화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.2195
발표분야 수소 생산 및 저장 재료 심포지엄 (재료부문위원회)
제목 Forming Fused Aromatic Organic Networks for Energy Applications
초록 Stable fused organic networks have been designed and synthesized. They have uniformly distributed heteroatoms,1 holes with heteroatoms,2 and transition metal nanoparticles in the holes.3 The structures were confirmed using various characterization techniques. Based on the stoichiometry of 2D layered structures, they were, respectively, designated C2N, C3N, C4N, and M@C2N (M = Co, Ni, Pd, Pt, Ru). Furthermore, robust three-dimensional (3D) cage-like organic networks have also been constructed and they show high sorption properties.4,5 The results suggest that these newly-developed robust fused aromatic 2D and 3D organic networks offer greater opportunities for energy applications.
References:
[1] Mahmood, et al. PNAS 2016, 113, 7414.
[2] Mahmood, et al. Nat. Commun. 2015, 6, 6486.
[3] Mahmood, et al. Nat. Nanotech. 2017, 12, 441.
[4] Bae, et al. Nat. Commun. 2017, 8, 159-Highlighted in Nat. Nanotech. 2018, 13, 4.
[5] Mahmood, et al. Angew. Chem. Int’l Ed. 2018, 57, 3415.
저자 백종범
소속 UNIST
키워드 Aromatic Organic Network; Electronic Property; Water Splitting; Hydrogen Evolution
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