A series of sodium alginate (SA) and starch blends, namely 100/0, 90/10, 80/20, 70/30, and 60/40, were processed into films by solution casting process and the obtained SA/starch blends have been characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). DSC analysis shows single glass transition temperature (T-g) up to 30 wt % starch content in the blend, indicating the compatibility and interaction between SA and starch molecules. The TGA reveals the reduction in thermal stability of SA/starch with increase in starch content. FTIR analysis demonstrated the existence of specific intermolecular interactions between carbonyl groups; of SA and hydroxyl groups of starch. The morphological analysis by SEM shows the homogeneous distribution of starch in the SA matrix. (c) 2008 Wiley Periodicals, Inc.