화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.30, No.1, 26-35, January, 2022
DOI10.1007/s13233-022-0002-3  Export Citation
Hybrid Adsorbent Based on Zeolite NaX Modified with Hyperbranched Polyester Poly(N-benzoylthiocarbamate)
Aleksei Maksimov†, Alina Vagapova, Marianna Kutyreva1, and Gennadiy Kutyrev
  • Kazan National Research Technological University, 420015, Kazan, st. K. Marx, 68, Russia, Russian Federation
  • 1Kazan Federal University, 420008, Kazan, st. Kremlin, 18, Russia, Russian Federation
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A new hybrid adsorbent has been synthesized by covalent linking of activated zeolite with hyperbranched polyester containing 8 terminal N-benzoylthiocarbamate groups. The structure of the polymer ligand was defined by IR, 1H and 13C NMR spectroscopy. The complexing properties of the adsorbent have been studied using the example of complexes with Cu(II) and Co(II) ions. It was proved by IR spectroscopy that N-benzoylthiocarbamate and toluylenecarbamate groups participate in complexation with metal ions. According to electron microscopy and porometry data, the average particle diameter of the adsorbent is 34.56 μm and the mesopore diameter is 4.19 nm. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) have shown that the hybrid adsorbent is thermally stable up to 150 °C. The sorption capacities of the adsorbent for Cu(II) and Co(II) ions are 31.92 and 17.7 g/kg. It was shown that the desorption process of metal ions from the complexes occurs in an acidic medium at pH 4 with the regeneration of the original adsorbent.
Keywords:hybrid adsorbent;hyperbranched polyester;metal complexes;zeolite
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