화학공학소재연구정보센터
Polymer Engineering and Science, Vol.41, No.9, 1540-1552, 2001
High, internal phase emulsion foams: Copolymers, and interpenetrating polymer networks
High internal phase emulsion (HIPE) copolymer and interpenetrating network foams were prepared from 2-ethylhexyl acrylate (EHA), styrene (S) and divinylbenzene (DVB) using a unique process. The morphologies, thermal properties, and dynamic and static mechanical properties of these foams were investigated. The glass transition temperatures and damping properties of the EHA/S copolymer foams vary with its composition. IPN foams with very broad tan delta peaks were obtained. The damping properties of IPN foams were tailored through changing copolymer composition and monomer composition. The IPN foams based on a copolymer foam and styrene had a broader tan delta, peak, a higher glass transition temperature and a higher modulus than the copolymer foams of similar overall styrene contents. It is therefore possible to prepare novel damping foams based on polyHIPE foams through the synthesis of interpenetrating polymer networks.