Boza F, Gallegos C, Bordado JCM, Diogo AC, J. Ind. Eng. Chem., 15(4), 458 (2009)
  20. Lu X, Isacsson U, Polymer Testing., 20, 77 (2001)
  21. Vasiljevic-Shikaleska A, Popovska-Pavlovska F, Cimmino S, Duraccio D, Silvestre C, J. Appl. Polym. Sci., 118(3), 1320 (2010)
  22. Fawcett AH, McNally T, McNally G, Adv. Polym. Technol., 21(4), 275 (2002)
  23. Fuentes-Aude´ n C, Sandoval JA, Jerez A, Navarro FJ, Martı´nez-Boza FJ, Partal P, Gallegos C, Polymer Testing., 27, 1005 (2008)
  24. Garcia-Morales M, Partal P, Navarro FJ, Gallegos C, Fuel, 85(7-8), 936 (2006)
  25. Gireesh KB, Jena KK, Allauddin S, Radhika KR, Narayan R, Raju KVSN, Progress in Organic Coatings., 68, 165 (2010)
  26. Cuadri AA, Partal P, Navarro FJ, Garcia-Morales M, Gallegos C, Fuel, 90(6), 2294 (2011)
  27. Vaughan BR, Wilkes GL, Dounis DV, McLaughlin C, J. Appl. Polym. Sci., 119(5), 2683 (2011)
  28. Madra H, Tantekin-Ersolmaz SB, Guner FS, Polymer Testing., 28, 773 (2009)
  29. Eaves D, Handbook of Polymer Foams, Smithers Rapra, Shawbury (2004)
  30. DEROSA ME, WINTER HH, Rheol. Acta, 33(3), 220 (1994)
  31. Xiaobin L, Hongbin C, Zhang Y, Science in China Series B., 49, 363 (2006)
  32. Navarro FJ, Partal P, Martinez-Boza F, Valencia C, Gallegos C, Chem. Eng. J., 89(1-3), 53 (2002)
  33. Singh B, Tarannum H, Gupta M, J. Appl. Polym. Sci., 90(5), 1365 (2003)
  34. Carrera V, Partal P, Garcia-Morales M, Gallegos C, Perez-Lepe A, Fuel Process. Technol., 91(9), 1139 (2010)
  35. Soon-Jae L, Amirkhanian SN, Kim KW, Construction and Building Materials., 23, 3087 (2009)
  36. Doh YS, Amirkhanian SN, Kim KW, Construction and Building Materials., 22, 1253 (2008)