Ion Exchange of Cs Ion in Acid Solution with Potassium Cobalt Hexacyanoferrate

Jei-Kwon Moon; Eil-Hee Lee; Hyung-Tae Kim

Korean Journal of Chemical Engineering, Vol.21, No.5, 1026-1031, September, 2004

DOI10.1007/BF02705588 Export Citation

Ion Exchange of Cs Ion in Acid Solution with Potassium Cobalt Hexacyanoferrate

Jei-Kwon Moon^†, Eil-Hee Lee , and Hyung-Tae Kim¹

Korea Atomic Energy Research Institute, P.O. Box 105 Yuseong, Daejeon 305-600, Korea
¹Yonsei University, Shinchon-Dong, Seodaemun-Gu, Seoul 120-749, Korea

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Potassium cobalt hexacyanoferrate (KCoFC) was synthesized for removal of Cs ions in acid waste solution. The synthesized KCoFC was stable in nitric acid solution of pH=1 and showed high selectivity for Cs ion over Sr and Na ions. The K_d,csfor 0.01 N Cs ion solution at pH=2 was about 3.6X10³mL/g in the presence of the same concentrations of Sr and Na ions, respectively. In the binary ion exchange system, both the Dubinin-Polanyi model Langmuir model. However, in the multi-component system, only the modified Dubinin-Polanyi model, which is a semiempirical equation, fit the experimental data accurately. The ion exchange capacity of KCoFC for Cs ion obtained by the Dubinin-Polanyi equation was 1.72 meq/g

Keywords:Ion Exchange;Cesium Ion;potassium Cobalt Hexacyanoferrate;Distribution Coefficient;Separation Factor;Radioactive;Liquid Waste

[References]

Broul M, Nyvlt J, Sohnel O, "Physical Sciences Data 6, Solubility in Inorganic Two-Component Systems," Elsevier Scientific Publishing Company, Amsterdam-Oxford-New York (1981)
Huckman ME, Latheef IM, Anthony RG, Sep. Sci. Technol., 34(6-7), 1145 (1999)
Kim HT, Shul YG, Moon JK, Jung CH, Lee EH, Czech. J. Phys., 53, 487 (2003)
Kubica B, Tuteja-Krysa M, Szeglowski Z, J. of Radioanal. Nucl. Chem. Letters., 213(6), 411 (1996)
Liang T, Hsu C, Radiochim. Acta, 61, 105 (1993)
Lopez H, Olguin MT, Bosch P, Bulbulian S, J. Radioanal. Nucl. Chem. Letters, 200(1), 19 (1995)
Ishfaq MM, Sci. Int. (Lahore), 11(3), 249 (1999)
Marageh MG, Husain SW, Khanchi AR, Appl. Radiat. Isot., 50, 459 (1999)
Mardan A, Rumana A, Mehmood A, Raza SM, Ghaffar A, Sep. Purif. Technol., 16, 147 (1999)
Mimura H, Kimura M, Akiba K, Onodera Y, J. of Nuclear and Technology, 35(5), 392 (1998)
Mimura H, Letho J, Harjula R, J. of Nuclear Science and Technology, 34(5), 484 (1997)
Mimura H, Letho J, Harjula R, J. of Nuclear Science and Technology, 34(6), 582 (1997)
Mimura H, Kobayashi T, Akiba K, J. of Nuclear Science and Techonology, 32(1), 60 (1995)
Mimura H, Akiba K, Kawamura K, J. of Nuclear Science and Techonology, 31(5), 463 (1994)
Moon JK, Kim HT, Shul YG, Lee EH, Yoo JH, HWAHAK KONGHAK, 38(6), 847 (2000)
Moon JK, Jung CH, Lee EH, Kim HT, Shul YG, Korean J. Chem. Eng., 19(5), 838 (2002)
Perona JJ, Coroneos AC, Kent TE, Richardson SA, Sep. Sci. Technol., 30(7-9), 1259 (1995)
Prout WE, Russell ER, Groh HJ, J. Inorg. Nucl. Chem., 27, 473 (1964)
Rengaraj S, Kim Y, Joo CK, Choi K, Yi J, Korean J. Chem. Eng., 21(1), 187 (2004)
Robinson SM, Arnold WD, Byers CH, "Multicomponent Liquid Ion Exchange with Chabazite Zeolite," ORNL TM-12403 (1993)
Sinha PK, Panicker PK, Amalraj RV, Krishnasamy V, Waste Manage., 15(2), 149 (1995)

[Referenced By]

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[1] Broul M, Nyvlt J, Sohnel O, "Physical Sciences Data 6, Solubility in Inorganic Two-Component Systems," Elsevier Scientific Publishing Company, Amsterdam-Oxford-New York (1981)

[2] Huckman ME, Latheef IM, Anthony RG, Sep. Sci. Technol., 34(6-7), 1145 (1999)

[3] Kim HT, Shul YG, Moon JK, Jung CH, Lee EH, Czech. J. Phys., 53, 487 (2003)

[4] Kubica B, Tuteja-Krysa M, Szeglowski Z, J. of Radioanal. Nucl. Chem. Letters., 213(6), 411 (1996)

[5] Liang T, Hsu C, Radiochim. Acta, 61, 105 (1993)

[6] Lopez H, Olguin MT, Bosch P, Bulbulian S, J. Radioanal. Nucl. Chem. Letters, 200(1), 19 (1995)

[7] Ishfaq MM, Sci. Int. (Lahore), 11(3), 249 (1999)

[8] Marageh MG, Husain SW, Khanchi AR, Appl. Radiat. Isot., 50, 459 (1999)

[9] Mardan A, Rumana A, Mehmood A, Raza SM, Ghaffar A, Sep. Purif. Technol., 16, 147 (1999)

[10] Mimura H, Kimura M, Akiba K, Onodera Y, J. of Nuclear and Technology, 35(5), 392 (1998)

[11] Mimura H, Letho J, Harjula R, J. of Nuclear Science and Technology, 34(5), 484 (1997)

[12] Mimura H, Letho J, Harjula R, J. of Nuclear Science and Technology, 34(6), 582 (1997)

[13] Mimura H, Kobayashi T, Akiba K, J. of Nuclear Science and Techonology, 32(1), 60 (1995)

[14] Mimura H, Akiba K, Kawamura K, J. of Nuclear Science and Techonology, 31(5), 463 (1994)

[15] Moon JK, Kim HT, Shul YG, Lee EH, Yoo JH, HWAHAK KONGHAK, 38(6), 847 (2000)

[16] Moon JK, Jung CH, Lee EH, Kim HT, Shul YG, Korean J. Chem. Eng., 19(5), 838 (2002)

[17] Perona JJ, Coroneos AC, Kent TE, Richardson SA, Sep. Sci. Technol., 30(7-9), 1259 (1995)

[18] Prout WE, Russell ER, Groh HJ, J. Inorg. Nucl. Chem., 27, 473 (1964)

[19] Rengaraj S, Kim Y, Joo CK, Choi K, Yi J, Korean J. Chem. Eng., 21(1), 187 (2004)

[20] Robinson SM, Arnold WD, Byers CH, "Multicomponent Liquid Ion Exchange with Chabazite Zeolite," ORNL TM-12403 (1993)

[21] Sinha PK, Panicker PK, Amalraj RV, Krishnasamy V, Waste Manage., 15(2), 149 (1995)