화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2021년 가을 (10/27 ~ 10/29, 광주 김대중컨벤션센터)
권호 27권 2호, p.2045
발표분야 재료
제목 A Novel Metallic Using Metal-Organic Framework for Electrochemical Reduction of CO2 to CO
초록 Cu-MOF74 has several advantages, including uniformly distributed bimetallic ions, less tendency towards aggregation, and more stable interfacial sites than Zn-MOF74. In this study, Cu-MOF74, and Zn-MOF74 were synthesized using nitrate salt of Cu and Zn combine with 2,5-dihydroxyterephtalic acid (H4DOBBDC) were dissolved in DMF with stirring, and after that addition of DI water. The electrochemical reduction CO2 (ERC) was taking place on an H-type cell in a 0.1 M KHCO3 aqueous solution. The efficiency of Cu-MOF74 exhibited excellent electrochemical CO2 reduction properties, including high CO selectivity (~ 85%) and low overpotential (< -1.9 V) than Zn-MOF74.

Keywords: Metal-organic framework (MOF-74), Electrocatalyst, Electrochemical reduction CO2 (ERC).
저자 Tran Van Phuc1, Jana Jayasmita2, Huynh Ngoc-Diem2, R.Nivetha2, 허승현2
소속 1울산대, 2Univ. of Ulsan
키워드 화공소재
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