A method is proposed for scattered light correlation spectroscopy for objective evaluation of the effect of water, oxidation products, and particulate contaminants on the size of colloidal formations in petroleum oils with additives. It was shown that to increase the colloidal stability - resistance to separation of oils with additives -and correspondingly improve their performance properties, it is necessary to take into account the intermolecular interactions of the additives in composites and to ensure the minimum change in them under the effect of external factors. The mechanism of the reaction of the additives and their selection for ensuring the assigned performance properties of lube oils is theoretically substantiated.