화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Chemical Engineering Research, Vol.47, No.4, 410-417, August, 2009
Export Citation
MCM41에 담지된 Imidazole 촉매에 의한 Glycidyl Methacrylate와 이산화탄소의 반응속도론
Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41
손영식, 박문기1, †, 김건우2, 박상욱
  • 부산대학교 화학공학과, 609-735 부산시 금정구 장전동 산 30
  • 1대구한의대학교 한방제약공학과, 712-715 경북 경산시 유곡동 290번지
  • 2부산울산지방중소기업청 기업환경개선과, 618-819 부산시 강서구 송정동 1633-1
Young-Sik Son, Moon-Ki Park1, †, Gun-Woo Kim2, and Sang-Wook Park
  • Division of Chemical Engineering, Pusan National University, San 30, Jangjun-dong, Gumjung-gu, Busan 609-735, Korea
  • 1Department of Pharmaceutical Engineering, Daegu Haany University, 290, Yugok-dong, Gyeongsan-si, Gyeongbuk 712-715, Korea
  • 2Business Environment Improvement Division, Busan-Ulsan Regional Office of Small and Medium Business Administration, 1633-1 Songjung-dong, Gangseo-gu, Busan 618-819, Korea
E-mail:
초록
중간세공크기(mesopore)의 MCM41에 Imidazole을 담지시킨 CP-MS41 고체 입자의 촉매를 사용하여 GMA 용액에 CO2를 흡수시켜 CO2의 흡수기구로부터 GMA와 CO2의 반응속도론을 고찰하였다. 대기압에서 회분식 흡수조를 사용하여 임펠러의 교반속도, 50 rpm, 촉매, 2 g, 반응온도, 60, 70, 80 ℃, GMA의 농도, 0.1~3.0 kmol/m3, 용제, DMA, NMP, DMSO에서 측정한 CO2의 흡수속도와 경막설에 의한 물질수지식을 사용하여 반응속도상수를 구하였다.
Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of CO2 was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.
Keywords:Imidazole;Carbon Dioxide;Absorption;Ionic Liquid
  1. Peppel WJ, Ind. Eng. Chem., 50, 767 (1958)
  2. Rokicki G, Jezewski P, Polym. J., 20, 499 (1988)
  3. Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
  4. Nishikubo T, Kameyama A, Yamashita J, Tomoi M, Fukuda W, J. Polym. Sci., Part A, Polym. Chem., 31, 939 (1993)
  5. Nishikubo T, Kameyama A, Yamashita J, Fukumitsu T, Maejima C, Tomoi M, J. Polym. Sci. A: Polym. Chem., 33(7), 1011 (1995)
  6. Yamazaki N, Iguchi T, Hicashi F, J. Polym. Sci., Part A, Poly. Chem.,, 13, 785 (1975)
  7. Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
  8. Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)
  9. Endo T, Nagai D, Monma T, Yamaguchi H, Ochiai B, Macromolecules, 37(6), 2007 (2004)
  10. Doraiswamy LK, Sharma MM, Heterogeneous reactions, vol.1, John Wiley & Sons, Inc., New York (1984)
  11. Park SW, Park DW, Kim TY, Lee JW, Stud. Surf. Sci. Catal., 153, 535 (2004)
  12. Park SW, Park DW, Kim TY, Park MY, Oh KJ, Catal. Today, 98(4), 493 (2004)
  13. Park SW, Choi BS, Park DW, Kim SS, J. Ind. Eng. Chem., 11(4), 527 (2005)
  14. Park SW, Lee JW, Stud. Surf. Sci. Catal., 159, 345 (2006)
  15. Park DW, Mun NY, Kim KH, Kim I, Park SW, Catal. Today, 115(1-4), 130 (2006)
  16. Park SW, Park DW, Lee JW, Korean J. Chem. Eng., 23(4), 645 (2006)
  17. Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)
  18. Park SW, Choi BS, Park DW, Kim SS, Lee JW, Korean J. Chem. Eng., 24(6), 953 (2007)
  19. Park SW, Choi BS, Park DW, Lee JW, React. Kinet. Catal. Lett., 90(2), 215 (2007)
  20. Park SW, Choi BC, Park DW, Oh KJ, Lee JW, Green Chemistry, 9, 605 (2007)
  21. Park SW, Choi BS, Park DW, Lee JW, React. Kinet. Catal. Lett., 91(1), 101 (2007)
  22. Park SW, Choi BC, Park DW, Udayakumar S, Lee JW, Catal. Today, 131, 559 (2008)
  23. Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)
  24. Alper E, Al-Hamed A, Shaikh AA, Proc. Int. Chem. React. Eng. Conf., 2, 17 (1987)
  25. Reid RC, Prausnitz JM, Sherwwod TK, The properties of Gases and Liquid, McGraw-Hill Book Company, New York (1977)
  26. Cussler EL, Diffusion, Cambridge University Press, NewYork (1984)
  27. Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
  28. Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)
  29. Herbrandson HF, Neufeld FR, J. Org. Chem., 31, 1140 (1966)
  30. Brandrup J, Immergut EH, Polymer Handbook, Second Ed., John Wiley & Sons, New York (1975)