Recent Topics in Heterogeneous Catalysis of Heteropolyacids

Misono M

Korean Journal of Chemical Engineering, Vol.14, No.6, 427-431, November, 1997

First, the state of the art of the catalyst design based on heteropoly compounds is briefly overviewed. Then, selected topics of solid heteropoly catalysts, that is, the selective oxidation of isobutyric acid and isobutane over molybdovanadophosphoric acids, the methyl t-butyl ether synthesis in pseudoliquid of heteropolyacids, and the shape-selective and bifunctional (combined with noble metals) acid catalysis of cesium and ammonium salts of tungstophosphoric acid are described based on the recent studies from our laboratory.

Keywords:Heteropolyacid;Selective Oxidation. Pseudoliquid Behavior;Alkane Isomerization

[References]

Centi G, Lena V, Trifiro F, J. Chem. Soc.-Faraday Trans., 86, 2775 (1990)
Inumaru K, Kubo Ono A, Misono M, "The Structure and Redox Behaviour of Vanadium Speeies in Molybdovanadophosphoric Acid Catalysts during Partial Oxidation of Isobutane," to be published
Inumaru K, Nakajima H, Ito T, Misono M, Chem. Lett., 559 (1996)
Japan Patent, 1988-145249 (Asahi Chemical) (1988)
Japan Patent, 1991-106839 (Sumitomo Chemical) (1991)
Koyano G, Saito T, Misono M, Chem. Lett., 415 (1997)
Koyano G, Yamaguchi F, Okuhara T, Misono M, Catal. Lett., 41(3-4), 149 (1996)
Lee KY, Arai T, Nakata S, Asaoka S, Okuhara T, Misono M, J. Am. Chem. Soc., 114, 2836 (1992)
Lee KY, Oishi S, Igarashi H, Misono M, Catal. Today, 33(1-3), 183 (1997)
Li W, Ueda W, Catal. Lett., 46, 261 (1991)
Liu Y, Koyano G, Na K, Makoto M, Appl. Catal. A: Gen., in press
Misono M, Okuhara T, Chemtech., 23 (1993)
Mizuno N, Tateishi M, Iwamoto M, J. Catal., 163(1), 87 (1996)
Mizuno N, Tateishi M, Iwamoto M, J. Mol. Catal., 114, 309 (1996)
Mizuno N, Tateishi M, Iwamoto M, Chem. Lett., 1121 (1996)
Nizuno N, J. Mol. Catal., "Catalytic Performance of Cs_2.5Fe_0.08H_1.26-PVMo₁₁O₄₀ for Direct. Oxidation of Lower Alkanes,"
Lizuno N, Chem. Lett., "Selective Oxidative Dehydrogenation of Ethane Catalyzed by Cs_2.5Mn_0.08H_1.34PVMo₁₁O₄₀," Catalyst Precursor
Na K, Okuhara T, Misono M, J. Chem. Soc.-Faraday Trans., 91, 367 (1993)
Na K, Okuhara T, Misono M, J. Chem. Soc.-Chem. Commun., 1422 (1993)
Na K, Okuhara T, Misono M, J. Catal., 170(1), 96 (1997)
Okuhara T, Mizuno N, Misono M, Adv. Catal., 41, 113 (1996)
Okuhara T, Nishimura T, Misono M, Chem. Lett., 155 (1995)
Okuhara T, Nishimura T, Misono M, Proc. 11th Intern. Congr. Catal., Baltimore, 581 (1996)
Okuhara T, Nishimura T, Misono M, J. Molec. Catal., 74, 247 (1992)
Shikata S, Nakata S, Okuhara T, Misono M, J. Catal., 166(2), 263 (1997)
Takahashi K, Okuhara T, Misono M, Chem. Lett., 841 (1985)
Tatematsu S, Hibi T, Okuhara T, Misono M, Chem. Lett., 865 (1984)

[Referenced By]

[1] Centi G, Lena V, Trifiro F, J. Chem. Soc.-Faraday Trans., 86, 2775 (1990)

[2] Inumaru K, Kubo Ono A, Misono M, "The Structure and Redox Behaviour of Vanadium Speeies in Molybdovanadophosphoric Acid Catalysts during Partial Oxidation of Isobutane," to be published

[3] Inumaru K, Nakajima H, Ito T, Misono M, Chem. Lett., 559 (1996)

[4] Japan Patent, 1988-145249 (Asahi Chemical) (1988)

[5] Japan Patent, 1991-106839 (Sumitomo Chemical) (1991)

[6] Koyano G, Saito T, Misono M, Chem. Lett., 415 (1997)

[7] Koyano G, Yamaguchi F, Okuhara T, Misono M, Catal. Lett., 41(3-4), 149 (1996)

[8] Lee KY, Arai T, Nakata S, Asaoka S, Okuhara T, Misono M, J. Am. Chem. Soc., 114, 2836 (1992)

[9] Lee KY, Oishi S, Igarashi H, Misono M, Catal. Today, 33(1-3), 183 (1997)

[10] Li W, Ueda W, Catal. Lett., 46, 261 (1991)

[11] Liu Y, Koyano G, Na K, Makoto M, Appl. Catal. A: Gen., in press

[12] Misono M, Okuhara T, Chemtech., 23 (1993)

[13] Mizuno N, Tateishi M, Iwamoto M, J. Catal., 163(1), 87 (1996)

[14] Mizuno N, Tateishi M, Iwamoto M, J. Mol. Catal., 114, 309 (1996)

[15] Mizuno N, Tateishi M, Iwamoto M, Chem. Lett., 1121 (1996)

[16] Nizuno N, J. Mol. Catal., "Catalytic Performance of Cs_2.5Fe_0.08H_1.26-PVMo₁₁O₄₀ for Direct. Oxidation of Lower Alkanes,"

[17] Lizuno N, Chem. Lett., "Selective Oxidative Dehydrogenation of Ethane Catalyzed by Cs_2.5Mn_0.08H_1.34PVMo₁₁O₄₀," Catalyst Precursor

[18] Na K, Okuhara T, Misono M, J. Chem. Soc.-Faraday Trans., 91, 367 (1993)

[19] Na K, Okuhara T, Misono M, J. Chem. Soc.-Chem. Commun., 1422 (1993)

[20] Na K, Okuhara T, Misono M, J. Catal., 170(1), 96 (1997)

[21] Okuhara T, Mizuno N, Misono M, Adv. Catal., 41, 113 (1996)

[22] Okuhara T, Nishimura T, Misono M, Chem. Lett., 155 (1995)

[23] Okuhara T, Nishimura T, Misono M, Proc. 11th Intern. Congr. Catal., Baltimore, 581 (1996)

[24] Okuhara T, Nishimura T, Misono M, J. Molec. Catal., 74, 247 (1992)

[25] Shikata S, Nakata S, Okuhara T, Misono M, J. Catal., 166(2), 263 (1997)

[26] Takahashi K, Okuhara T, Misono M, Chem. Lett., 841 (1985)

[27] Tatematsu S, Hibi T, Okuhara T, Misono M, Chem. Lett., 865 (1984)