단분자 막의 실험에 의한 콜레스테롤을 갖는 고분자의 분자량 측정

조의환; 정상원; 신재섭

Polymer(Korea), Vol.18, No.1, 23-27, January, 1994

Export Citation

단분자 막의 실험에 의한 콜레스테롤을 갖는 고분자의 분자량 측정

Molecular Weight Determination of Cholesterol-Containing Polymer by Monolayer Study

조의환, 정상원, 신재섭

초록

콜레스테롤을 갖는 단량체와 N-vinylpyrrolidone측 공중합하여 amphiphilic 고분자를 합성하였으며 이 고분자를 이용하여 단분자막 실험을 하였다. Trough를 이용하여 π-A curve를 얻었으며 이 결과로 부터 πA-π 관계식을 유도하여 이 고분자의 분자량을 측정하였다. 이 결과로부터 측정된 분자량 값과 GPC 실험으로부터 얻은 분자량값은 거의 비슷하였다.

Copolymerization of cholesterol-containing monomer and N-vinylpyrrolidone was carried out to make amphiphilic polymer. Using a trough monolayer study for this polymer was done and π-A curves were obtained. The molecular weight of this polymer was determined from πA-π relationship. These results were almost similar with the molecular weight obtained by GPC.

[References]

Mufson D, Meksuwan K, Zarembo JE, Ravin LJ, Science, 177, 701 (1972)
Lester R, Carey MC, Little JM, Dowd SR, Science, 189, 1098 (1975)
Burns RA, Roberts MF, Biochemistry, 20, 7102 (1981)
Pal S, Moulikkk SP, J. Lipid Res., 24, 1281 (1983)
Schott H, Sayeed FAA, J. Colloid Interface Sci., 112, 274 (1986)
Cho I, Chung KC, Macromolecules, 17, 2935 (1984)
Cho I, Chung KC, Macromolecules, 21, 565 (1988)
Cho I, Park JG, Chem. Lett., 977 (1987)
Cho I, Kim SH, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 273 (1992)
Cho I, Kim YW, Polym. Bull., 24, 545 (1990)
Chi IF, Johnston RR, Ringsdorf H, Kimizuka N, Kunitake T, Thin Solid Films, 210-211, 111 (1992)
Peng JB, Barnes GT, Schutster A, Ringsdorf H, Thin Solid Films, 210-211, 16 (1992)
Teerenstra MN, Vorenkamp EJ, Schouten AJ, Nolte RJM, Walree CA, Pol JF, Thin Solid Films, 210-211, 496 (1992)
Kawaguchi M, Yoshida A, Takahashi A, Macromolecules, 16, 956 (1983)
Kawaguchi M, Komatsu S, Matsuzumi M, Takahashi A, J. Colloid Interface Sci., 102, 356 (1984)
Ponpipom MM, Bugianesi RL, Shen TY, Friedman A, Med. Chem., 23, 1184 (1980)

[Referenced By]

[1] Mufson D, Meksuwan K, Zarembo JE, Ravin LJ, Science, 177, 701 (1972)

[2] Lester R, Carey MC, Little JM, Dowd SR, Science, 189, 1098 (1975)

[3] Burns RA, Roberts MF, Biochemistry, 20, 7102 (1981)

[4] Pal S, Moulikkk SP, J. Lipid Res., 24, 1281 (1983)

[5] Schott H, Sayeed FAA, J. Colloid Interface Sci., 112, 274 (1986)

[6] Cho I, Chung KC, Macromolecules, 17, 2935 (1984)

[7] Cho I, Chung KC, Macromolecules, 21, 565 (1988)

[8] Cho I, Park JG, Chem. Lett., 977 (1987)

[9] Cho I, Kim SH, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 273 (1992)

[10] Cho I, Kim YW, Polym. Bull., 24, 545 (1990)

[11] Chi IF, Johnston RR, Ringsdorf H, Kimizuka N, Kunitake T, Thin Solid Films, 210-211, 111 (1992)

[12] Peng JB, Barnes GT, Schutster A, Ringsdorf H, Thin Solid Films, 210-211, 16 (1992)

[13] Teerenstra MN, Vorenkamp EJ, Schouten AJ, Nolte RJM, Walree CA, Pol JF, Thin Solid Films, 210-211, 496 (1992)

[14] Kawaguchi M, Yoshida A, Takahashi A, Macromolecules, 16, 956 (1983)

[15] Kawaguchi M, Komatsu S, Matsuzumi M, Takahashi A, J. Colloid Interface Sci., 102, 356 (1984)

[16] Ponpipom MM, Bugianesi RL, Shen TY, Friedman A, Med. Chem., 23, 1184 (1980)