화학공학소재연구정보센터
Journal of Materials Science, Vol.47, No.5, 2472-2478, 2012
High-temperature deformation and crystallization behavior of a Cu36Zr48Al8Ag8 bulk metallic glass
The influence of annealing on the crystallization behavior of a Cu36Zr48Al8Ag8 (at.%) bulk metallic glass (BMG) was investigated. In both isochronal and isothermal annealing processes, the effective activation energies of the primary crystallizations were obtained as 295.8 +/- A 13.4 and 302.7 +/- A 14.5 kJ/mol by applying the Kissinger and Ozawa methods, respectively. Using the isothermal transformation kinetics described by the Johnson-Mehl-Avrami model, the Avrami exponent n was found to range between 2.56 and 3.25, which indicates that the primary crystallization behavior was three-dimensional diffusion-controlled growth with an increasing nucleation rate. The high-temperature deformation behavior of a Cu36Zr48Al8Ag8 BMG was then investigated by performing a series of compression tests after rapid heating within a supercooled liquid region. It was found that at least 14-17 dense randomly packed atoms are necessary to produce a unit local flow when the present BMG is subjected to non-Newtonian homogeneous deformation, as described by the transition state equation. Deformation and processing maps were also constructed based on the dynamic materials model to predict optimum bulk formability in a Cu36Zr48Al8Ag8 BMG taking warm deformation-induced crystallization within a supercooled liquid into account.