이차원 구조를 갖는 고분자의 합성

신재섭

Journal of the Korean Industrial and Engineering Chemistry, Vol.9, No.5, 763-767, October, 1998

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이차원 구조를 갖는 고분자의 합성

Synthesis of Two Dimensional Polymer Network

신재섭

초록

콜레스테롤을 갖는 계면활성제를 합성하고, 이 계면활성제를 단량체[tetradeca(ethylene glycol) diacrylate]와 함께 물 속에서 음파 파쇄하여 vesicle 용액을 형성한 다음, 이 용액내의 물을 증발시켜, 분자들이 규칙적으로 배열된 분자 다층 구조를 갖는 막을 형성하였다. 이 막에 들어 있는 단량체들은 광중합하여, 고분자가 계면활성제들의 층과 층 사이에 들어 있는 분자 다층 구조를 합성하였다. 중합이 끝난 후 유기 용매를 사용하여 계면활성제를 추출하여 이차원적인 구조를 갖는

Cholesterol-containing surfactant was synthesized, and it was sonicated with monomer [tetradeca(ethylene glycol) diacrylate] in water to from a vesicle solution. This vesicle solution was dried to construct a membrane which had a molecular multilayer structure. The monomer which stay in this membrane was polymerized with photoinitiation, and then surfactant was extracted by organic solvent. The physical properties of the two dimensional polymer network were measured, and these physical propertise are tensile strength, elongation, and swelling.

Keywords:Multilayer;Cholesterol;Vesicle

[References]

Fendler JH, Accounts Chem. Res., 13, 7 (1980)
Fendler JH, "Membrane Mimetic Chemistry," pp. 160-168, John Wiley & Sons, New York (1982)
Tunuli MS, Fendler JH, J. Am. Chem. Soc., 103, 2507 (1981)
Tricot YM, Fendler JH, J. Am. Chem. Soc., 106, 7359 (1984)
Moss RA, Shin JS, J. Chem. Soc.-Chem. Commun., 1027 (1983)
Moss RA, Bhattacharya S, Scrimin P, Swarup S, J. Am. Chem. Soc., 109, 5740 (1987)
Moss RA, Okumura Y, J. Am. Chem. Soc., 114, 1750 (1992)
Cho I, Shin JS, Polym.(Korea), 15(2), 170 (1991)
Shin JS, J. Korean Ind. Eng. Chem., 2(1), 64 (1991)
Bae DH, Kim KS, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 335 (1992)
Cho I, Chung KC, Macromolecules, 17, 2935 (1984)
Cho I, Chung KC, Macromolecules, 21, 565 (1988)
Cho I, Park JG, Chem. Lett., 977 (1987)
Choi I, Kim YW, Polym. Bull., 24, 545 (1990)
Cho I, Kim SH, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 273 (1992)
Cho I, Jeong SW, Shin JS, Polym.(Korea), 18(1), 23 (1994)
Shin JS, Polym.(Korea), 19(3), 379 (1995)
Shin JS, J. Korean Ind. Eng. Chem., 7(6), 1142 (1996)
Lee H, Chemworld, 33, 814 (1993)
Park JW, Chemworld, 34, 111 (1994)
Lee H, Polym. Sci. Technol., 5(5), 471 (1994)

[Referenced By]

[1] Fendler JH, Accounts Chem. Res., 13, 7 (1980)

[2] Fendler JH, "Membrane Mimetic Chemistry," pp. 160-168, John Wiley & Sons, New York (1982)

[3] Tunuli MS, Fendler JH, J. Am. Chem. Soc., 103, 2507 (1981)

[4] Tricot YM, Fendler JH, J. Am. Chem. Soc., 106, 7359 (1984)

[5] Moss RA, Shin JS, J. Chem. Soc.-Chem. Commun., 1027 (1983)

[6] Moss RA, Bhattacharya S, Scrimin P, Swarup S, J. Am. Chem. Soc., 109, 5740 (1987)

[7] Moss RA, Okumura Y, J. Am. Chem. Soc., 114, 1750 (1992)

[8] Cho I, Shin JS, Polym.(Korea), 15(2), 170 (1991)

[9] Shin JS, J. Korean Ind. Eng. Chem., 2(1), 64 (1991)

[10] Bae DH, Kim KS, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 335 (1992)

[11] Cho I, Chung KC, Macromolecules, 17, 2935 (1984)

[12] Cho I, Chung KC, Macromolecules, 21, 565 (1988)

[13] Cho I, Park JG, Chem. Lett., 977 (1987)

[14] Choi I, Kim YW, Polym. Bull., 24, 545 (1990)

[15] Cho I, Kim SH, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 273 (1992)

[16] Cho I, Jeong SW, Shin JS, Polym.(Korea), 18(1), 23 (1994)

[17] Shin JS, Polym.(Korea), 19(3), 379 (1995)

[18] Shin JS, J. Korean Ind. Eng. Chem., 7(6), 1142 (1996)

[19] Lee H, Chemworld, 33, 814 (1993)

[20] Park JW, Chemworld, 34, 111 (1994)

[21] Lee H, Polym. Sci. Technol., 5(5), 471 (1994)