Materials Chemistry and Physics, Vol.132, No.2-3, 421-430, 2012
Temperature and thickness dependence of the grain boundary scattering in the Ni-Si suicide films formed on silicon substrate at 500 degrees C by RTA
The temperature-dependent resistivity measurements of Ni-Si silicide films with 18-290 nm thicknesses are studied as a function of temperature and film thickness over the temperature range of 100-900K. The most striking behavior is that the variation of the resistivity of the films with temperature exhibits an unusual behavior. The total resistivity of the Ni-Si silicide films in this work increases linearly with temperature up to a T-m temperature, thereafter decreases rapidly and finally reaches zero. Our analyses have shown that in the temperature range of 100 to T-m (K), parallel-resistor formula reduces to Matthiessen's rule and theta(D) Debye temperature becomes independent of the temperature for the given thickness range, whereas at high temperatures (above T-m) it increases slightly with thickness. theta(D) Debye temperature have been found to be about 400-430 K for the films. We have also shown that for temperature range of 100 to T-m (K), linear variation of the resistivity of the silicide films with temperature has been caused from both grain-boundary scattering and electron-phonon scattering. That is why, resistivity data could have been analyzed in terms of the Mayadas-Schatzkes (M-S) model successfully. Theoretical and experimental values of reflection coefficients have been calculated by analyzing resistivity data using M-S model. According to our analysis, R increases with decreasing film thickness for a given temperature, while it is almost constant for the thickness range of 200-67 nm and 47-18 nm, over which silicide films show almost the same phases, also confirmed by our XRD, SEM and RBS measurements. (C) 2011 Elsevier B.V. All rights reserved.