Multiple-Layered Colloidal Assemblies via Dipping Method with an External Electric Field

Sang Hyuk Im; O Ok Park; Moo Hyun Kwon

Macromolecular Research, Vol.11, No.2, 110-114, April, 2003

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Multiple-Layered Colloidal Assemblies via Dipping Method with an External Electric Field

Sang Hyuk Im, O Ok Park^†, and Moo Hyun Kwon¹

Department of Chemical & Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1Guesong-Dong, Yuseong-Gu, Daejeon, Korea
¹Department of Chemical Engineering, Woosuk University, 490 Hujung-ri, Samrae-eup, Wanju-gun, Jeonbuk 656-701, Korea

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When using the dipping method for crystal formation, mono-layered colloidal crystal structures depend upon the lift-up rate of a glass substrate. The mono-layered colloidal crystals showed the highest quality when the glass substrate was raised at a rate of 3 mm/min at 25 ℃ in a 1 wt% polystyrene colloidal suspension (ethanol medium). In addition, in order to obtain multiple-layered colloidal crystals, an external electric field was introduced. Multiple-layered colloidal crystals were successfully obtained via this method. The colloidal particles were well ordered over large areas and assembled into a homogeneous structure.

Keywords:colloidal crystals;mono-layer;multiple-layer;colloidal suspension

[References]

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Yi GR, Moon JH, Yang SM, Chem. Mater., 13, 2613 (2001)
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Park MS, Korea Polym. J., 2(1), 54 (1994)
Shmuylovich L, Shen AQ, Stone HA, Langmuir, 18(9), 3441 (2002)
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[Referenced By]

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[1] Okuyama S, Matsushita SI, Fujishima A, Langmuir, 18(22), 8282 (2002)

[2] van Duffel B, Ras RHA, DeSchryver FC, Schoonheydt RA, J. Mater. Chem., 11, 3333 (2001)

[3] Vogelaar L, Nijda W, vanWolferen HA, deRidder RM, Segerink FB, Kuipers EFL, vanHulst NF, Adv. Mater., 13, 1551 (2001)

[4] Shkunov MN, Vardeny XV, Delong MC, Poloson RC, Zakhidov AA, Baughman RH, Adv. Funct. Mater., 12, 21 (2002)

[5] Park SH, Xia YN, Langmuir, 15(1), 266 (1999)

[6] Tran P, J. Opt. Soc. Am., 14, 2589 (1997)

[7] Denkov ND, Velev OD, Kralchevsky PA, Ivanov IB, Yoshimura H, Nagayama K, Nature, 361, 26 (1993)

[8] Denkov ND, Velev OD, Kralchevsky PA, Ivanov IB, Yoshimura H, Nagayama K, Langmuir, 8, 3183 (1992)

[9] Yamaki M, Higo J, Nagayama K, Langmuir, 11(8), 2975 (1995)

[10] Dimitrov AS, Nagayama K, Langmuir, 12(5), 1303 (1996)

[11] Miguez H, Meseguer F, Lopez C, Blanco A, Moya J, Requena J, Mifsud A, Fornes V, Adv. Mater., 10, 480 (1998)

[12] Jiang P, Bertone JF, Hwang KS, Colvin VL, Chem. Mater., 11, 2132 (1999)

[13] Vlasov YA, Bo XZ, Sturm JC, Norris DJ, Nature, 414, 289 (2001)

[14] Rogach AL, Kotov NA, Koktysh DS, Ostrander JW, Ragoisha GA, Chem. Mater., 12, 2721 (2000)

[15] Im SH, Lim YT, Suh DJ, Park OO, Adv. Mater., 14, 1367 (2002)

[16] Griesebock B, Egen M, Zentel R, Chem. Mater., 14, 4023 (2002)

[17] Yi GR, Moon JH, Yang SM, Chem. Mater., 13, 2613 (2001)

[18] Kim JH, Chainey M, El-Aasser MS, Vanderhoff JW, J. Polym. Sci. A: Polym. Chem., 30, 171 (1992)

[19] Chengyou K, Huihui L, Qing Y, Xiangzheng K, Korea Polym. J., 5(4), 221 (1997)

[20] Park MS, Korea Polym. J., 2(1), 54 (1994)

[21] Shmuylovich L, Shen AQ, Stone HA, Langmuir, 18(9), 3441 (2002)

[22] Deegan RD, Bakajin O, Dupont TF, Huber G, Nagel SR, Witten TA, Nature, 389(6653), 827 (1997)

[23] Deegan RD, Phys. Rev. E, 61, 61475 (2000)

[24] Amos RM, Rarity JG, Tapster PR, Shepherd TJ, Phys. Rev. E, 61, 2929 (2000)