This article reports the synthesis, charge transport studies, and microwave shielding properties of polyaniline-Ti-doped gamma-Fe2O3 nanocomposite. The composite has been prepared by the in situ chemical oxidative polymerization using dodecylbenzenzesulfonic acid as a dopant. These resulting polymer composites have been found thermally stability up to 260 A degrees C with magnetization value of similar to 10 emu/g. The temperature dependence of electrical conductivity reveals the applicability of Mott's 3D-VRH model. The composites has shown the shielding effectiveness of 35.64-45.20 dB (> 99.99% attenuation) in 12.4-18 GHz (Ku-Band) frequency range. The enhancement of SE has been due to combination of dielectric and magnetic losses leading to decrease in skin depth increase in total (sigma(T)) conductivity and better matching of input impedance.