Graphene oxide/poly(acrylic acid) hydrogel by γ-ray pre-irradiation on graphene oxide surface

Sungyoung Lee; Hoik Lee; Jae Hyun Sim; Daewon Sohn

Macromolecular Research, Vol.22, No.2, 165-172, February, 2014

DOI10.1007/s13233-014-2025-x Export Citation

Graphene oxide/poly(acrylic acid) hydrogel by γ-ray pre-irradiation on graphene oxide surface

Sungyoung Lee, Hoik Lee, Jae Hyun Sim¹, and Daewon Sohn^†

Department of Chemistry, Hanyang University, Seoul, 133-791, Korea
¹Department of Applied Chemistry, Kyushu University, Fukuoka, 812-8581, Japan, Korea

E-mail:

Graphene oxide/poly(acrylic acid) (GO/PAA) hybrid hydrogel was prepared using a γ-ray pre-irradiation technique. The functional groups in graphene oxide were modified to peroxide in an O2 environment with γ-ray radiation. Radical species from the thermal decomposition of peroxides initiated radical polymerization of the acrylic acid monomers. Modified GO and GO/PAA hydrogels were investigated using scanning electron microscopy and Fourier transform infrared (FTIR), Raman, and electron spin resonance spectroscopy. The thermal, mechanical, and swelling properties of GO/PAA hydrogel were studied by a tensile stress-strain curve and thermal gravimetric analysis. A genuine binary hybrid hydrogel of graphene oxide and PAA was obtained from a simple synthetic procedure based on γ-ray pre-irradiation without further additives.

Keywords:graphene oxide;hydrogel;poly(acrylic acid);γ-ray;hybrid gel

[References]

