학회 | 한국화학공학회 |
학술대회 | 2021년 가을 (10/27 ~ 10/29, 광주 김대중컨벤션센터) |
권호 | 27권 2호, p.2045 |
발표분야 | 재료 |
제목 | A Novel Metallic Using Metal-Organic Framework for Electrochemical Reduction of CO2 to CO |
초록 | Cu-MOF74 has several advantages, including uniformly distributed bimetallic ions, less tendency towards aggregation, and more stable interfacial sites than Zn-MOF74. In this study, Cu-MOF74, and Zn-MOF74 were synthesized using nitrate salt of Cu and Zn combine with 2,5-dihydroxyterephtalic acid (H4DOBBDC) were dissolved in DMF with stirring, and after that addition of DI water. The electrochemical reduction CO2 (ERC) was taking place on an H-type cell in a 0.1 M KHCO3 aqueous solution. The efficiency of Cu-MOF74 exhibited excellent electrochemical CO2 reduction properties, including high CO selectivity (~ 85%) and low overpotential (< -1.9 V) than Zn-MOF74. Keywords: Metal-organic framework (MOF-74), Electrocatalyst, Electrochemical reduction CO2 (ERC). |
저자 | Tran Van Phuc1, Jana Jayasmita2, Huynh Ngoc-Diem2, R.Nivetha2, 허승현2 |
소속 | 1울산대, 2Univ. of Ulsan |
키워드 | 화공소재 |
원문파일 | 초록 보기 |