Effect of surface modification of graphene oxide on photochemical stability of poly(vinyl alcohol)/graphene oxide composites

Minhee Han; Jumi Yun; Hyung-Il Kim; Young-Seak Lee

Journal of Industrial and Engineering Chemistry, Vol.18, No.2, 752-756, March, 2012

DOI10.1016/j.jiec.2011.11.122 Export Citation

Effect of surface modification of graphene oxide on photochemical stability of poly(vinyl alcohol)/graphene oxide composites

Minhee Han, Jumi Yun, Hyung-Il Kim^†, and Young-Seak Lee

Department of Fine Chemical Engineering and Applied Chemistry, BK21-E2M, Chungnam National University, Daejeon 305-764, Republic of Korea

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Poly(vinyl alcohol) (PVA)/graphene oxide (GO) composites were prepared to improve the photochemical stability of PVA. The surface of GO was modified by oxyfluorination to introduce the polar functional groups on GO for the stronger interfacial interaction with PVA. The photochemical stability of PVA/oxyfluorinated-GO composites was evaluated by measuring the insoluble gel content after partial photodegradation of PVA under various UV irradiations. PVA/oxyfluorinated-GO composites showed the significant improvement in both the dispersion of GO in PVA matrix and the photochemical stability of PVA as the oxygen content increased in the oxyfluorination. The photochemical stability of composites had a close relation with the uniform distribution of GO in PVA matrix. The proper modification of GO by oxyfluorination showed the better photochemical stability for PVA/GO composites as compared to that of PVA/pristine GO composite.

Keywords:Photochemical stability;Graphene oxide;Poly(vinyl alcohol);Oxyfluorination

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[Referenced By]

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[2] Breuer O, Sundararaj U, Polym. Compos., 25, 630 (2004)

[3] Krishnamoorti R, Vaia RA, Introduction to the Polymer Nanocomposites, ACS,Washington, DC, 1 (2001)

[4] Kacperski M, Polimery., 47, 801 (2002)

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[10] Tian HY, Tagaya H, J. Mater. Sci., 42(9), 3244 (2007)

[11] Ray SS, Yamada K, Okamoto M, Ueda K, Polymer, 44(3), 857 (2003)

[12] Paradossi G, Cavalieri F, Chiessi E, Spagnoli C, Cowman MK, J. Mater. Sci. Mater. Med., 14, 687 (2003)

[13] Pourciel ML, Launay J, Sant W, Cone´de´ ra V, Martinez A, Temple-Boyer P, Sens.Actuators B: Chem., 94, 330 (2003)

[14] Kwiecin´ ska B, Petersen HI, Int. J. Coal Geol., 57, 99 (2004)

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[16] De´ka´ ny I, Kru¨ ger-Grasser R, Weiss A, Colloid Polym. Sci., 276, 570 (1998)

[17] Liang JJ, Huang Y, Zhang L, Wang Y, Ma YF, Guo TY, Chen YS, Adv. Funct. Mater., 19(14), 2297 (2009)

[18] Chandra V, Kim KS, Chem. Commun., 47, 3942 (2011)

[19] Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)

[20] Lee JM, Kim SJ, Kim JW, Kang PH, Nho YC, Lee YS, J. Ind. Eng. Chem., 15(1), 66 (2009)

[21] Bissessur R, Liu PKY, Scully SF, Synth. Met., 156, 1023 (2006)

[22] Chen G, Weng W, Wu D, Wu C, Lu J, Wang P, Chen X, Carbon., 42, 753 (2004)

[23] Titelman GI, Gelman V, Bron S, Khalfin RL, Cohen Y, Bianco-Peled H, Carbon., 43, 641 (2005)

[24] Ren P, Yan D, Ji X, Chen T, Li Z, Nanotechnology., 22, 1 (2011)

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[26] Guerinoa M, Massia M, Mansanob RD, Microelectron. J., 38, 915 (2007)

[27] Xu YX, Hong WJ, Bai H, Li C, Shi GQ, Carbon., 47, 3538 (2009)

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[29] Nadagouda MN, Varma RS, Macromol. Rapid Commun., 28(7), 842 (2007)