| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.23 |
| 발표분야 |
고분자 |
| 제목 |
Ring-opening polymerization of Glycidyl methacrylate (GMA) with boron trifluride ethyl etherate (BF3·OEt2) in compressed liquid dimethyl ether (DME) |
| 초록 |
Poly(glycidyl methacrylate) (PGMA) was synthesized through ring-opening polymerization with boron ethyl etherate (BF3•OEt2) as a catalyst in compressed liquid dimethyl ether (DME). Optimized conditions allow the direct synthesis of well defined spherical PGMA particles at 40°C and 20 bar. The results of FT-IR indicated that the reactivity of the epoxy groups was higher than that of the double bonds in the bifunctional monomer GMA under the polymerization conditions. |
| 저자 |
오경실1, 조동우1, 배 원2, 김화용1
|
| 소속 |
1서울대, 2미원상사주식회사 |
| 키워드 |
ring-opening; PGMA
|
| E-Mail |
|
| 원문파일 |
초록 보기 |
