Design of heteropoly Compound-Imbedded Polymer Film Catalysts and Their Application

Lee WY; Song IK; Lee JK; Park GI; Lim SS

Korean Journal of Chemical Engineering, Vol.14, No.6, 432-440, November, 1997

Lee WY, Song IK, Lee JK, Park GI, Lim SS

Heteropolyacid-imbedded polymer film catalysts were applied for the vapor-phase catalytic reaction. Thin film catalysts were prepared by membrane technology using homogeneous heteropolyacid-polymer solutions. It was found that heteropolyacid was finely and uniformly dispersed throughout the polymer matrix. Heteropolyacid catalyst could be designed by this method to enhance acid or oxidation catalysis. Future aspects of the film catalyst were also described in this work.

Keywords:Heteropolyacid;Polymer;Catalyst Design;Application

[References]

Ai M, Appl. Catal., 4, 245 (1982)
Hasik M, Turek W, Stochmal E, Lapkowski M, Pron A, J. Catal., 147(2), 544 (1994)
Hill CL, Prosser-McCartha CM, Coord. Chem. Rev., 143, 407 (1995)
Huang C, Delacruz MO, Swift BW, Macromolecules, 28(24), 7996 (1995)
Kim HC, Moon SH, Lee WY, Chem. Lett., 447 (1991)
Kim JJ, Rhee HK, Lee WY, Chem. Eng. Commun., 34, 49 (1985)
Konishi Y, Sakata K, Misono M, Yoneda Y, J. Catal., 77, 169 (1982)
Kozhevnikov IV, Catal. Rev.-Sci. Eng., 37(2), 311 (1995)
Kozhevnikov IV, Matveev KI, Appl. Catal., 5, 135 (1983)
Lee JK, Song IK, Lee WY, Korean J. Chem. Eng., 12(3), 384 (1995)
Lee JK, Song IK, Lee WY, Kim JJ, J. Mol. Catal., 104, 311 (1996)
Lee JK, Song IK, Park GI, Lee WY, HWAHAK KONGHAK, 35(2), 237 (1997)
Lee KY, Arai T, Nakata S, Asaoka S, Okuhara T, Misono M, J. Am. Chem. Soc., 114, 2836 (1992)
Lee WY, HWAHAK KONGHAK, 17(5), 317 (1979)
Misono M, Okuhara T, Mizuno N, "Catalysis by Heteropoly Compounds," Successful Design of Catalysts, Inui, T., Eds., Elsevier, Amsterdam, 267 (1988)
Misono M, Sakata K, Yoneda Y, Lee WY, "Acid-Base Bifunctional Properties of Heteropoly Compounds of Molybdenum and Tungsten Correlated with Activity for Oxidatin of Methacrolein," New Horizons in Catalysis, Seiyama, T. and Tanabe, K., eds., Kodansha-Elsevier, Amsterdam, 1047 (1980)
Nizuno N, Misono M, J. Mol. Catal., 86, 319 (1994)
Nomiya K, Murasaki H, Miwa M, Polyhedrons, 5, 1031 (1986)
Okuhara T, Mizuno N, Misono M, Adv. Catal., 41, 113 (1996)
Pozniczek J, Kulszewicz-Bajer I, Zagorska M, Kruczala K, Dyrek K, Bielanski A, Pron A, J. Catal., 132, 311 (1991)
Song IK, Lee JK, Lee WY, J. Korean Ind. Eng. Chem., 5(5), 819 (1994)
Song IK, Lee JK, Lee WY, Appl. Catal. A: Gen., 119(1), 107 (1994)
Song IK, Lee JK, Song JC, Lee WY, J. Korean Ind. Eng. Chem., 5(3), 431 (1994)
Song IK, Lee WY, Kim JJ, Polym.(Korea), 16(2), 209 (1992)
Song IK, Moon SH, Lee WY, Korean J. Chem. Eng., 8(1), 33 (1991)
Song IK, Shin SK, Lee WY, J. Catal., 144, 348 (1993)
Tsai FJ, Torkelson JM, Macromolecules, 23, 775 (1990)

[Referenced By]

[1] Ai M, Appl. Catal., 4, 245 (1982)

[2] Hasik M, Turek W, Stochmal E, Lapkowski M, Pron A, J. Catal., 147(2), 544 (1994)

[3] Hill CL, Prosser-McCartha CM, Coord. Chem. Rev., 143, 407 (1995)

[4] Huang C, Delacruz MO, Swift BW, Macromolecules, 28(24), 7996 (1995)

[5] Kim HC, Moon SH, Lee WY, Chem. Lett., 447 (1991)

[6] Kim JJ, Rhee HK, Lee WY, Chem. Eng. Commun., 34, 49 (1985)

[7] Konishi Y, Sakata K, Misono M, Yoneda Y, J. Catal., 77, 169 (1982)

[8] Kozhevnikov IV, Catal. Rev.-Sci. Eng., 37(2), 311 (1995)

[9] Kozhevnikov IV, Matveev KI, Appl. Catal., 5, 135 (1983)

[10] Lee JK, Song IK, Lee WY, Korean J. Chem. Eng., 12(3), 384 (1995)

[11] Lee JK, Song IK, Lee WY, Kim JJ, J. Mol. Catal., 104, 311 (1996)

[12] Lee JK, Song IK, Park GI, Lee WY, HWAHAK KONGHAK, 35(2), 237 (1997)

[13] Lee KY, Arai T, Nakata S, Asaoka S, Okuhara T, Misono M, J. Am. Chem. Soc., 114, 2836 (1992)

[14] Lee WY, HWAHAK KONGHAK, 17(5), 317 (1979)

[15] Misono M, Okuhara T, Mizuno N, "Catalysis by Heteropoly Compounds," Successful Design of Catalysts, Inui, T., Eds., Elsevier, Amsterdam, 267 (1988)

[16] Misono M, Sakata K, Yoneda Y, Lee WY, "Acid-Base Bifunctional Properties of Heteropoly Compounds of Molybdenum and Tungsten Correlated with Activity for Oxidatin of Methacrolein," New Horizons in Catalysis, Seiyama, T. and Tanabe, K., eds., Kodansha-Elsevier, Amsterdam, 1047 (1980)

[17] Nizuno N, Misono M, J. Mol. Catal., 86, 319 (1994)

[18] Nomiya K, Murasaki H, Miwa M, Polyhedrons, 5, 1031 (1986)

[19] Okuhara T, Mizuno N, Misono M, Adv. Catal., 41, 113 (1996)

[20] Pozniczek J, Kulszewicz-Bajer I, Zagorska M, Kruczala K, Dyrek K, Bielanski A, Pron A, J. Catal., 132, 311 (1991)

[21] Song IK, Lee JK, Lee WY, J. Korean Ind. Eng. Chem., 5(5), 819 (1994)

[22] Song IK, Lee JK, Lee WY, Appl. Catal. A: Gen., 119(1), 107 (1994)

[23] Song IK, Lee JK, Song JC, Lee WY, J. Korean Ind. Eng. Chem., 5(3), 431 (1994)

[24] Song IK, Lee WY, Kim JJ, Polym.(Korea), 16(2), 209 (1992)

[25] Song IK, Moon SH, Lee WY, Korean J. Chem. Eng., 8(1), 33 (1991)

[26] Song IK, Shin SK, Lee WY, J. Catal., 144, 348 (1993)

[27] Tsai FJ, Torkelson JM, Macromolecules, 23, 775 (1990)