화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.2649
발표분야 환경
제목 Development of new regenerable potassium-based α-alumina sorbent for post-combustion CO2 capture
초록 A new regenerable potassium-based sorbent, which was prepared by impregnation of α-Al2O3 with 30 wt% K2CO3, was developed for CO2 sorption and regeneration at low temperature (50~130oC). This sorbent showed high CO2 sorption capacity and excellent regeneration properties during multiple tests, unlike the potassium-based γ-Al2O3 sorbent which was deactivated by the formation of by-product, KAl(CO3)(OH)2, during CO2 sorption. The excellent regeneration properties of the new regenerable sorbent are due to the formation of a KHCO3 phase without by-products during CO2 sorption, resulting from the structure effect of alumina. From these results, it is concluded that α-Al2O3 is one of the most useful materials for designing the ideal potassium-based sorbent for CO2 sorption and regeneration in the temperature range between 50oC and 130oC.
저자 조민선1, 김재창1, 이수출1, 정석용1, 이중범2, 류청걸2
소속 1경북대, 2한국전력(연)
키워드 CO2; alumina; K2CO3; KHCO3
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