화학공학소재연구정보센터
Applied Surface Science, Vol.253, No.4, 2208-2216, 2006
1064-nm laser fragmentation of thin Au and Ag flakes in acetone for highly productive pathway to stable metal nanoparticles
The laser-induced fragmentation of thin An and Ag flakes in acetone by 1064-nm nanosecond laser (with the fluence typically similar to 2 J/cm(2)) potentially offers a highly productive pathway to stable metal nanoparticles in liquid. Acetone serves as a superior liquid medium that keeps fine metal nanoparticles free from precipitation even in such concentrated nanoparticle solutions exceeding similar to 0.1 M. Thin metal flakes have good capability to absorb the 1064-nm laser energy as efficiently as in the visible region. A part of the thus laser-heated molten flakes explosively split into submicroparticles, and some other significant part directly into fine nanoparticles. Both kinds of product particles have minor absorption cross-sections for subsequent laser pulses at 1064 nm, and thus no longer fragment further. One of the two kinds of Ag flakes studied in this work yielded fine Ag nanoparticles at a remarkable high production rate of 1.1 mg/min for the input laser power of only similar to 0.65 W. (c) 2006 Elsevier B.V. All rights reserved.