Peppas NA, Bures P, Leobandung W, Ichikawa H, Eur. J. Pharm. Biopharm., 50, 27 (2000)
Lin X, Deng L, Xu Y, Dong A, Soft Matter, 8, 3470 (2012)
Pitt WG, Jack DR, Zhao Y, Nelson JL, Pruitt JD, J. Biomater. Sci.-Polym. Ed., 23, 527 (2012)
Kope ek J, Yang J, Angew. Chem.-Int. Edit., 51, 7396 (2012)
Oh JK, Drumright R, Siegwart DJ, Matyjaszewski K, Prog. Polym. Sci, 33, 448 (2008)
Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)
Tung NT, Khai TV, Lee H, Sohn D, Synth. Met., 161, 177 (2011)
Sun S, Wu P, J. Mater. Chem., 21, 4095 (2011)
Koo J, Kim J, Lee H, Chung H, Lee Y, Yi W, Sohn D, Macromol. Res., 20(2), 138 (2012)
Huang T, Xu HG, Jiao KX, Zhu LP, Brown HR, Wang HL, Adv. Mater., 19(12), 1622 (2007)
Severini F, Gallo R, J. Therm. Anal. Calorim., 30, 841 (1985)
Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)
Marcano DC, Kosynkin DV, Berlin JM, Sunitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)
Cote LJ, Kim F, Huang JX, J. Am. Chem. Soc., 131(3), 1043 (2009)
Bourlinos AB, Gournis D, Petridis D, Szabo T, Szeri A, Dekany I, Langmuir, 19(15), 6050 (2003)
Sljivancanin Z, Milosevic AS, Popovic ZS, Vukajlovic FR, Carbon, 54, 482 (2013)
Wilson MT, Reeder BJ, Biochem. J., 330, 1317 (1998)
Paredes JI, Villar-Rodil S, Martinez-Alonso A, Tascon JMD, Langmuir, 24(19), 10560 (2008)
Chen W, Zhu Z, Li S, Chen C, Yan L, Nanoscale, 4, 2124 (2012)
Kudin KN, Ozbas B, Schniepp HC, Prud’homme RK, Aksay IA, Car R, Nano Lett., 8, 36 (2008)
Zhuo Q, Gao J, Peng M, Bai L, Deng J, Xia Y, Ma Y, Zhong J, Sun X, Carbon, 52, 559 (2013)
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)
Eiric L, Sienkiewicz A, Gaal R, Jacimovic J, Vaju C, Magrez A, Forro L, Phys. Rev. B, 86, 195139 (2012)
Ciric L, Sienkiewicz A, Djokic DM, Smajda R, Magrez A, Kaspar T, Nesper R, Forro L, Phys. Status Solidi B, 247, 2958 (2010)
Yuan B, Zhang ZX, Zhou K, Appl. Surf. Sci., 257(13), 5754 (2011)
Zhang L, Wang Z, Xu C, Li Y, Gao J, Wang W, Liu Y, J. Mater. Chem., 21, 10399 (2011)
Zhu J, Lee CH, Joh HI, Kim HC, Lee S, Catal. Lett., 13, 230 (2012)
Socrates G, Infrared Characteristic Group Frequencies, 2nd ed., Wiley, New York, 1994.
Silverstein RM, Webster FX, in Spectrometric Identification of Organic Compounds, 6th ed., John Wiley & Sons, Inc., New York, 1998.
Williams DH, Fleming I, in Spectroscopic Methods in Organic Chemistry, 4th ed., McGraw Hill, New York, 1987.
Arndt KF, Richter A, Ludwig S, Zimmermann J, Kressler J, Kuckling D, Adler HJ, Acta Polym., 50, 11 (2000)
Moharram MA, Rabie SM, El-Gendy HM, J. Appl. Polym. Sci., 85(8), 1619 (2002)
Flory P, J. Chem. Rev., 35, 51 (1944)
Yang J, Gong C, Shi FK, Xie XM, J. Phys. Chem. B, 116(39), 12038 (2012)
Shen J, Yan B, Li T, Long Y, Ye M, Compos. Pt. A-Appl. Sci. Manuf., 43, 1476 (2012)
Webber RE, Creton C, Brown HR, Gong JP, Macromolecules, 40(8), 2919 (2007)
Zhang N, Li R, Zhang L, Chen H, Wang W, Liu Y, Wu T, Wang X, Wang W, Li Y, Zhao Y, Gao J, Soft Matter, 7, 7231 (2011)
Cheng QY, Zhou D, Gao Y, Chen Q, Zhang Z, Han BH, Langmuir, 28(5), 3005 (2012)
Yu C, Hui-min T, Carbohydr. Res., 341, 887 (2006)
Zhu L, Zhang L, Tang Y, Yang J, Polym. Polym. Compos., 21, 21 (2013)

[Referenced By]

[1] Peppas NA, Bures P, Leobandung W, Ichikawa H, Eur. J. Pharm. Biopharm., 50, 27 (2000)

[2] Lin X, Deng L, Xu Y, Dong A, Soft Matter, 8, 3470 (2012)

[3] Pitt WG, Jack DR, Zhao Y, Nelson JL, Pruitt JD, J. Biomater. Sci.-Polym. Ed., 23, 527 (2012)

[4] Kope ek J, Yang J, Angew. Chem.-Int. Edit., 51, 7396 (2012)

[5] Oh JK, Drumright R, Siegwart DJ, Matyjaszewski K, Prog. Polym. Sci, 33, 448 (2008)

[6] Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)

[7] Tung NT, Khai TV, Lee H, Sohn D, Synth. Met., 161, 177 (2011)

[8] Sun S, Wu P, J. Mater. Chem., 21, 4095 (2011)

[9] Koo J, Kim J, Lee H, Chung H, Lee Y, Yi W, Sohn D, Macromol. Res., 20(2), 138 (2012)

[10] Huang T, Xu HG, Jiao KX, Zhu LP, Brown HR, Wang HL, Adv. Mater., 19(12), 1622 (2007)

[11] Severini F, Gallo R, J. Therm. Anal. Calorim., 30, 841 (1985)

[12] Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)

[13] Marcano DC, Kosynkin DV, Berlin JM, Sunitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)

[14] Cote LJ, Kim F, Huang JX, J. Am. Chem. Soc., 131(3), 1043 (2009)

[15] Bourlinos AB, Gournis D, Petridis D, Szabo T, Szeri A, Dekany I, Langmuir, 19(15), 6050 (2003)

[16] Sljivancanin Z, Milosevic AS, Popovic ZS, Vukajlovic FR, Carbon, 54, 482 (2013)

[17] Wilson MT, Reeder BJ, Biochem. J., 330, 1317 (1998)

[18] Paredes JI, Villar-Rodil S, Martinez-Alonso A, Tascon JMD, Langmuir, 24(19), 10560 (2008)

[19] Chen W, Zhu Z, Li S, Chen C, Yan L, Nanoscale, 4, 2124 (2012)

[20] Kudin KN, Ozbas B, Schniepp HC, Prud’homme RK, Aksay IA, Car R, Nano Lett., 8, 36 (2008)

[21] Zhuo Q, Gao J, Peng M, Bai L, Deng J, Xia Y, Ma Y, Zhong J, Sun X, Carbon, 52, 559 (2013)

[22] Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)

[23] Eiric L, Sienkiewicz A, Gaal R, Jacimovic J, Vaju C, Magrez A, Forro L, Phys. Rev. B, 86, 195139 (2012)

[24] Ciric L, Sienkiewicz A, Djokic DM, Smajda R, Magrez A, Kaspar T, Nesper R, Forro L, Phys. Status Solidi B, 247, 2958 (2010)

[25] Yuan B, Zhang ZX, Zhou K, Appl. Surf. Sci., 257(13), 5754 (2011)

[26] Zhang L, Wang Z, Xu C, Li Y, Gao J, Wang W, Liu Y, J. Mater. Chem., 21, 10399 (2011)

[27] Zhu J, Lee CH, Joh HI, Kim HC, Lee S, Catal. Lett., 13, 230 (2012)

[28] Socrates G, Infrared Characteristic Group Frequencies, 2nd ed., Wiley, New York, 1994.

[29] Silverstein RM, Webster FX, in Spectrometric Identification of Organic Compounds, 6th ed., John Wiley & Sons, Inc., New York, 1998.

[30] Williams DH, Fleming I, in Spectroscopic Methods in Organic Chemistry, 4th ed., McGraw Hill, New York, 1987.

[31] Arndt KF, Richter A, Ludwig S, Zimmermann J, Kressler J, Kuckling D, Adler HJ, Acta Polym., 50, 11 (2000)

[32] Moharram MA, Rabie SM, El-Gendy HM, J. Appl. Polym. Sci., 85(8), 1619 (2002)

[33] Flory P, J. Chem. Rev., 35, 51 (1944)

[34] Yang J, Gong C, Shi FK, Xie XM, J. Phys. Chem. B, 116(39), 12038 (2012)

[35] Shen J, Yan B, Li T, Long Y, Ye M, Compos. Pt. A-Appl. Sci. Manuf., 43, 1476 (2012)

[36] Webber RE, Creton C, Brown HR, Gong JP, Macromolecules, 40(8), 2919 (2007)

[37] Zhang N, Li R, Zhang L, Chen H, Wang W, Liu Y, Wu T, Wang X, Wang W, Li Y, Zhao Y, Gao J, Soft Matter, 7, 7231 (2011)

[38] Cheng QY, Zhou D, Gao Y, Chen Q, Zhang Z, Han BH, Langmuir, 28(5), 3005 (2012)

[39] Yu C, Hui-min T, Carbohydr. Res., 341, 887 (2006)

[40] Zhu L, Zhang L, Tang Y, Yang J, Polym. Polym. Compos., 21, 21 (2013)